IP Library Granted Patent US 10,513,155
Granted Patent B2
US 10,513,155 · App. 15/236,428 · Granted Dec 24, 2019

Tire balancing compositions

Inventor: Alvin Ronlan (Stockholm, SE)
Assignee: Bertil Carnehammar
B60C19/003B01J13/0065B29D30/0633B60C19/002C08L71/02B29D2030/0637B29K2023/04B29K2071/12B29K2105/0085C08K3/36
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Quick Facts
Patent No.
US 10,513,155
App. No.
15/236,428
Granted
Dec 24, 2019
Kind
B2
Abstract

Visco-elastic tyre balancing compositions comprising 1) 85 to 97% by weight of a glycol ether component comprising one or more ethylene/propylene glycol copolymer ethers of the general formula (I) or the general (II) or mixtures thereof R—O{[CH(CH 3 )CH 2 —O—] m [CH 2 —CH 2 —O—] n }H (I) R 1 —(O—{[CH(CH 3 )CH 2 —O—] m [CH 2 —CH 2 —O—] n }H) 2 (II) wherein R is hydrogen or an alkyl group of 2-8 carbon atoms; R 1 is an alkylene moiety of 2-8 carbon atoms in which the two substituents are not carried on the same carbon atom; m is the mole percentage of propylene glycol in the ethylene/propylene glycol copolymer moiety or moieties; and n is the mole percentage of ethylene glycol in the ethylene/propylene glycol copolymer moiety or moieties, wherein the ratio n:m is in the range from 35:65 to 80:20; each glycol copolymer compound having a number average molecular weight in the range of 2000-10000; and 2) 3 to 15% by weight of a fumed silica gel former; said balancing compositions being visco-elastic and having a Storage Modulus (G′) between 1500 Pa and 5000 Pa at 22° C., a Loss Modulus (G″) smaller than the Storage Modulus up to a Cross Over Frequency of 10-40 Hz, and a Critical Yield Stress exceeding 2 Pa.

Claims (21)

1. A method for balancing tires having an air cavity comprising introducing a gel formulation onto the inner surface of a tire, wherein the gel composition consists essentially of:

1) 93.3 to 94 weight-percent of a glycol ether component comprising a mixture of ethylene/propylene glycol copolymer ethers of the general formula (II):

R 1 —(O—{[CH(CH 3 )CH 2 —O—] m [CH 2 CH 2 —O] n }H) 2   (II)

wherein

R is hydrogen or an alkyl group of 2-8 carbon atoms;

R 1 is an alkylene moiety of 2-8 carbon atoms in which the two substituents are not carried on the same carbon atom;

m is the mole percentage of propylene glycol in the ethylene/propylene glycol copolymer moiety or moieties; and

n is the mole percentage of ethylene glycol in the ethylene/propylene glycol copolymer moiety or moieties, wherein the n:m ratio is in the range from 35:65 to 80:20;

each glycol copolymer compound having a number average molecular weight in the range of 2000-10000; and

2) a fumed silica gel former;

said gel composition being visco-elastic and having a Storage Modulus (G′) between 1500 Pa and 5000 Pa at 22° C., a Loss Modulus (G″) smaller than the Storage Modulus up to a Cross Over Frequency of 10-40 Hz, and a Critical Yield Stress exceeding 2 Pa,

wherein ethylene/propylene glycol copolymer ether of the general formula (II) having a n:m ratio from 70:30 to 80:20 is present in the composition in an amount of 1% by weight of the gel composition and the balance of the ethylene/-propylene glycol copolymer ether of the general formula (II) has a n:m ratio from 50:50 up to, but not including, 70:30 and

the fumed silica gel former is present in the composition in an amount in the range from 6 to 6.7% by weight.

2. The method according to claim 1 , wherein the number average molecular weight of the glycol ether component(s) is/are in the range of 3000-10000.

3. The method according to claim 2 , wherein the fumed silica gel former is a hydrophilic type fumed silica having a BET surface area in the range from 200 to 300 m 2 /g; or the fumed silica gel former is a hydrophobized type fumed silica having a BET surface area in the range from 250 to 350 m 2 /g; or mixtures of such hydrophilic and hydrophobized type fumed silica gel formers.

4. The method according to claim 3 , wherein the ethylene/propylene glycol copolymer ether of the general formula (II) having a n:m ratio from 70:30 to 80:20 is a random copolymer of ethylene oxide and propylene oxide containing 75% by weight oxyethylene and 25% by weight oxypropylene groups.

5. The method according to claim 4 , wherein the fumed silica gel former is present in the gel composition in an amount of 6.5+/−0.2% by weight of the gel composition.

6. The method according to claim 1 , wherein the fumed silica gel former is a hydrophilic type fumed silica having a BET surface area in the range from 200 to 300 m 2 /g; or the fumed silica gel former is a hydrophobized type fumed silica having a BET surface area in the range from 250 to 350 m 2 /g; or mixtures of such hydrophilic and hydrophobized type fumed silica gel formers.

7. The method according to claim 1 , wherein the glycol ether component(s) exhibit(s) a Viscosity Grade determined according to ISO3448 in the range from 800 to 1200.

8. The method according to claim 1 , wherein the ethylene/propylene glycol copolymer ether of the general formula (II) having a n:m ratio from 70:30 to 80:20 is a random copolymer of ethylene oxide and propylene oxide containing 75% by weight oxyethylene and 25% by weight oxypropylene groups.

9. The method according to claim 1 , wherein the fumed silica gel former is present in the gel composition in an amount of 6.5+/−0.2% by weight of the gel composition.

Assignments (7)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 20, 2026
From: GEL SCIENCES GROUP LLC
To: GEL DYNAMICS, INC.
Reel/Frame 073517/0441 →
CORRECTIVE ASSIGNMENT TO CORRECT THE SPELLING OF ASSIGNOR'S LAST NAME PREVIOUSLY RECORDED AT REEL: 060845 FRAME: 0802. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Aug 23, 2022
From: CARNEHAMMAR, BERTIL
To: IGS HOLDINGS LLC
Reel/Frame 061302/0796 →
CHANGE OF NAME Recorded Aug 18, 2022
From: IGS HOLDINGS LLC
To: GEL SCIENCES GROUP LLC
Reel/Frame 061207/0561 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 18, 2022
From: CARNEHAMMER, BERTIL
To: IGS HOLDINGS LLC
Reel/Frame 060845/0802 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2019
From: RONLAN, ALVIN
To: PROF. DR. LARS BERTIL CARNEHAMMAR
Reel/Frame 051005/0541 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2019
From: RONLAN, ALVIN
To: CARNEHAMMAR, BERTIL
Reel/Frame 051005/0779 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME IN PARAGRAPH2 OF ASSIGNMENT AND SECTION 2 OF COVER SHEET PREVIOUSLY RECORDED ON REEL 026386 FRAME 0814. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT OF THE ENTIRE RIGHT, TITLE AND INTEREST TO GOTTE LARS BERTIL CARNEHAMMAR.. Recorded Nov 14, 2019
From: RONLAN, ALVIN
To: DR. GOTTE LARS BERTIL CARNEHAMMAR
Reel/Frame 051850/0910 →
Priority Claims (1)
EP 08168913 · Nov 12, 2008 · regional
Continuity (2)
Continuation 13126693
Related Publication 20160347128A1 · Dec 1, 2016