Method for synthesizing organic metal complex and organic electroluminescent element using compound synthesized by said synthesis method

1. A method for synthetizing an organic metal complex having a structure represented by Formula (1), the method comprising:

replacing substituents RX and RX′ in an organic metal complex having a structure represented by Formula (2) with substituents RB and RB′, respectively, in an organic metal complex having a structure represented by Formula (1):

wherein the ring formed by A 11 to A 16 is a benzene ring, a pyridine ring, or a pyrimidine ring;

A 11 forms a covalent bond with a central metal M;

the ring formed by B 11 to B 15 is an imidazole ring;

B 11 forms a coordination bond with the central metal M;

Ra represents a substituent and p represents an integer of 0 to 4;

Rb represents a substituent and q represents an integer of 0 to 3;

if two or more Ra's are present, Ra's may be identical to or different from one another;

if two or more Rb's are present, Rb's may be identical to or different from one another;

RB and RB′ each independently represent a hydroxy group, an amino group optionally substituted by an alkyl or aryl group, a cyano group, a pyridyl group, a pyrimidyl group, a pyrazyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a thiol group, a sulfide group, or a phosphino group optionally substituted by an alkyl or aryl group;

r represents an integer of 1 or more, r′ represents an integer of 0 or more, and p, q, r, and r′ satisfy the following relations:

0<p+r′≤4 and 1≤q+r≤3;

M represents iridium or platinum;

L represents a monoanionic bidentate ligand; and

n represents an integer of 1 to 3, m represents an integer of 0 to 2, and the sum of m and n is 2 or 3;

wherein RX and RX′ respectively represent substituents replaceable with RB and RB′, and each of RX and RX′ is a halogen atom, a sulfonyloxy group, a carboxy group, a formyl group, or a carbamoyl group;

A 11 to A 16 , B 11 to B 15 , Ra, p, Rb, q, r, r′, M, L, n, and m are the same as those defined in Formula (1); and

the positions of Ra, Rb, RB, and RB′ in Formula (1) are the same as those of Ra, Rb, RX, and RX′, respectively, in Formula (2).

2. The method for synthetizing an organic metal complex according to claim 1 , wherein each of RB and RB′ in Formula (1) represents the pyridyl group, the pyrimidyl group, the pyrazyl group, the pyrazolyl group, the imidazolyl group, the triazolyl group, the cyano group, or the thiol group.

3. The method for synthetizing an organic metal complex according to claim 2 ,

wherein RB or RB′ in Formula (1) is the cyano group.

4. The method for synthetizing an organic metal complex according to claim 1 ,

wherein the position of the substituent RB in Formula (1) is B 15 , and

the position of the substituent RX in Formula (1) is B 15 .

5. The method for synthetizing an organic metal complex according to claim 1 ,

wherein B 11 is a nitrogen atom.

6. The method for synthetizing an organic metal complex according to claim 1 , wherein the ring formed by A 11 to A 16 in Formula (1) is a benzene ring.