IP Library Granted Patent US 9,679,967
Granted Patent B1
US 9,679,967 · App. 15/282,152 · Granted Jun 13, 2017

Contact resistance reduction by III-V Ga deficient surface

Inventors: Takashi Ando (Tuckahoe, NY); Kevin K. Chan (Staten Island, NY); John Rozen (Hastings on Hudson, NY); Jeng-Bang Yau (Yorktown Heights, NY); Yu Zhu (Rye Brook, NY)
Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
H01L29/0847H01L21/0257H01L21/02241H01L21/02546H01L21/2258H01L21/266H01L21/26546H01L29/207
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Quick Facts
Patent No.
US 9,679,967
App. No.
15/282,152
Granted
Jun 13, 2017
Kind
B1
Abstract

A method for forming a semiconductor device includes forming a III-V semiconductor substrate and forming a gate structure on the III-V semiconductor substrate. The method also includes forming a thin spacer surrounding the gate structure and forming a source/drain junction with a first doped III-V material at an upper surface of the III-V semiconductor substrate. The method also includes oxidizing a surface the source/drain forming an oxidation layer; removing natural oxides from the oxidation layer on a surface of the source/drain to expose ions of the first doped material at least at a surface of the source/drain. The method further includes applying a second doping to the source/drain to increase a doping concentration of the first doped III-V material, forming metal contacts at least at the second doped surface of the source/drain; and then annealing the contact.

Claims (35)

1. A method of forming a semiconductor device, the method comprising:

forming a III-V semiconductor substrate;

forming a gate structure on the III-V semiconductor substrate;

forming a spacer surrounding the gate structure;

forming a source/drain junction with a first doped III-V material at an upper surface of the III-V semiconductor substrate;

oxidizing a surface the first doped III-V material forming an oxidation layer;

removing natural oxides from the oxidation layer on a surface of the first doped III-V material to expose ions of the first doped III-V material at least at a surface of the source/drain;

applying a second doping to the exposed ions to further increase a doping concentration of the first doped III-V material at least at a surface thereof;

forming metal contacts at least at the second doped surface of the source/drain; and

annealing the metal contacts.

2. The method according to claim 1 , further comprising forming an oxide layer on top of the source/drain.

3. The method according to claim 2 , further comprising removing a trench in the oxide layer to expose at least a portion of a surface of the first doped III-V material proximate to the oxide layer.

4. The method according to claim 2 , wherein the oxide layer is formed with SiO 2 .

5. The method according to claim 1 , wherein the oxidizing is accomplished with ozone.

6. The method according to claim 1 , wherein the removing is by HF or HCl etching.

7. The method according to claim 1 , wherein the removing is by plasma ion bombardment.

8. The method according to claim 1 , wherein the first doping is in situ.

9. The method according to claim 1 , wherein the second doping is at least one or more of plasma doping followed by annealing processing, and low temperature thermal dissociation.

10. The method according to claim 1 , wherein the doping concentration is increased by at least about 50%.

11. The method according to claim 1 , wherein the III-V semiconductor is InGaAs.

12. The method according to claim 1 wherein the nFET transistor is at least one of a planar FET, trench FET, and FINFET.

13. A method of reducing metal contact resistance in a III-V type material, the method comprising:

forming a III-V semiconductor substrate;

forming a junction with a first doped III-V material at an upper surface of the III-V semiconductor substrate;

oxidizing a surface a first doped III-V material forming an oxidation layer;

removing natural oxides from the oxidation layer on a surface of the a first doped III-V material to expose ions of the first doped III-V material;

applying a second doping to the first doped III-V material to increase a doping concentration of the first doped III-V material at least at a surface thereof and form a second doped III-V material;

forming metal contacts at least at a portion of the surface of the second doped III-V material; and

annealing the metal contacts.

14. The method according to claim 13 , wherein the oxidizing is accomplished with ozone.

15. The method according to claim 13 , wherein the removing is by HF or HCl etching.

16. The method according to claim 13 , wherein the first doping is in situ.

17. The method according to claim 13 , wherein the second doping is at least one or more of plasma doping followed by annealing processing, and low temperature thermal dissociation.

18. The method according to claim 13 , wherein the doping concentration is increased by at least about 50%.

19. The method according to claim 13 , wherein the III-V semiconductor is InGaAs.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 13, 2020
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: ELPIS TECHNOLOGIES INC.
Reel/Frame 052644/0868 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 30, 2016
From: ANDO, TAKASHI; CHAN, KEVIN K.; ROZEN, JOHN; YAU, JENG-BANG; ZHU, YU
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 039912/0163 →