IP Library Granted Patent US 10,126,543
Granted Patent B2
US 10,126,543 · App. 15/280,795 · Granted Nov 13, 2018

Water content of a fluid of an electrowetting element

Inventor: Romaric Mathieu Massard (Eindhoven, NL)
Assignee: Amazon Technologies, Inc.
G02B26/005B01F17/0014B01F17/0021B01F17/0028B01F17/0071B01F17/0085G09G3/348
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Quick Facts
Patent No.
US 10,126,543
App. No.
15/280,795
Granted
Nov 13, 2018
Kind
B2
Abstract

An electrowetting element comprises a first fluid and a second fluid substantially immiscible with the first fluid. Greater than or equal to 0.05 wt % and less than or equal to 15 wt % of the second fluid is water.

Claims (81)

1. An electrowetting element comprising:

a first fluid;

a second fluid substantially immiscible with the first fluid, the second fluid comprising water, wherein a wt % of the water of the second fluid is greater than or equal to 0.05 wt % and less than or equal to 15 wt %; and

a support plate comprising:

an electrode, and

a surface in contact with at least the first fluid.

2. The electrowetting element according to claim 1 , wherein the wt % of the water of the second fluid is less than or equal to a maximum equilibrium hygroscopic amount of water.

3. The electrowetting element according to claim 1 , wherein the wt % of the water of the second fluid is less than or equal to 0.5 wt %.

4. The electrowetting element according to claim 1 , wherein the first fluid comprises a dye.

5. The electrowetting element according to claim 1 , the first fluid comprising at least one of: an oil, an alkane, or a cyclic alkane.

6. The electrowetting element according to claim 5 , wherein the oil comprises silicone oil.

7. The electrowetting element according to claim 5 , wherein the alkane comprises at least one of: hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, or pentadecane.

8. The electrowetting element according to claim 5 , wherein the cyclic alkane comprises decalin.

9. The electrowetting element according to claim 1 , wherein the first fluid comprises approximately 0 wt % of water.

10. The electrowetting element according to claim 1 , wherein a balancing wt % of the second fluid does not comprise water.

11. The electrowetting element according to claim 1 , wherein a wt % of the second fluid of less than or equal to 99.95 wt % and greater than or equal to 85 wt % does not comprise water.

12. The electrowetting element according to claim 1 , wherein the second fluid comprises at least one component selected from the group consisting of:

a polyether,

a polyethylene glycol having the general formula:

wherein n is an integer,

a polyethylene glycol having the general formula:

wherein n is an integer and n=1 to 20, 1 to 15, 1 to 10, 1 to 5, or 1,

a peroxide,

a polymeric diethyl ether peroxide having the general formula:

wherein n is an integer, or

a polymeric diethyl ether peroxide having the general formula:

wherein n is an integer and n=1 to 20, 1 to 15, 1 to 10, 1 to 5, or 1, a derivative thereof, and a combination thereof.

13. The electrowetting element of claim 1 , wherein the second fluid comprises at least one component selected from the group consisting of:

a polyol, a diol, ethylene glycol, propylene glycol, ethylene glycol substituted with at least one heteroatom, propylene glycol substituted with at least one heteroatom, a triol, glycerol, butanetriol, pentanetriol, a tetraol, erythritol, a derivative thereof, and a combination thereof.

14. The electrowetting element according to claim 1 , the second fluid comprising at least one component selected from the group consisting of:

an ether, dioxalane, dimethoxymethane, 1;1-dimethoxyethylene, an amide, a polyamide, a carboxylic acid, formic acid, acetic acid, propanoic acid, glycolic acid, a heteroatom substituted carboxylic acid, a halogenated carboxylic acid, chloroacetic acid, trifluoroacetic acid, a dicarboxylic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, a tricarboxylic acid, citric acid, aconitric acid, an ester, methyl acetate, ethyl lactate, a sulphone, dimethyl sulphate, dimethyl sulphite, methylsulphonylmethane, an aldehyde, acetaldehyde, glyoxal, methylglyoxal, a peroxide, methyl ethyl ketone peroxide, oxamic acid, organosulphoxide, ethylene carbonate, propylene carbonate, diethylene glycol, a derivative thereof, and a combination thereof.

15. The electrowetting element according to claim 1 , wherein the second fluid comprises:

a first component selected from the group consisting of: ethylene glycol, diethyleneglycol, polyethylene glycol, propylene glycol, dioxalane, glyoxal, citric acid, oxalic acid, oxamic acid, and formic acid, and

a second component different from the first component and selected from the group consisting of: erythritol, ethylene carbonate, propylene carbonate, ethylene glycol, glycerol, and butanetriol.

16. The electrowetting element according to claim 15 , wherein a ratio in the second fluid of a wt % of the first component to a wt % of the second component is approximately: 90:10, 80:20, 75:25, 70:30, 65:35, 60:40, 55:45, 50:50, 45:55, 40:60, 35:65, 30:70, 25:75, 20:80, or 10:90.

