Polyanthraquinone-based organic cathode for high-performance rechargeable magnesium-ion batteries
A rechargeable magnesium ion electrochemical cell comprising an anode, a cathode, and a non-aqueous magnesium electrolyte disposed between the anode and the cathode is described herein. The cathode comprises a redox-active anthraquinone-based polymer comprising one or more of 1,4-polyanthraquinone or 2,6-polyanthraquinone. Both 2,6-polyanthraquinone and 1,4-polyanthraquinone can operate with 1.5-2.0 V with above 100 mAh/g capacities at a reasonable rate, higher than the state-of-the-art Mg—Mg 6 S 8 battery. More than 1000 cycles with very small capacity loss can be realized.
1. A rechargeable magnesium ion electrochemical cell comprising:
an anode;
a cathode;
and a magnesium ion-containing electrolyte disposed between the anode and the cathode;
wherein the cathode comprises a redox-active anthraquinone polymer selected from the group consisting of 1,4-polyanthraquinone, 2,6-polyanthraquinone, and a combination thereof.
2. The electrochemical cell of claim 1 , wherein the anthraquinone polymer comprises 1,4-polyanthraquinone.
3. The electrochemical cell of claim 1 , wherein the anthraquinone polymer comprises 2,6-polyanthraquinone.
4. The electrochemical cell of claim 1 , wherein the cathode further comprises a particulate carbon material in addition to the anthraquinone polymer.
5. The electrochemical cell of claim 4 , wherein the particulate carbon material comprises carbon black.
6. The electrochemical cell of claim 4 , wherein the cathode further comprises a binder to bind the carbon and polymer together.
7. The electrochemical cell of claim 6 , wherein the binder is poly(vinylidene difluoride).
8. The electrochemical cell of claim 1 , wherein the cathode further comprises a conductive substrate in contact with the anthraquinone polymer.
9. The electrochemical cell of claim 1 , wherein the electrolyte comprises a non-nucleophilic magnesium salt in a non-aqueous solvent.
10. The electrochemical cell of claim 1 , wherein the electrolyte comprises a magnesium salt selected from MgCl 2 —AlCl 3 , Mg(HMDS) 2 -AlCl 3 , Mg(HMDS) 2 -4MgCl 2 , and Mg(TFSI) 2 -MgCl 2 , wherein HMDS is hexamethyldisilazide, and TFSI is bis(trifluoromethanesulfonyl)imide.
11. The electrochemical cell of claim 1 , wherein the electrolyte comprises Mg(HMDS) 2 -4MgCl 2 in tetrahydrofuran.
12. The electrochemical cell of claim 1 , wherein the cell maintains at least 80% discharge capacity after 100 cycles at a current rate of about 0.5 C (130 mA g −1 ).
13. The electrochemical cell of claim 1 , wherein the cell maintains at least 90% discharge capacity after 1000 cycles at a current rate of about 1 C (260 mA g −1 ).
14. The electrochemical cell of claim 1 , wherein the cathode comprises:
a mixture of the redox-active anthraquinone polymer and a particulate carbon material held together by a binder and coated on a conductive substrate.
15. The electrochemical cell of claim 14 , wherein the binder is poly(vinylidene difluoride).
16. The electrochemical cell of claim 15 , wherein the particulate carbon material comprises carbon black.
17. The electrochemical cell of claim 14 , wherein the conductive substrate comprises graphite foil.
18. The electrochemical cell of claim 16 , wherein the anthraquinone polymer, carbon black, and binder are present in a weight ratio of about 4:5:1, respectively.
19. A battery comprising a plurality of the electrochemical cell of claim 1 electrically connected together.