Polymer composition, capstock comprising the same and a process to make such capstock
A base resin including from 30 to 70 percent by weight impact modified acrylic resin having a Tg from 60 to 150° C.; from 70 to 30 percent by weight polyvinylchloride (PVC), wherein the weight percentages of the impact modified acrylic resin and the polyvinylchloride are based on the combined weight of the impact modified acrylic resin and the polyvinylchloride; from 0.25 to 4 weight percent of anti-melding additive based on the total base resin weight; and from 0.5 weight percent to 25 weight percent colorant based on total base resin weight is provided. Also provided are capstock compositions including one or more base resins, a process for making a capstock, and capstock produced thereby.
1. A polymer composition comprising:
a base resin which comprises
from 30 to 70 weight percent (meth)acrylic resin having a Tg from 60 to 150° C.;
from 70 to 30 weight percent polyvinylchloride (PVC);
from 0.5 to 4 weight percent of anti-melding additive based on the total base resin weight; and
from 0.5 to 25 weight percent colorant based on total base resin weight;
wherein said anti-melding additive is a low density polyethylene wax having an acid number of equal to or less than 5 mg KOH/g and that is a homopolymer, or copolymer with acrylic acid, methacrylic acid, ethyl acrylate, butyl acrylate, vinyl acetate, maleic anhydride, or a combination thereof; and
wherein the (meth)acrylic resin comprises:
one or more core/shell polymers which comprise
a crosslinked core comprising between 0.1 and 4 PHM crosslinking monomer and/or graft-linking agent and a (meth)acrylate copolymer having a glass transition temperature of less than or equal to −20° C.; and
one or more, optionally crosslinked, thermoplastic shells having a Tg of equal to or greater than 60° C. wherein the total amount of the one or more shells comprises 5 to 90 wt % of the total weight of the one or more core/shell polymers.
2. The polymer composition according to claim 1 , wherein the (meth)acrylate copolymer of the crosslinked core is butyl acrylate.
3. The polymer composition according to claim 1 , wherein the thermoplastic shells comprise one or more (meth)acrylate copolymers, one or more (meth)acrylate/styrenic copolymers, one or more styrenic copolymers, or any combination thereof.
4. The polymer composition according to claim 1 , wherein the (meth)acrylic resin comprises 25 to 90% of a thermoplastic (meth)acrylic copolymer having a Tg from 60 to 150° C. blended with 75% to 10% of an impact modifier selected from the group consisting of (meth)acrylic impact modifiers.
5. A capstock composition comprising two or more polymer compositions according to claim 1 .
6. A process for making a capstock having more than one color comprising:
selecting two or more polymer compositions according to claim 1 , wherein the base resins do not comprise the same amount and/or type of colorant;
extruding the two or more polymer compositions into pellets;
mixing the two or more polymer composition pellets and extruding them to form a streaked capstock.
7. A capstock produced according to the process of claim 6 .