Method for manufacturing plastic substrate for electrostatic painting
A method of preparing a plastic substrate for electrostatic painting includes preparing a carbon nanotube pellet by molding carbon nanotube powder. The method also includes preparing a conductive resin composition by mixing 0.1 to 10 wt % of the carbon nanotube pellet, 0.1 to 20 wt % of carbon black, and 70 to 99 wt % of a thermoplastic polymer resin. The method further includes molding the conductive resin composition.
1. A method of preparing a plastic substrate for electrostatic painting, comprising:
(a) preparing a carbon nanotube pellet by molding carbon nanotube powder;
(b) preparing a conductive resin composition by mixing 0.1 to 10 wt % of the carbon nanotube pellet, 0.1 to 20 wt % of carbon black, and 70 to 99 wt % of a rubber-reinforced styrene-based resin; and
(c) molding the conductive resin composition by extrusion at a temperature in a range of 200° C. to 300° C.,
wherein the mixing of step (b) comprises mixing the carbon nanotube pellet and the carbon black at a weight ratio of 1.5:5 to 1.5:10.
2. The method of claim 1 , wherein, in step (a), the molding is performed by injecting the carbon nanotube powder into a rotary tablet press and applying pressure.
3. The method of claim 2 , wherein the pressure is in a range of 100 to 700 kg/cm 3 .
4. The method of claim 2 , wherein the rotary tablet press has a punch size in a range of 1 to 8 mm.
5. The method of claim 4 , wherein a turntable of the rotary tablet press has a rotational speed in a range of 10 to 60 rpm.
6. The method of claim 1 , wherein a carbon nanotube included in the carbon nanotube pellet has a diameter of 50 nm or less and a length of 100 μm or less.
7. The method of claim 6 , wherein the carbon nanotube has a bulk density in a range of 50 to 800 kg/m 3 .
8. The method of claim 1 , wherein the carbon black has a specific surface area in a range of 30 to 300 m 2 /g and a dibutyl phthalate (DBP) oil absorption amount of 600 cc/100 mg or less.
9. The method of claim 8 , wherein the carbon black has an average particle size of 100 nm or less.
10. The method of claim 1 , wherein the rubber-reinforced styrene-based resin comprises at least one of an acrylonitrile-butadiene-styrene copolymer (ABS) resin, an acrylonitrile-acrylic rubber-styrene copolymer (AAS) resin, and an acrylonitrile-ethylene propylene rubber-styrene copolymer (AES) resin.
11. The method of claim 1 , wherein, in step (c), the molding is performed by extrusion molding, injection molding, or a combination thereof.