IP Library Granted Patent US 9,837,564
Granted Patent B1
US 9,837,564 · App. 15/274,152 · Granted Dec 5, 2017

Actinide oxide photodiode and nuclear battery

Inventors: Milan Sykora (Los Alamos, NM); Igor Usov (Los Alamos, NM)
Assignee: Los Alamos National Security, LLC
H01L31/032H01L31/022408H01L31/103H01L31/18
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Quick Facts
Patent No.
US 9,837,564
App. No.
15/274,152
Granted
Dec 5, 2017
Kind
B1
Abstract

Photodiodes and nuclear batteries may utilize actinide oxides, such a uranium oxide. An actinide oxide photodiode may include a first actinide oxide layer and a second actinide oxide layer deposited on the first actinide oxide layer. The first actinide oxide layer may be n-doped or p-doped. The second actinide oxide layer may be p-doped when the first actinide oxide layer is n-doped, and the second actinide oxide layer may be n-doped when the first actinide oxide layer is p-doped. The first actinide oxide layer and the second actinide oxide layer may form a p/n junction therebetween. Photodiodes including actinide oxides are better light absorbers, can be used in thinner films, and are more thermally stable than silicon, germanium, and gallium arsenide.

Claims (56)

1. An apparatus, comprising:

a first actinide oxide layer;

a second actinide oxide layer deposited on the first actinide oxide layer;

a substrate located under the first actinide oxide layer;

a first electrical contact connected to the substrate; and

a second electrical contact connected to the second actinide oxide layer, wherein

the first actinide oxide layer is n-doped or p-doped,

the second actinide oxide layer is p-doped when the first actinide oxide layer is n-doped,

the second actinide oxide layer is n-doped when the first actinide oxide layer is p-doped,

the first actinide oxide layer and the second actinide oxide layer form a p/n junction therebetween,

the first electrical contact is an anode when the first actinide oxide layer is p-doped and the first electrical contact is a cathode when the first actinide oxide layer is n-doped, and

the second electrical contact is an anode when the second actinide oxide layer is p-doped and the second electrical contact is a cathode when the second actinide oxide layer is n-doped.

2. The apparatus of claim 1 , wherein the first actinide layer and the second actinide layer comprise a thin film.

3. The apparatus of claim 1 , wherein the substrate extends horizontally further than the first actinide layer in at least one direction.

4. The apparatus of claim 1 , further comprising:

an anti-reflective coating located on top of the second actinide oxide layer, wherein

the second actinide oxide layer extends horizontally further than the anti-reflective coating in at least one direction.

5. The apparatus of claim 4 , wherein

the first electrical contact is connected to a top of the substrate at a location where the substrate is not covered by the first actinide oxide layer, and

the second electrical contact is connected to a top of the second actinide oxide layer at a location where the second actinide oxide layer is not covered by the anti-reflective coating.

6. The apparatus of claim 1 , wherein an actinide in the first actinide oxide layer, the second actinide oxide layer, or both, comprises actinium (Ac), thorium (Th), protactinium (Pa), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berkelium (Bk), californium (CO, einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No), or lawrencium (Lr).

7. The apparatus of claim 1 , wherein the first actinide oxide layer, the second actinide oxide layer, or both, comprise at least two of actinium (Ac), thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berkelium (Bk), californium (Cf), einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No), or lawrencium (Lr).

8. An actinide oxide photodiode, comprising:

a first actinide oxide thin film layer; and

a second actinide oxide thin film layer deposited on the first actinide oxide layer, wherein the first actinide oxide thin film layer is n-doped or p-doped,

the second actinide oxide thin film layer is p-doped when the first actinide oxide thin film layer is n-doped,

the second actinide oxide thin film layer is n-doped when the first actinide oxide thin film layer is p-doped,

the first actinide oxide thin film layer and the second actinide oxide thin film layer form a p/n junction therebetween, and

the first actinide thin film layer comprises a recess in a top surface thereof in which the second actinide oxide thin film layer is deposited.

9. The actinide oxide photodiode of claim 8 , further comprising:

a substrate located under the first actinide oxide layer.

10. The actinide oxide photodiode of claim 9 , further comprising:

a first electrical contact connected to the substrate; and

a second electrical contact connected to the second actinide oxide layer, wherein

the first electrical contact is an anode when the first actinide oxide layer is p-doped and the first electrical contact is a cathode when the first actinide oxide layer is n-doped, and

the second electrical contact is an anode when the second actinide oxide layer is p-doped and the second electrical contact is a cathode when the second actinide oxide layer is n-doped.

11. The actinide oxide photodiode of claim 10 , further comprising:

an anti-reflective coating located on top of the second actinide oxide layer.

12. The actinide oxide photodiode of claim 11 , wherein

the first electrical contact is connected to a bottom or side of the substrate, and

the second electrical contact is connected to a top of the second actinide oxide layer underneath the anti-reflective coating.

13. The actinide oxide photodiode of claim 8 , wherein an actinide in the first actinide oxide thin film layer, the second actinide oxide thin film layer, or both, comprises actinium (Ac), thorium (Th), protactinium (Pa), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berkelium (Bk), californium (CO, einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No), or lawrencium (Lr).

14. The actinide oxide photodiode of claim 8 , wherein the first actinide oxide thin film layer, the second actinide oxide thin film layer, or both, comprise at least two of actinium (Ac), thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berkelium (Bk), californium (Cf), einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No), or lawrencium (Lr).

15. An actinide oxide photodiode, comprising:

a substrate;

a first actinide oxide thin film layer deposited on the substrate;

a second actinide oxide thin film layer deposited on the first actinide oxide layer;

a first electrical contact connected to the substrate; and

a second electrical contact connected to the second actinide oxide thin film layer, wherein the first actinide oxide thin film layer is n-doped or p-doped,

the second actinide oxide thin film layer is p-doped when the first actinide oxide thin film layer is n-doped,

the second actinide oxide thin film layer is n-doped when the first actinide oxide thin film layer is p-doped,

the first actinide oxide thin film layer and the second actinide oxide thin film layer form a p/n junction therebetween,

the first electrical contact is an anode when the first actinide oxide layer is p-doped and the first electrical contact is a cathode when the first actinide oxide layer is n-doped, and

the second electrical contact is an anode when the second actinide oxide layer is p-doped and the second electrical contact is a cathode when the second actinide oxide layer is n-doped.

16. The actinide oxide photodiode of claim 15 , wherein the first actinide thin film layer comprises a recess in a top surface thereof in which the second actinide oxide thin film layer is deposited.

17. The actinide oxide photodiode of claim 15 , wherein the first actinide oxide thin film layer, the second actinide oxide thin film layer, or both, comprise at least two of actinium (Ac), thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berkelium (Bk), californium (Cf), einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No), or lawrencium (Lr).

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2018
From: LOS ALAMOS NATIONAL SECURITY, LLC
To: TRIAD NATIONAL SECURITY, LLC
Reel/Frame 047396/0489 →
CONFIRMATORY LICENSE Recorded Dec 1, 2016
From: LOS ALAMOS NATIONAL SECURITY
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 040482/0651 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 23, 2016
From: SYKORA, MILAN, MR.; USOV, IGOR, MR.
To: LOS ALAMOS NATIONAL SECURITY, LLC
Reel/Frame 039844/0041 →
Continuity (2)
Continuation In Part 15188152 · Jun 21, 2016
Provisional Application 62191601 · Jul 13, 2015