CATIONIC POLYMERS AND POROUS MATERIALS
According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to form mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m 2 /g and a pore volume of greater than 0.3 cm 3 /g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.
1 . A cationic polymer comprising the structure:
where A is nitrogen or phosphorus and B is nitrogen or phosphorus;
where R5 is a branched or unbranched hydrocarbon chain having a carbon chain length of from 1 to 10,000 carbon atoms;
where each of R6, R7, R8, R9, R10, R11, R12, and R13 are hydrogen atoms or hydrocarbons, and where each of the hydrocarbons optionally comprises one or more heteroatoms; and
where n is from 10 to 10,000,000.
2 . The cationic polymer of claim 1 , where A and B are nitrogen.
3 . The cationic polymer of claim 1 , further comprising one or more anions selected from Cl − , Br − , F − , I − , OH − , ½ SO 4 2− , ⅓ PO 4 3− , ½ S 2− , AlO 2 − .
4 . The cationic polymer of claim 1 , where R5 comprises a carbon chain length of from 3 to 30 carbon atoms.
5 . The cationic polymer of claim 1 , where R5 comprises a carbon chain length of from 5 to 10 carbon atoms.
6 . The cationic polymer of claim 1 , where R6, R7, R8, and R9 are hydrogen.
7 . The cationic polymer of claim 1 , where R10 is an alkyl group.
8 . The cationic polymer of claim 1 , where R10 is a methyl group.
9 . The cationic polymer of claim 1 , where R11, R12 and R13 are alkyl groups.
10 . The cationic polymer of claim 1 , where R11, R12 and R13 are methyl groups.
11 . The cationic polymer of claim 1 , where R11, R12 and R13 are ethyl groups.
12 . The cationic polymer of claim 1 , where R11, R12 and R13 are propyl groups.
13 . The cationic polymer of claim 1 , where the cationic polymer is poly(N 1 ,N 1 -diallyl-N 1 -alkyl-N 6 ,N 6 ,N 6 -trialkylalkane-1,6-diamonium halide).
14 . The cationic polymer of claim 1 , where the cationic polymer is poly(N 1 ,N 1 -diallyl-N 1 -methyl-N 6 ,N 6 ,N 6 -trimethylhexane-1,6-diamonium bromide).
15 . The cationic polymer of claim 1 , where the cationic polymer is poly(N 1 ,N 1 -diallyl-N 1 -methyl-N 6 ,N 6 ,N 6 -triethylhexane-1,6-diamonium bromide).
16 . The cationic polymer of claim 1 , where the cationic polymer is poly(N 1 ,N 1 -diallyl-N 1 -methyl-N 6 ,N 6 ,N 6 -tripropylhexane-1,6-diamonium bromide).
17 . The cationic polymer of claim 1 , where the cationic polymer is a non-surfactant.
18 . The cationic polymer of claim 1 , where the cationic polymer is utilized as a structure-directing agent to form a mesoporous zeolite.
19 . A cationic polymer comprising H-NMR peaks at one or more of:
from 0.65 ppm to 1.05 ppm;
from 1.1 ppm to 1.5 ppm;
from 1.4 ppm to 1.8 ppm;
from 2.6 ppm to 3.0 ppm; and
from 2.85 ppm to 3.25 ppm.
20 . The cationic polymer of claim 19 , where the cationic polymer comprises H-NMR peaks at:
from 0.65 ppm to 1.05 ppm;
from 1.1 ppm to 1.5 ppm;
from 1.4 ppm to 1.8 ppm;
from 2.6 ppm to 3.0 ppm; and
from 2.85 ppm to 3.25 ppm.
21 .- 80 . (canceled)