IP Library Granted Patent US 10,094,603
Granted Patent B2
US 10,094,603 · App. 15/255,826 · Granted Oct 9, 2018

System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant

Inventor: Charles Harkins (Hampstead, NH)
Assignee: Hudson Technologies, Inc.
F25B45/00C09K5/045C10M105/38C10M171/008F25B31/002C09K2205/104C09K2205/122C09K2205/22C09K2205/40C09K2205/43C10M2207/2835C10N2220/302C10N2240/30F25B2345/001F25B2345/007
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,094,603
App. No.
15/255,826
Granted
Oct 9, 2018
Kind
B2
Abstract

A system and method for retrofitting a refrigeration system containing an HCFC refrigerant and a compatible lubricant, with an HFC refrigerant, comprising providing a transport container containing a mixture of about 5-15% by weight of a miscible lubricant and the HFC refrigerant, removing the HCFC refrigerant from the refrigeration system while maintaining at least a portion of a lubricant immiscible with the HFC refrigerant, and charging the refrigeration system with the mixture.

Claims (28)

1. A kit for retrofitting a refrigeration system from an HCFC refrigerant mixed with a compressor lubricant consisting of a mineral oil or alkyl benzene lubricant, to an HFC refrigerant compatible with a polyol ester lubricant, comprising:

a U.S. Department of Transportation compliant refrigerant transport container; and

an HFC refrigerant mixed with a compatible hygroscopic polyol ester compressor lubricant, in an amount of 5-20% by weight of the HFC refrigerant, within the U.S. Department of Transportation compliant transport container.

2. The kit according to claim 1 , wherein the HFC refrigerant comprises a blend of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a).

3. The kit according to claim 1 , wherein the HFC comprises R-407C.

4. The kit according to claim 1 , wherein the compatible hygroscopic polyol ester compressor lubricant is present in an amount of 8% by weight of the HFC refrigerant.

5. The kit according to claim 1 , wherein the compatible hygroscopic polyol ester compressor lubricant is present in an amount of 5-15% by weight of the HFC refrigerant.

6. The kit according to claim 1 , wherein the U.S. Department of Transportation compliant refrigerant transport container is compliant at least one of DOT-39, DOT 3, DOT 3A, DOT 3AA, DOT 3AL, DOT 3B, DOT 3BN, DOT 3E, DOT 4B, DOT 4BA, DOT 4B240ET, DOT 4BW, DOT 4E, DOT 3AL1800; DOT 4D; DOT-3A1000; DOT-3A1200; DOT-3A150; DOT-3A1800; DOT-3A2000; DOT-3A225; DOT-3A240; DOT-3A2400; DOT-3A300; DOT-3A400; DOT-3A480; DOT-3A480X; DOT-3AA; DOT-3AA1000; DOT-3AA1200; DOT-3AA150; DOT-3AA1800; DOT-3AA2000; DOT-3AA225; DOT-3AA240; DOT-3AA2400; DOT-3AA300; DOT-3AA400; DOT-3AA480; DOT-3AAX1800; DOT-3AAX2000; DOT-3AAX2200; DOT-3AAX2400; DOT-3AL; DOT-3AL1000; DOT-3AL150; DOT-3AL1800; DOT-3AL2000; DOT-3AL225; DOT-3AL240; DOT-3AL2400; DOT-3AL400; DOT-3AL480; DOT-3AX1800; DOT-3AX2000; DOT-3AX2200; DOT-3AX2400; DOT-3B; DOT-3B150; DOT-3B1800; DOT-3B225; DOT-3B240; DOT-3B300; DOT-3B400; DOT-3BN400; DOT-3BN480; DOT-3E1800; DOT-3HT; DOT-3HT2000; DOT-3T1800; DOT-3T2000; DOT-3T2200; DOT-3T2400; DOT-4A; DOT-4AA480; DOT-4B; DOT-4B150; DOT-4B150; DOT-4B225; DOT-4B240; DOT-4B240ET; DOT-4B300; DOT-4B400; DOT-4B480; DOT-4BA; DOT-4BA225; DOT-4BA240; DOT-4BA300; DOT-4BA400; DOT-4BW225; DOT-4BW240; DOT-4BW300; DOT-4BW400; DOT-4BW480; DOT-4DA; DOT-4DS; DOT-4E225; DOT-4E240; DOT-4L; and DOT-AAX2400.

