Electrode material for lithium-ion secondary battery, electrode for lithium-ion secondary battery, and lithium-ion secondary battery
An electrode material includes inorganic particles of LiFe x Mn 1-x-y M y PO 4 and a carbonaceous film coating surfaces of the inorganic particles, and volume of micropores having micropore diameter of 2 to 10 nm is 3 to 11 cm 3 /g. A method for manufacturing an electrode material includes immersing the inorganic particles in an aqueous solution having pH of 7.0 to 10.0; producing a slurry including the inorganic particles, a carbonaceous film precursor, and water; producing a dried substance of the slurry by drying the slurry; and calcinating the dried substance in a non-oxidative atmosphere of 500° C. to 1,000° C., and an amount of the carbonaceous film precursor blended into 100 parts by mass of the inorganic particles when converted to a carbon element is 1.0 to 5.0 parts by mass. An electrode includes the electrode material. A lithium-ion secondary battery includes a cathode; an anode; and a non-aqueous electrolyte, the cathode being the electrode.
1. An electrode material for a lithium-ion secondary battery comprising:
inorganic particles represented by General Formula LiFe x Mn 1-x-y M y PO 4 (0.05≤x≤1.0, 0≤y≤0.14, here, M represents at least one element selected from Mg, Ca, Co, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, and rare earth elements); and
a carbonaceous film that coats surfaces of the inorganic particles,
wherein the electrode material for a lithium-ion secondary battery has a pore volume of 3 cm 3 /g or more and 11 cm 3 /g or less in the case of a pore diameter range of 2 nm or more and 10 nm or less.
2. The electrode material for a lithium-ion secondary battery according to claim 1 , having a carbon content of 0.5% by mass or more and 3.5% by mass or less.
3. The electrode material for a lithium-ion secondary battery according to claim 1 ,
wherein a powder resistance of the electrode material for a lithium-ion secondary battery is 1,000 Ω·cm or less, the powder resistance can be measured using a four-terminal method in which four probes are brought into contact with the surface of a compact, and the compact is obtained by injecting the electrode material into a mold, and pressing of 16 kN.
4. A method for manufacturing an electrode material for a lithium-ion secondary battery, comprising:
a step of immersing inorganic particles represented by General Formula LiFe x Mn 1-x-y M y PO 4 (0.05≤x≤1.0, 0≤y≤0.14, here, M represents at least one element selected from Mg, Ca, Co, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, and rare earth elements) in an aqueous solution having a pH of 7.6 or more and 9.2 or less;
a step of producing a slurry including the inorganic particles immersed in the aqueous solution, a carbonaceous film precursor, and water;
a step of producing a dried substance of the slurry by drying the slurry; and
a step of calcinating the dried substance in a non-oxidative atmosphere at a temperature of 500° C. or higher and 1,000° C. or lower,
wherein the carbonaceous film precursor is at least one element selected from the group consisting of glucose, fructose, galactose, mannose, maltose, sucrose, lactose, arabinose, glycogen, pectin, alginic acid, glucomannan, chitin, hyaluronic acid, chondroitin, agarose, polyethers, divalent alcohols, and trivalent alcohols,
an amount of the carbonaceous film precursor in terms of a carbon element to 100 parts by mass of the inorganic particles is 1.0 part by mass or more and 5.0 parts by mass or less; and
wherein the electrode material has a pore volume of 3 cm 3 /g or more and 11 cm 3 /g or less in the case of a pore diameter range of 2 nm or more and 10 nm or less.
5. An electrode for a lithium-ion secondary battery comprising:
the electrode material for a lithium-ion secondary battery according to claim 1 .
6. A lithium-ion secondary battery comprising:
a cathode being the electrode for a lithium-ion secondary battery according to claim 5 ;
an anode; and
a non-aqueous electrolyte.