17. The electrowetting element according to claim 1 , wherein the second fluid comprises at least one component each independently having a general formula comprising at least two carbon atoms and at least one oxygen atom, a ratio of the at least one oxygen atom to the at least two carbon atoms being greater than 1:2.

18. The electrowetting element according to claim 1 , wherein the second fluid has a surface tension of at least one of:

greater than 30,

greater than 35,

greater than 40, or

greater than 45 mN m −1 .

19. The electrowetting element according to claim 1 , wherein, by application of a voltage between the second fluid and the electrode, the first fluid and the second fluid are switchable between:

a first configuration with the first fluid in contact with an area of the surface; and

a second configuration with the second fluid in contact with the area of the surface.

20. A display apparatus comprising:

an electrowetting element comprising:

a first fluid;

a second fluid substantially immiscible with the first fluid, the second fluid comprising water, wherein a wt % of the water of the second fluid is greater than or equal to 0.05 wt % and less than or equal to 15 wt %; and

a support plate comprising:

an electrode, and

a surface in contact with at least the first fluid; and

a display driving system for controlling application of a voltage between the electrode and the second fluid to switch the first fluid and the second fluid between:

a first configuration with the first fluid in contact with an area of the surface, and

a second configuration with the second fluid in contact with the area of the surface.

21. The display apparatus of claim 20 , wherein the wt % of the water of the second fluid is less than or equal to a maximum equilibrium hygroscopic amount of water.

22. The display apparatus of claim 20 , wherein the wt % of the water of the second fluid is less than or equal to 0.5 wt %.

23. The display apparatus of claim 20 , wherein at least one of:

the first fluid comprises a dye;

the first fluid comprises at least one of: an oil, an alkane, or a cyclic alkane;

the first fluid comprises silicone oil;

the first fluid comprises at least one of: hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, or pentadecane; or

the first fluid comprises decalin.

24. The display apparatus of claim 20 , wherein the first fluid comprises approximately 0 wt % of water.

25. The display apparatus of claim 20 , wherein a balancing wt % of the second fluid does not comprise water.

26. The display apparatus of claim 20 , wherein a wt % of the second fluid of less than or equal to 99.95 wt % and greater than or equal to 85 wt % does not comprise water.

27. The display apparatus of claim 1 , wherein the second fluid comprises at least one component selected from the group consisting of:

a polyether, a polyethylene glycol having the general formula:

wherein n is an integer,

a polyethylene glycol having the general formula:

wherein n is an integer and n=1 to 20, 1 to 15, 1 to 10, 1 to 5, or 1,

a peroxide,

a polymeric diethyl ether peroxide having the general formula:

wherein n is an integer,

a polymeric diethyl ether peroxide having the general formula:

wherein n is an integer and n=1 to 20, 1 to 15, 1 to 10, 1 to 5, or 1, a polyol, a diol, ethylene glycol, propylene glycol, ethylene glycol substituted with at least one heteroatom, propylene glycol substituted with at least one heteroatom, a triol, glycerol, butanetriol, pentanetriol, a tetraol, erythritol, a derivative thereof, and a combination thereof.

28. The display apparatus of claim 20 , wherein the second fluid comprises:

a first component selected from the group consisting of: ethylene glycol, diethyleneglycol, polyethylene glycol, propylene glycol, dioxalane, glyoxal, citric acid, oxalic acid, oxamic acid, and formic acid, and

a second component different from the first component and selected from the group consisting of: erythritol, ethylene carbonate, propylene carbonate, ethylene glycol, glycerol, and butanetriol.

29. The display apparatus of claim 20 , the display driving system comprising:

a driver stage with an output for at least one signal to apply the voltage between the electrode and the second fluid;

a controller connected to the driver stage and configured to, in response to a data signal input to the display driving system, control the driver stage to output the at least one signal.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 9, 2018
From: MASSARD, ROMARIC
To: SAMSUNG LCD NETHERLANDS R&D CENTER B.V.
Reel/Frame 047108/0967 →
CHANGE OF NAME Recorded Oct 9, 2018
From: SAMSUNG LCD NETHERLANDS R&D CENTER B.V.
To: LIQUAVISTA B.V.
Reel/Frame 047208/0014 →
BILL OF SALE Recorded Oct 9, 2018
From: LIQUAVISTA B.V.
To: AMAZON TECHNOLOGIES, INC.
Reel/Frame 047777/0971 →
Priority Claims (1)
GB 1010296.0 · Jun 18, 2010 · national
Continuity (3)
Continuation 13718489 · Dec 18, 2012
Continuation PCTEP2011060114 · Jun 17, 2011
Related Publication 20170017073A1 · Jan 19, 2017