Pattern-forming method
A pattern-forming method comprises applying a chemically amplified resist material on an antireflective film formed on a substrate to form a resist material film. The resist material film is patternwise exposed to ionizing radiation or nonionizing radiation having a wavelength of no greater than 400 nm. The resist material film patternwise exposed is floodwise exposed to nonionizing radiation having a wavelength greater than the nonionizing radiation for the patternwise exposing and greater than 200 nm. The resist material film floodwise exposed is baked. The resist material film baked is developed with a developer solution. An extinction coefficient of the antireflective film for the nonionizing radiation employed for the floodwise exposing is no less than 0.1. The chemically amplified resist material comprises a base component and a generative component that is capable of generating a radiation-sensitive sensitizer and an acid upon an exposure.
1. A pattern-forming method comprising:
applying a chemically amplified resist material on an antireflective film formed on a substrate to form a resist material film;
patternwise exposing the resist material film to ionizing radiation or nonionizing radiation having a wavelength of no greater than 400 nm;
floodwise exposing the resist material film patternwise exposed, to nonionizing radiation having a wavelength greater than the nonionizing radiation for the patternwise exposing and greater than 200 nm;
baking the resist material film floodwise exposed; and
developing with a developer solution the resist material film baked,
wherein
an extinction coefficient of the antireflective film for the nonionizing radiation employed for the floodwise exposing is no less than 0.1, and
the chemically amplified resist material comprises:
a base component that is made soluble or insoluble in the developer solution by an action of an acid; and
a generative component that is capable of generating a radiation-sensitive sensitizer and an acid upon an exposure,
wherein the generative component comprises: a radiation-sensitive acid-and-sensitizer generating agent; any two among the radiation-sensitive acid-and-sensitizer generating agent, a radiation-sensitive sensitizer generating agent and a radiation-sensitive acid generating agent, or all the radiation-sensitive acid-and-sensitizer generating agent, the radiation-sensitive sensitizer generating agent and the radiation-sensitive acid generating agent,
wherein
the radiation-sensitive acid-and-sensitizer generating agent is capable of generating, upon an exposure to the ionizing radiation or the nonionizing radiation in the patternwise exposing, an acid and a radiation-sensitive sensitizer that absorbs the nonionizing radiation in the floodwise exposing, and is not substantially capable of generating the acid and the radiation-sensitive sensitizer during the floodwise exposing, in light-unexposed regions in the patternwise exposing,
the radiation-sensitive sensitizer generating agent is capable of generating, upon the exposure to the ionizing radiation or the nonionizing radiation in the patternwise exposing, the radiation-sensitive sensitizer that absorbs the nonionizing radiation in the floodwise exposing, and is not substantially capable of generating the radiation-sensitive sensitizer during the floodwise exposing, in the light-unexposed regions in the patternwise exposing, and
the radiation-sensitive acid generating agent is capable of generating the acid upon the exposure to the ionizing radiation or the nonionizing radiation in the patternwise exposing, and is not substantially capable of generating the acid during the floodwise exposing, in the light-unexposed regions in the patternwise exposing.
2. The pattern-forming method according to claim 1 , wherein prior to the forming of the resist material film, a transparent film having an extinction coefficient for the nonionizing radiation employed for the floodwise exposing of no greater than 0.1 is formed to be provided between the antireflective film and the resist material film.
3. The pattern-forming method according to claim 1 , wherein prior to the forming of the resist material film, a silicon-containing film is formed to be provided between the antireflective film and the resist material film.
4. The pattern-forming method according to claim 1 , wherein the antireflective film is an organic film.
5. The pattern-forming method according to claim 1 , wherein the extinction coefficient of the antireflective film for the ionizing radiation or the nonionizing radiation employed for the patternwise exposing is no less than 0.3.