Polyester film and manufacturing method thereof
The present invention relates to a transfer polyester film. More particularly, the present invention relates to a transfer polyester film and a method for manufacturing the same, wherein the transfer polyester film has a coating layer with an excellent releasing property so that at the time of forming a hard coating layer in order to impart a surface gloss to an interior product, the transfer polyester film may be attached to a surface of the hard coating layer so as to allow the surface of the hard coating layer to be smoothly formed in a step of coating and curing a hard coating solution and may be removed after completely curing the hard coating layer.
1. A polyester transfer film comprising:
a base layer made of a polyester resin; and
a release coating layer stacked on one surface or both surfaces of the base layer,
wherein the release coating layer is formed by coating an aqueous coating composition including (a) a composition containing a silane coupling agent of the following Chemical Formula 1 and water, and (b) a dispersion solution containing inorganic particles on the base layer, and drying the coated composition, wherein said aqueous coating composition and said release coating layer do not include a polymer binder resin, and
wherein a pH difference between (a) the composition containing a silane coupling agent and water and (b) the dispersion solution containing inorganic particles is less than 3, and the aqueous coating composition has a pH of 8 or more or 5 or less,
wherein X is a straight-chain, branched-chain, or cyclic C 1 -C 12 hydrocarbon group having one or at least two functional groups selected from a vinyl group, an epoxy group, an amino group, a methacrylic group, an acrylic group, and a mercapto group, and R 1 to R 3 are each independently a C 1 -C 5 alkyl.
2. The polyester transfer film of claim 1 , wherein the release coating layer contains 10 to 90 wt % of the inorganic particles.
3. The polyester transfer film of claim 1 , wherein the inorganic particles have an average particle size of 10 to 200 nm and are any one or at least two inorganic particles selected from the group consisting of silica, alumina, zirconia, and titania particles.
4. The polyester transfer film of claim 1 , wherein the silane coupling agent of Chemical Formula 1 is any one or at least two selected from the group consisting of [3-(2-aminoethylamino)propyl]trimethoxysilane, N-(2-aminoethyl-3-aminopropyl)triethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, 3-acryloxypropyltrimethoxysilane, 3-acryloxypropyltriethoxysilane, 3-(meth)acryloxypropyltrimethoxysilane, 3-(meth)acryloxypropyltriethoxysilane, 3-(meth)acryloxypropyltripropoxysilane, 3-aminopropyltrimethoxysilane, and 3-aminopropyltriethoxysilane.
5. The polyester transfer film of claim 1 , wherein the aqueous coating composition further contains an alcohol based solvent.
6. The polyester transfer film of claim 1 , wherein the release coating layer is formed by an in-line coating method.
7. The polyester transfer film of claim 1 , wherein the release coating layer has a dried coating thickness of 10 to 500 nm.
8. The polyester transfer film of claim 1 , wherein the polyester transfer film has an entire thickness of 12 to 250 μm.
9. The polyester transfer film of claim 1 , wherein the number of aggregated particles having a particle size of 300 nm or more, in the coating layer of the polyester transfer film is less than 5.
10. A manufacturing method of a polyester transfer film, the manufacturing method comprising:
a) melt-extruding a polyester resin to manufacture a polyester sheet;
b) stretching the polyester sheet in a machine direction;
c) coating an aqueous coating composition including (i) a composition containing a silane coupling agent of the following Chemical Formula 1 and water, and (ii) a dispersion solution containing inorganic particles on one surface or both surfaces of the polyester sheet stretched in the machine direction to form a release coating layer and stretching the resulting coated polyester sheet in a transverse direction to give a bi-axially stretched polyester transfer film; and
d) heat-setting the bi-axially stretched polyester transfer film,
wherein the aqueous coating composition and the resulting release coating layer of c) do not include a polymer binder resin;
wherein a pH difference between (i) the composition containing a silane coupling agent and water and (ii) the dispersion solution containing inorganic particles is less than 3; and
wherein the aqueous coating composition has a pH of 8 or more or 5 or less,
wherein X is a straight-chain, branched-chain, or cyclic C 1 -C 12 hydrocarbon group having one or at least two functional groups selected from a vinyl group, an epoxy group, an amino group, a methacrylic group, an acrylic group, and a mercapto group, and R 1 to R 3 are each independently a C 1 -C 5 alkyl.
11. The manufacturing method of claim 10 , wherein the inorganic particles have an average particle size of 10 to 200 nm and are any one or at least two inorganic particles selected from the group consisting of silica, alumina, zirconia, and titania particles.
12. The manufacturing method of claim 10 , wherein the silane coupling agent of Chemical Formula 1 is any one or at least two selected from the group consisting of [3-(2-aminoethylamino)propyl]trimethoxysilane, N-(2-aminoethyl-3-aminopropyl)triethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, 3-acryloxypropyltrimethoxysilane, 3-acryloxypropyltriethoxysilane, 3-(meth)acryloxypropyltrimethoxysilane, 3-(meth)acryloxypropyltriethoxysilane, 3-(meth)acryloxypropyltripropoxysilane, 3-aminopropyltrimethoxysilane, and 3-aminopropyltriethoxysilane.
13. The manufacturing method of claim 10 , wherein the aqueous coating composition further contains an alcohol based solvent.
14. The manufacturing method of claim 10 , wherein the number of aggregated particles having a particle size of 300 nm or more, in the coating layer of the polyester transfer film, is less than 5.