IP Library Granted Patent US 10,138,439
Granted Patent B2
US 10,138,439 · App. 15/281,471 · Granted Nov 27, 2018

Lubrication material using self-dispersed crumpled graphene balls as additives in oil for friction and wear reduction

Inventors: Jiaxing Huang (Wilmette, IL); Qian Wang (Mt. Prospect, IL); Yip-Wah Chung (Wilmette, IL); Xuan Dou (Evanston, IL)
Assignee: NORTHWESTERN UNIVERSITY
C10M141/12C10M125/02C10M139/04C10M2201/041C10M2203/022C10M2227/04C10N2220/082C10N2230/06
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Quick Facts
Patent No.
US 10,138,439
App. No.
15/281,471
Granted
Nov 27, 2018
Kind
B2
Abstract

A method for forming a lubrication material using self-dispersed crumpled graphene balls as additives in a lubricant base fluid for friction and wear reduction. The lubricant base fluid may be, for example, a polyalphaolefin type-4 (PAO4) oil. After the crumpled graphene balls are added as additives in the lubricant base fluid, the lubricant base fluid with the additives are sonicated for a sonicating time period, so that the crumpled graphene balls are self-dispersed in the lubricant base fluid to improve friction and wear properties of the lubricant base fluid. In some cases, a dispersing agent, such as Triethoxysilane, may be added in the lubricant base fluid to enhance stability of dispersion of the crumpled graphene balls in the lubricant base fluid. The crumpled graphene balls may stay stably dispersed in the lubricant base fluid between a lower temperature (such as −15° C.) to a higher temperature (such as 90° C.).

Claims (24)

1. A method for forming a lubrication material, the method comprising:

providing a lubricant base fluid;

adding crumpled graphene balls as additives in the lubricant base fluid;

sonicating the lubricant base fluid with the additives for a sonicating time period, so that the crumpled graphene balls are self-dispersed in the lubricant base fluid to improve friction and wear properties of the lubricant base fluid; and

adding a dispersing agent in the lubricant base fluid to enhance stability of dispersion of the crumpled graphene balls in the lubricant base fluid,

wherein the lubricant base fluid is a polyalphaolefin type-4 (PAO4) oil, and the dispersing agent is Triethoxysilane.

2. The method of claim 1 , wherein a weight percentage of the crumpled graphene balls to the lubricant base fluid is in a range between 0.01% and 0.1%.

3. The method of claim 1 , wherein the sonicating time period is about 30 minutes.

4. The method of claim 1 , wherein the crumpled graphene balls are configured to stay stably dispersed in the lubricant base fluid between a first temperature and a second temperature, wherein the first temperature is lower than a room temperature, and the second temperature is higher than the room temperature.

5. The method of claim 4 , wherein the first temperature is about −15° C. and the second temperature is about 90° C.

6. The method of claim 1 , wherein the crumpled graphene balls are formed by isotropically compressing flat graphene-based sheets suspended in nebulized aerosol droplets during a solvent evaporation process.

7. A method of providing lubrication using the lubrication material formed by the method of claim 1 .

8. A lubrication material, comprising:

a lubricant base fluid;

crumpled graphene balls being added as additives in the lubricant base fluid; and

a dispersing agent being added in the lubricant base fluid to enhance stability of dispersion of the crumpled graphene balls in the lubricant base fluid,

wherein the lubrication material is sonicated for a sonicating time period, so that the crumpled graphene balls are self-dispersed in the lubricant base fluid; and

wherein the lubricant base fluid is a polyalphaolefin type-4 (PAO4) oil, and the dispersing agent is Triethoxysilane.

9. The lubrication material of claim 8 , wherein a weight percentage of the crumpled graphene balls to the lubricant base fluid is in a range between 0.01% and 0.1%.

10. The lubrication material of claim 8 , wherein the sonicating time period is about 30 minutes.

11. The lubrication material of claim 8 , wherein the crumpled graphene balls are configured to stay stably dispersed in the lubricant base fluid between a first temperature and a second temperature, wherein the first temperature is higher than a room temperature, and the second temperature is lower than the room temperature.

12. The lubrication material of claim 11 , wherein the first temperature is about −15° C. and the second temperature is about 90° C.

13. The lubrication material of claim 8 , wherein the crumpled graphene balls are formed by isotropically compressing flat graphene-based sheets suspended in nebulized aerosol droplets during a solvent evaporation process.

14. A method of providing lubrication using the lubrication material of claim 8 .

Assignments (2)
CONFIRMATORY LICENSE Recorded Jan 6, 2020
From: NORTHWESTERN UNIVERSITY
To: NAVY, SECRETARY OF THE UNITED STATES OF AMERICA
Reel/Frame 052258/0762 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 30, 2016
From: HUANG, JIAXING; CHUNG, YIP-WAH; WANG, QIAN; DOU, XUAN
To: NORTHWESTERN UNIVERSITY
Reel/Frame 039905/0701 →
Continuity (2)
Provisional Application 62235201 · Sep 30, 2015
Related Publication 20170088788A1 · Mar 30, 2017