CERAMIC COMPOSITIONS
A dried or at least partially dried ceramic feedstock, a method of preparing a dried or at least partially dried ceramic feedstock having a residual solvent content of up to about 15 wt. %, ceramic formulations comprising one or more ceramic precursors, temperature sensitive gelling agent, solvent, and having a viscosity suitable for low pressure injection molding, methods for preparing said ceramic formulations, a method of forming a ceramic article from said ceramic formulations, and a ceramic article obtainable therefrom.
1 . A ceramic formulation comprising one or more ceramic precursors, a temperature sensitive gelling agent, and a solvent, wherein the ceramic formulation has a solids concentration of at least 50 vol. % and a viscosity of not more than 10 Pa·s at a shear rate of 100 s −1 at a temperature greater than the gel point of the gelling agent.
2 . A ceramic feedstock comprising one or more ceramic precursors and a temperature sensitive gelling agent, wherein the ceramic feedstock is dried or at least partially dried and has a solvent content of up to about 15 wt. %, based on the total weight of the ceramic feedstock.
3 . A ceramic feedstock according to claim 2 , wherein the feedstock is obtainable by a method comprising:
preparing, obtaining or providing a ceramic slurry comprising one or more ceramic precursors, a temperature sensitive gelling agent, and a solvent; and
treating the ceramic slurry to obtain a dried or at least partially dried ceramic feedstock having a residual solvent content of up to about 15 wt. %, based on the total weight of the ceramic feedstock.
4 . A ceramic feedstock according to claim 2 in powder, granulated or pelletized form.
5 . (canceled)
6 . (canceled)
7 . A ceramic feedstock according to claim 3 , wherein the ceramic slurry is prepared by a process comprising:
mixing the one or more ceramic precursors with solvent and heating;
separately dissolving gelling agent in solvent; and
mixing the one or more ceramic precursors with solvent with the dissolved gelling agent.
8 . A ceramic feedstock according to claim 3 , wherein treating the ceramic slurry comprises:
(i) cooling the ceramic slurry to below the gel point of the gelling agent, shredding the resultant cooled ceramic gelled material, drying and milling the shredded cooled ceramic gelled material; or
(ii) spray drying the ceramic slurry.
9 . (canceled)
10 . A method of making a ceramic formulation in accordance with claim 1 , comprising:
providing at least one pre-dispersed ceramic precursor;
providing a solution or suspension comprising a solvent and at least one pre-dispersed temperature sensitive gelling agent; and
admixing the at least one pre-dispersed ceramic precursor and the solution or suspension to form the ceramic formulation.
11 . The method of claim 10 , wherein the at least one dispersed ceramic precursor is provided in a dry or partially dry form.
12 . (canceled)
13 . The method according to claim 10 , further comprising heating the solution or suspension to a temperature that is above the gel point of the gelling agent and not greater than about 100° C., prior to admixing with the at least one pre-dispersed ceramic precursor.
14 . (canceled)
15 . A method of forming a ceramic article, said method comprising:
forming a green gelled ceramic body from a ceramic formulation comprising one or more ceramic precursors, a temperature sensitive gelling agent, and a solvent and having a solids concentration of at least 50 vol. %,
and
firing the green gelled ceramic body to form a sintered ceramic article.
16 . A method according to claim 15 , further comprising preparing a ceramic formulation in accordance with the method of claim 10 .
17 . A method according to claim 15 , wherein forming comprises low pressure injection molding the ceramic formulation and cooling the molded formulation to below the gel point of the gelling agent, the injection molding is carried out at a gauge pressure of less than about 10 bars, and wherein the ceramic formulation is at a temperature of no greater than about 80° C. during injection molding.
18 . (canceled)
19 . (canceled)
20 . A ceramic feedstock according to claim 1 , wherein the temperature sensitive gelling agent is selected from one or more of a polysaccharide, gelatin, a polyoside, a poloxamer and mixtures thereof.
21 . A ceramic feedstock according to claim 20 , wherein the temperature sensitive gelling agent is a polysaccharide or a mixture of polysaccharides.
22 . A ceramic feedstock according to claim 21 , wherein the polysaccharide is selected from one or more of agar, agarose, and arabic gum.
23 . A ceramic feedstock according to claim 1 , wherein the temperature sensitive additive has a gel point of less than about 60° C.
24 . A ceramic feedstock according to claim 1 , further comprising dispersant and/or reinforcing additive and/or binder other than the gelling agent.
25 . A ceramic feedstock according to claim 24 , wherein the dispersant is selected from the group consisting of sulfonated naphthalene formaldehyde condensate (SNFC), polyelectrolytes such as polycarboxylic acids, polyacrylates and copolymers containing polyacrylate species, especially polyacrylate salts (e.g., sodium and aluminium optionally with a group II metal salt), polyphosphonates, sodium hexametaphosphates, non-ionic polyol, polyphosphoric acid, condensed sodium phosphate, non-ionic surfactants, and alkanolamines.
26 . A ceramic feedstock according to claim 24 , wherein the reinforcing additive is a monosaccharide or a polysaccharide other than the temperature sensitive gelling agent.
27 . A ceramic feedstock according to claim 1 , wherein the one or more ceramic precursors are suitable for manufacturing ceramics selected from tableware, sanitary ware, porcelain statues or decorative figurines, kiln furniture, refractory materials and technical grade ceramics.
28 . A ceramic feedstock according to claim 1 , wherein the one or more ceramic precursors are selected from alumina, aluminosilicate, nepheline syenite, feldspar, talc, mica, quartz, silica, titania, zirconia, zirconia silicate, wollastonite, perlite, diatomaceous earth, an alkaline earth metal carbonate or sulphate, such as calcium carbonate, magnesium carbonate, dolomite, and gypsum, a carbide such as silicon carbide, boron carbide, tungsten carbide and titanium carbide, boron nitride, silicon nitride, a silicide such as nickel silicide, sodium silicide, magnesium silicide, platinum silicide, titanium silicide, tungsten silicide, ceria, yttrium oxide, ferrite such as zinc-iron ferrite, barium ferrite, strontium ferrite, garnet such as yttrium-aluminium garnet, titanate such as barium titanate, lead titanate, graphite, other carbon based ceramic precursor materials, and combinations thereof.
29 . A ceramic feedstock according to claim 1 , wherein the solvent is an aqueous solvent.