IP Library Granted Patent US 9,845,398
Granted Patent B2
US 9,845,398 · App. 15/296,863 · Granted Dec 19, 2017

Magnetic multilayer pigment flake and coating composition

Inventors: Vladimir P. Raksha (Santa Rosa, CA); Paul T. Kohlmann (Windsor, CA); Cornelis Jan Delst (Fairfax, CA); Paul G. Coombs (Santa Rosa, CA)
Assignee: VIAVI SOLUTIONS INC.
C09D7/1225C09C1/0015C09D5/32C09D7/1291C09D11/037C09D17/004H01F1/01H01F1/0306H01F1/28C01P2004/54C01P2004/61C01P2006/42C01P2006/60C09C2200/1054C09C2210/00H01F1/26
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Quick Facts
Patent No.
US 9,845,398
App. No.
15/296,863
Filed
Oct 18, 2016
Granted
Dec 19, 2017
Kind
B2
Art Unit
1788
USPC
428/402
Abstract

The present invention provides a magnetic multilayer pigment flake and a magnetic coating composition that are relatively safe for human health and the environment. The pigment flake includes one or more magnetic layers of a magnetic alloy and one or more dielectric layers of a dielectric material. The magnetic alloy is an iron-chromium alloy or an iron-chromium-aluminum alloy, having a substantially nickel-free composition. The coating composition includes a plurality of the pigment flakes disposed in a binder medium.

Claims (27)

1. A multilayer pigment flake comprising:

one or more layers of a ferromagnetic or ferrimagnetic alloy;

one or more dielectric layers; and

a reflecting layer,

wherein the ferromagnetic or ferrimagnetic alloy is an iron-chromium alloy or an iron-chromium-aluminum alloy.

2. The multilayer pigment flake of claim 1 , wherein at least one of the iron-chromium alloy and the iron chromium-aluminum alloy have a substantially nickel free composition.

3. The multilayer pigment flake of claim 1 , wherein at least one of the one or more layers of ferromagnetic or ferromagnetic alloy is semi-transparent.

4. The multilayer pigment flake of claim 1 , wherein at least one of the one or more dielectric layers is transparent.

5. The multilayer pigment flake of claim 1 , wherein the one or more dielectric layers include a first dielectric layer that is outward of a first layer of the one or more layers of ferromagnetic or ferromagnetic alloy.

6. The multilayer pigment flake of claim 1 , wherein the one or more layers of ferromagnetic or ferromagnetic alloy include a first layer that is disposed between a first dielectric layer of the one or more dielectric layers and the reflecting layer.

7. The multilayer pigment flake of claim 1 , wherein the one or more dielectric layers include a second dielectric layer that is outward the reflecting layer.

8. The multilayer pigment flake of claim 5 , wherein the one or more layers of ferromagnetic or ferromagnetic alloy include a second layer that is disposed between a second dielectric layer of the one or more dielectric layers and the reflecting layer.

9. The multilayer pigment flake of claim 1 , wherein the reflecting layer is an opaque reflecting layer.

10. The multilayer pigment flake of claim 1 , wherein the one or more layers of ferromagnetic or ferromagnetic alloy is magnetic.

11. The multilayer pigment flake of claim 1 , wherein the one or more layers of the ferromagnetic or ferrimagnetic alloy includes a composition that comprises from about 5 wt % to about 30 wt % chromium, from about 0 wt % to about 18 wt % aluminum, and about 52 wt % to about 95 wt % of iron.

12. The multilayer pigment flake of claim 1 , wherein the one or more layers of ferromagnetic or ferrimagnetic alloy are amorphous thin-film layers.

13. The multilayer pigment flake of claim 1 , comprising an interference layer structure configured to allow the pigment flake to change color with viewing angle or angle of incident.

14. The multilayer pigment flake of claim 1 , wherein the multilayer pigment flake has a layer-thickness profile selected to optimize resonant microwave absorption.

15. The multilayer pigment flake of claim 1 , wherein the multilayer pigment flake has a size of from about 2 μm to about 20 μm.

16. The multilayer pigment flake of claim 1 , wherein the one or more dielectric layers include at least one of SiO2, Al2O3, MgF2, SiO, and ZnS.

17. The multilayer pigment flake of claim 1 , wherein the one or more dielectric layers have a thickness of from about 100 to about 5,000 nm.

18. The multilayer pigment flake of claim 1 , wherein the one or more layers of ferromagnetic or ferrimagnetic alloy have a thickness of from about 20 nm to about 1,000 nm.

19. A magnetic coating composition comprising:

a binder medium; and

a plurality of the multilayer pigment flake of claim 1 disposed in the binder medium.

20. The magnetic coating composition of claim 19 , wherein the binder medium is a high-viscosity binder medium, and wherein the magnetic coating composition is an intaglio ink.

21. The magnetic coating composition of claim 19 , wherein the binder medium includes a curable resin.

Assignments (7)
RELEASE OF SECURITY INTEREST AT REEL/FRAME 73189/0873 Recorded May 28, 2026
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: INERTIAL LABS, INC.; VIAVI SOLUTIONS INC.; VIAVI SOLUTIONS LICENSING LLC
Reel/Frame 075642/0381 →
SECURITY INTEREST Recorded Nov 14, 2025
From: VIAVI SOLUTIONS INC.; VIAVI SOLUTIONS LICENSING LLC; INERTIAL LABS, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 073571/0137 →
SECURITY AGREEMENT Recorded Oct 21, 2025
From: INERTIAL LABS, INC.; VIAVI SOLUTIONS INC.; VIAVI SOLUTIONS LICENSING LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 073189/0873 →
TERMINATIONS OF SECURITY INTEREST AT REEL 052729, FRAME 0321 Recorded Jan 5, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: VIAVI SOLUTIONS INC.; RPC PHOTONICS, INC.
Reel/Frame 058666/0639 →
SECURITY INTEREST Recorded May 21, 2020
From: VIAVI SOLUTIONS INC.; 3Z TELECOM, INC.; ACTERNA LLC; ACTERNA WG INTERNATIONAL HOLDINGS LLC; VIAVI SOLUTIONS LLC; JDSU ACTERNA HOLDINGS LLC; OPTICAL COATING LABORATORY, LLC; RPC PHOTONICS, INC.; TTC INTERNATIONAL HOLDINGS, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 052729/0321 →
CHANGE OF NAME Recorded Dec 30, 2016
From: JDS UNIPHASE CORPORATION
To: VIAVI SOLUTIONS INC.
Reel/Frame 041228/0678 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 30, 2016
From: RAKSHA, VLADIMIR P.; KOHLMANN, PAUL T.; DELST, CORNELIS JAN; COOMBS, PAUL G.
To: JDS UNIPHASE CORPORATION
Reel/Frame 040811/0619 →
Continuity (3)
Continuation 13733792 · Jan 3, 2013
Continuation In Part 12828069 · Jun 30, 2010
Related Publication 20170037264A1 · Feb 9, 2017