7. The kit according to claim 6 , wherein the U.S. Department of Transportation compliant refrigerant transport container is compliant with DOT-39.

8. A U.S. Department of Transportation compliant transport container containing a mixture of an HFC refrigerant mixed with a compatible polyol ester compressor lubricant, in an amount of 5-20% by weight of the HFC refrigerant.

9. The U.S. Department of Transportation compliant transport container according to claim 8 , compliant with at least one of:

DOT-39, DOT 3, DOT 3A, DOT 3AA, DOT 3AL, DOT 3B, DOT 3BN, DOT 3E, DOT 4B, DOT 4BA, DOT 4B240ET, DOT 4BW, DOT 4E, DOT 3AL1800; DOT 4D; DOT-3A1000; DOT-3A1200; DOT-3A150; DOT-3A1800; DOT-3A2000; DOT-3A225; DOT-3A240; DOT-3A2400; DOT-3A300; DOT-3A400; DOT-3A480; DOT-3A480X; DOT-3AA; DOT-3AA1000; DOT-3AA1200; DOT-3AA150; DOT-3AA1800; DOT-3AA2000; DOT-3AA225; DOT-3AA240; DOT-3AA2400; DOT-3AA300; DOT-3AA400; DOT-3AA480; DOT-3AAX1800; DOT-3AAX2000; DOT-3AAX2200; DOT-3AAX2400; DOT-3AL; DOT-3AL1000; DOT-3AL150; DOT-3AL1800; DOT-3AL2000; DOT-3AL225; DOT-3AL240; DOT-3AL2400; DOT-3AL400; DOT-3AL480; DOT-3AX1800; DOT-3AX2000; DOT-3AX2200; DOT-3AX2400; DOT-3B; DOT-3B150; DOT-3B1800; DOT-3B225; DOT-3B240; DOT-3B300; DOT-3B400; DOT-3BN400; DOT-3BN480; DOT-3E1800; DOT-3HT; DOT-3HT2000; DOT-3T1800; DOT-3T2000; DOT-3T2200; DOT-3T2400; DOT-4A; DOT-4AA480; DOT-4B; DOT-4B150; DOT-4B150; DOT-4B225; DOT-4B240; DOT-4B240ET; DOT-4B300; DOT-4B400; DOT-4B480; DOT-4BA; DOT-4BA225; DOT-4BA240; DOT-4BA300; DOT-4BA400; DOT-4BW225; DOT-4BW240; DOT-4BW300; DOT-4BW400; DOT-4BW480; DOT-4DA; DOT-4DS; DOT-4E225; DOT-4E240; DOT-4L; and DOT-AAX2400;

wherein the HFC refrigerant is selected from the group consisting of R-134a, R-404A, R-407A, R-407C, R-407F, R-410A, R-417A, R-417B, R-422A, R-422B, R-422C, R-422D, R-424A, R-427A, R-428A, R-434A, R-438A, R-442A, and RS07A; and

the compatible polyol ester compressor lubricant is present in an amount of between 5% and 15% by weight of the HFC refrigerant.

10. A method for retrofitting a refrigeration system from an HCFC refrigerant mixed with a mineral oil or alkyl benzene lubricant to an HFC refrigerant, comprising:

withdrawing all of the HCFC refrigerant from the refrigeration system and removing a portion of the mineral oil or alkyl benzene lubricant through a charge port of the refrigeration system, while leaving a portion of the mineral oil or alkyl benzene lubricant within the refrigeration system in an amount of at least 5% by weight of the HCFC refrigerant;

providing a U.S. Department of Transportation compliant transport container containing an HFC refrigerant mixed with a compatible hygroscopic polyol ester compressor lubricant, in an amount of 5-20% by weight of the HFC refrigerant; and

charging the refrigeration system through the charge port with the HFC refrigerant mixed with the compatible hygroscopic polyol ester compressor lubricant, in the amount of 5-20% by weight of the HFC refrigerant.

