Cleaning blade
A cleaning blade has an elastic body formed of a urethane elastomer, and a treated surface layer formed at least at a portion which comes into contact with a contact target of the elastic body. The treated surface layer is formed through impregnating a surface portion of the elastic body with a surface treatment liquid containing a bifunctional isocyanate compound, at least one polyol, and an organic solvent; or a surface treatment liquid containing an isocyanate group-containing compound having an isocyanate group at an end thereof, which compound is a reaction product of the bifunctional isocyanate compound with the at least one polyol, and an organic solvent, and curing the surface treatment liquid. The difference between the nitrogen concentration at the surface and the nitrogen concentration in the elastic body at a depth of 0.5 mm from the surface of the treated surface layer is 0.02 to 0.15 mass %.
1. A cleaning blade, comprising:
an elastic body formed of a urethane elastomer; and
a treated surface layer formed at least at a portion which comes into contact with a contact target of the elastic body, wherein:
the treated surface layer is formed through impregnating a surface portion of the elastic body with a surface treatment liquid containing a bifunctional isocyanate compound having a molecular weight of 200 to 300, at least one polyol selected from a bifunctional polyol and a trifunctional polyol having a molecular weight of 150 or lower, and an organic solvent; or a surface treatment liquid containing an isocyanate group-containing compound having an isocyanate group at an end thereof, which compound is a reaction product of the bifunctional isocyanate compound with said at least one polyol selected from a bifunctional polyol and a trifunctional polyol, and an organic solvent, and curing the surface treatment liquid; and
a difference between a nitrogen concentration at a surface of the treated surface layer and the nitrogen concentration in the treated surface layer at a depth of 0.5 mm from the surface of the treated surface layer is 0.02 to 0.15 mass %.
2. The cleaning blade according to claim 1 , wherein the treated surface layer has a thickness of 10 μm to 100 μm.
3. The cleaning blade according to claim 2 , wherein a ratio of isocyanate groups present in the bifunctional isocyanate compound of the surface treatment liquid to hydroxyl groups present in said at least one polyol selected from the bifunctional polyol and the trifunctional polyol (NCO groups/OH groups) is 1.0 to 1.5.
4. The cleaning blade according to claim 3 , wherein:
the surface treatment liquid contains the bifunctional polyol and the trifunctional polyol, and
a ratio in functional group number of bifunctional polyol to trifunctional polyol (number of bifunctional groups/number of trifunctional groups) is 50/50 to 95/5.
5. The cleaning blade according to claim 2 , wherein:
the surface treatment liquid contains the bifunctional polyol and the trifunctional polyol, and
a ratio in functional group number of bifunctional polyol to trifunctional polyol (number of bifunctional groups/number of trifunctional groups) is 50/50 to 95/5.
6. The cleaning blade according to claim 1 , wherein a ratio of isocyanate groups present in the bifunctional isocyanate compound of the surface treatment liquid to hydroxyl groups present in said at least one polyol selected from the bifunctional polyol and the trifunctional polyol (NCO groups/OH groups) is 1.0 to 1.5.
7. The cleaning blade according to claim 6 , wherein:
the surface treatment liquid contains the bifunctional polyol and the trifunctional polyol, and
a ratio in functional group number of bifunctional polyol to trifunctional polyol (number of bifunctional groups/number of trifunctional groups) is 50/50 to 95/5.
8. The cleaning blade according to claim 1 , wherein:
the surface treatment liquid contains the bifunctional polyol and the trifunctional polyol, and
a ratio in functional group number of bifunctional polyol to trifunctional polyol (number of bifunctional groups/number of trifunctional groups) is 50/50 to 95/5.