Super absorbent polymer and preparation method thereof
The present invention relates to a super absorbent polymer and a preparation method thereof. The super absorbent polymer includes surface crosslinked polymer particles prepared by surface crosslinking of particles of a base resin, wherein the base resin is polymerized from a monomer composition including water-soluble ethylene-based unsaturated monomers, and a water-soluble component, wherein the water-soluble component has a ratio (dwt/d(log M)) of 0.9 or less over molecular weights (M) ranging from 100,000 to 300,000 when measured from an eluted solution after swelling the super absorbent polymer for 1 hour, and wherein the content of the water-soluble component is 5% by weight or less, based on the total weight of the super absorbent polymer, when measured after swelling the super absorbent polymer for 1 hour. The super absorbent polymer has excellent liquid permeability even when swollen without a reduction in centrifuge retention capacity or absorbency under load while having improved permeability.
1. A preparation method of a super absorbent polymer, comprising:
heating or irradiating a monomer composition to form a hydrogel polymer by polymerization, wherein the monomer composition contains water-soluble ethylene-based unsaturated monomers and a polymerization initiator;
drying the hydrogel polymer;
pulverizing the dried polymer to form particles; and
heating a mixture of the particles and a surface crosslinking solution at a temperature ranging from about 180 to about 200° C. to form surface crosslinked polymer particles of the super absorbent polymer,
wherein the surface crosslinking solution contains a surface crosslinking agent and water,
wherein the super absorbent polymer includes a water-soluble component having a ratio (dwt/d(log M)) of 0.86 or less over an entire range of molecular weight ranging from 100,000 to 300,000 when measured from an eluted solution after swelling 1 g of the super absorbent polymer in 200 ml of 0.9% NaCl solution at 25° C. for 1 hour, and
wherein the water-soluble component is present in an amount of 5% by weight or less, based on the total weight of the super absorbent polymer, when measured from an eluted solution after swelling 1 g of the super absorbent polymer in 200 ml of 0.9% NaCl solution at 25° C. for 1 hour.
2. The preparation method of claim 1 , wherein the monomer composition includes a internal crosslinking agent.
3. The preparation method of claim 2 , wherein the internal cross linking agent is present in an amount ranging from 0.1 to 0.5 wt % based on the monomer composition.