IP Library Granted Patent US 10,293,291
Granted Patent B2
US 10,293,291 · App. 15/250,865 · Granted May 21, 2019

Interlaced filtration barrier

Inventors: Ho Wang Tong (Hong Kong, CN); Sau Kuen Connie Kwok (Hong Kong, CN)
Assignee: Nano and Advanced Materials Institute Ltd.
B01D46/0001B01D39/1623B01D46/0023B01D46/0028B01D46/0032B01D46/546B29C48/18B29C65/08B29C65/565B29C65/72D01D1/02D01D5/003D01D5/0076B01D2239/025B01D2239/0435B01D2239/0442B01D2239/064B01D2239/065B01D2239/0631B01D2239/0645B01D2239/0654B01D2239/0672B01D2239/1233B29K2001/00B29K2001/12B29K2023/10B29L2031/14
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,293,291
App. No.
15/250,865
Granted
May 21, 2019
Kind
B2
Abstract

A filtration barrier comprises at least one barrier layer which includes polymeric nanofibers interlaced with microfibers, and at least one substrate layer which includes polymeric microfibers. The filtration barrier can be made by electrospinning process.

Claims (45)

1. A method of fabricating a filtration barrier, comprising:

obtaining a polymer solution that includes cellulose acetate (CA) and polyethylene oxide (PEO); and

electrospinning the polymer solution onto a substrate layer to form an interlaced structure of nanofibers and microfibers on the substrate layer so that the nanofibers and the microfibers form a barrier layer;

wherein the nanofibers account for 60%-70% by weight in the barrier layer and the microfibers of the interlaced structure account for 30%-40% by weight in the barrier layer;

wherein the barrier layer and the substrate layer are attached to form the filtration barrier,

wherein the nanofibers and the microfibers are made from the same polymer solution, the nanofibers and the microfibers are interlaced in the same layer, and the nanofibers and the microfibers are discharged together from the same polymer solution during electrospinning to form the interlaced structure.

2. The method of claim 1 , wherein the CA accounts for 10%-20% by weight in the polymer solution.

3. The method of claim 1 , wherein the PEO accounts for 0.05%-0.2% by weight in the polymer solution.

4. The method of claim 1 , wherein the polymer solution includes benzyltriethylammonium chloride that accounts for 0.1%-0.3% by weight in the polymer solution.

5. The method of claim 1 , wherein the polymer solution includes dimethylformamide (DMF) that accounts for 80%-90% by weight in the polymer solution.

6. The method of claim 1 further comprising:

varying a conductivity, viscosity or surface tension of the polymer solution during electrospinning the polymer solution onto the substrate layer so that the interlaced structure of nanofibers and microfibers is formed.

7. The method of claim 1 further comprising:

adding a conductivity-enhancing additive into the polymer solution to vary a conductivity of the polymer solution.

8. The method of claim 1 further comprising:

adding a conductivity-enhancing additive into the polymer solution to vary a conductivity of the polymer solution,

wherein the conductivity-enhancing additive is benzyltriethylammonium chloride.

9. The method of claim 1 , wherein the substrate layer is a nonwoven fabric made of 10-100 gsm polypropylene.

10. The method of claim 1 , wherein a diameter of the nanofibers is 10 nanometers to 1000 nanometers, and a diameter of the microfibers in the barrier layer is 1 micron to 10 microns.

11. The method of claim 1 further comprising:

attaching the barrier layer to a supporting layer, wherein the barrier layer is sandwiched between the supporting layer and the substrate layer.

12. The method of claim 1 further comprising:

attaching the barrier layer to a supporting layer, wherein the barrier layer is sandwiched between the supporting layer and the substrate layer, the supporting layer is a nonwoven fabric made of 40-120 gsm polypropylene.

13. The method of claim 1 further comprising:

adding a biocide and a cross-linker to the polymer solution, wherein the biocide is cross-linked to the barrier layer, the biocide is chlorhexidine (CHX), and the cross-linker is organic titanate (TTE).

14. A method of fabricating a filtration barrier, comprising:

obtaining a polymer solution that includes a polymer;

electrospinning the polymer solution to form a barrier layer; and

attaching the barrier layer to a substrate layer to obtain the filtration barrier,

wherein

the barrier layer includes a plurality of first polymer-based nanofibers and a plurality of second polymer-based microfibers that are interlaced with the first polymer-based nanofibers in a same layer; and

the substrate layer includes a plurality of third polymer-based microfibers and is attached onto the barrier layer,

wherein the first polymer-based nanofibers and the second polymer-based microfibers that are interlaced with the first polymer-based nanofibers in the barrier layer are made from the same polymer solution,

wherein the first polymer-based nanofibers are electrospun nanofibers and the second polymer-based microfibers are electrospun microfibers,

wherein the first polymer-based nanofibers account for 60%-70% by weight of the barrier layer, and the interlaced structure of the barrier layer has a pore size of 100-10000 nanometers,

wherein the first polymer-based nanofibers and the second polymer-based microfibers are discharged together from the same polymer solution during electrospinning to form the interlaced structure.

15. The method of claim 14 , wherein the polymer solution includes a combination of cellulose acetate (CA) and polyethylene oxide (PEO).

16. The method of claim 14 , wherein the barrier layer is attached onto the substrate layer via mechanical interlocking or electrostatic attraction.

17. The method of claim 14 , wherein a perimeter of the barrier layer is attached onto a perimeter of the substrate layer via ultrasonic welding.

18. The method of claim 14 , wherein a conductivity, viscosity or surface tension of the polymer solution is varied during electrospinning the polymer solution onto the substrate layer so that the interlaced structure of the first polymer-based nanofibers and the second polymer-based microfibers is formed.

19. The method of claim 14 further comprising:

adding a conductivity-enhancing additive into the polymer solution to vary a conductivity of the polymer solution,

wherein the conductivity-enhancing additive is benzyltriethylammonium chloride.

20. The method of claim 14 further comprising:

attaching a supporting layer to the barrier layer, wherein the barrier layer is sandwiched between the supporting layer and the substrate layer.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 17, 2026
From: NANO AND ADVANCED MATERIALS INSTITUTE LIMITED
To: HONG KONG APPLIED SCIENCE AND TECHNOLOGY RESEARCH INSTITUTE COMPANY LIMITED
Reel/Frame 075402/0602 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2017
From: TONG, HO WANG; KWOK, SAU KUEN CONNIE
To: NANO AND ADVANCED MATERIALS INSTITUTE LTD.
Reel/Frame 042792/0721 →
Continuity (3)
Division 14562779 · Dec 8, 2014
Provisional Application 61963612 · Dec 9, 2013
Related Publication 20170007950A1 · Jan 12, 2017