11. The method according to claim 10 , wherein after charging the refrigeration system, the compatible hygroscopic polyol ester compressor lubricant is present in an amount of at least 10% by weight of the total weight of the compatible hygroscopic polyol ester compressor lubricant and the remaining mineral oil or alkyl benzene lubricant in the refrigeration system.

12. The method according to claim 10 , wherein the compatible hygroscopic polyol ester compressor lubricant is present in an amount of about 8% by weight of the HFC refrigerant.

13. The method according to claim 10 , wherein after charging the refrigeration system, the compatible hygroscopic polyol ester compressor lubricant is present in an amount of about 25% to 50% of the total weight of the compatible hygroscopic polyol ester compressor lubricant and the remaining mineral oil or alkyl benzene lubricant in the refrigeration system.

14. The method according to claim 10 , wherein after charging the refrigeration system, the compatible hygroscopic polyol ester compressor lubricant and the remaining mineral oil or alkyl benzene lubricant in the refrigeration system are present in an amount of 15% to 32% by weight of the HFC refrigerant.

15. The method according to claim 10 , wherein the remaining mineral oil or alkyl benzene lubricant in the refrigeration system is present in an amount of between 8% and 24% by weight of the HFC refrigerant.

16. The method according to claim 10 , wherein the HCFC refrigerant comprises R-22.

17. The method according to claim 10 , wherein the HFC refrigerant comprises difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a).

18. The method according to claim 10 , wherein the compatible hygroscopic polyol ester compressor lubricant and the remaining mineral oil or alkyl benzene lubricant in the refrigeration system are present in an amount of about 15% to 25% by weight of the HFC refrigerant.

19. The method according to claim 10 , wherein the HFC refrigerant is selected from the group consisting of R-134a, R-404A, R-407A, R-407C, R-407F, R-410A, R-417A, R-417B, R-422A, R-422B, R-422C, R-422D, R-424A, R-427A, R-428A, R-434A, R-438A, R-442A, and RS07A.

20. The method according to claim 10 , wherein the portion of the mineral oil or alkyl benzene lubricant left within the refrigeration system is at least 8% by weight of the HCFC refrigerant.

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2023
From: TCW ASSET MANAGEMENT COMPANY LLC
To: HUDSON TECHNOLOGIES, INC.
Reel/Frame 064650/0964 →
SECURITY INTEREST Recorded Mar 2, 2022
From: HUDSON TECHNOLOGIES, INC.
To: TCW ASSET MANAGEMENT COMPANY LLC, AS AGENT
Reel/Frame 059146/0131 →
RELEASE OF SECURITY INTEREST Recorded Dec 24, 2019
From: PNC BANK, NATIONAL ASSOCIATION
To: HUDSON TECHNOLOGIES, INC
Reel/Frame 051361/0803 →
SECURITY INTEREST Recorded Dec 19, 2019
From: HUDSON TECHNOLOGIES, INC.; HUDSON TECHNOLOGIES COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 051337/0590 →
SECURITY INTEREST Recorded Oct 17, 2017
From: HUDSON TECHNOLOGIES, INC.
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 043887/0250 →
SECURITY INTEREST Recorded Oct 10, 2017
From: HUDSON TECHNOLOGIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 043828/0001 →
Continuity (5)
Continuation 14877609 · Oct 7, 2015
Continuation 14744776 · Jun 19, 2015
Provisional Application 62032129 · Aug 1, 2014
Provisional Application 62017530 · Jun 26, 2014
Related Publication 20170131009A1 · May 11, 2017