Process for preparing polyurea microcapsules with improved deposition
The present invention relates to a process for producing perfume- or flavor-containing polyurea microcapsules with improved deposition of encapsulated actives on targeted surfaces such as fiber, hair and skin, which can be used in home or personal care products, as well as to microcapsules obtainable by such a process and consumer products comprising these microcapsules.
1. A process for the preparation of core-shell microcapsules comprising the following steps:
a) dissolving at least one polyisocyanate having at least two isocyanate groups, in a perfume to form an oil phase;
b) dispersing the oil phase obtained in step a) into an aqueous solution comprising an emulsifier to form an oil-in-water emulsion;
c) adding, sequentially, to the oil-in-water emulsion obtained in step b) a polymeric cross-linker bearing amino groups with a molecular weight equal or higher than 2 000 g/mol chosen from the group consisting of a polyvinylamine, a polyethyleneimine, a polyaminoethylacrylate and mixtures thereof, followed by a polyamine with a molecular weight lower than 250 g/mol selected from the group consisting of 1,2-diaminopropane, 1,2-diaminoethane, diethylenetriamine, guanidine, water soluble guanidine salts, tris-(2-aminoethy)amine, N,N,N′,N′-tetrakis(3-aminopropyl)-1,4-butanediamine, N,N′-bis(3-aminopropyl)-ethylenediamine, and 3,5-diamino-1,2,4-triazole, to form a microcapsule slurry.
2. The process according to claim 1 , wherein the polymeric cross-linker bearing amino groups has a molecular weight that is either higher than 50 000 g/mol or higher than 200 000 g/mol.
3. The process according to claim 1 , wherein the polymeric cross-linker bearing amino groups and the emulsifier are used in a weight ratio based on dry matter that is either between 0.1 and 10 or between 0.5 and 2.
4. The process according to claim 1 , wherein at least one polyisocyanate is selected from the group consisting of a polyisocyanurate of toluene diisocyanate, a trimethylol propane-adduct of toluene diisocyanate, a trimethylol propane-adduct of xylylene diisocyanate, a trimer of hexamethylene diisocyanate, a trimer of isophorone diisocyanate, a trimethylol propane-adduct of hexamethylene diisocyanate, a biuret of hexamethylene diisocyanate and mixtures thereof.
5. The process according to claim 1 , wherein the at least one polyisocyanate is used in an amount comprised between 2 and 20% by weight, relative to the total weight of the oil phase obtained in step a).
6. The process according to claim 1 , wherein the emulsifier is selected from the group consisting of polyvinyl alcohol, a cellulose derivative, polyethylene oxide, a copolymer of polyethylene oxide and polyethylene or polypropylene oxide, a copolymer of acrylamide and acrylic acid, a copolymer of vinylpyrrolidone and a quaternized vinylimidazol, and sodium dodecyl sulfate.
7. The process according to claim 1 , wherein the concentration of perfume is comprised between 10% and 60% by weight relative to the total weight of the microcapsule slurry.
8. The process according to claim 1 which further comprises recovering microcapsules from the microcapsule slurry.
9. The process according to claim 8 , wherein the ratio between the average size of the microcapsules to the average droplet size of the emulsion obtained in step b) is comprised between 1.1 and 25 or between 1.1 and 10.
10. The process according to claim 8 , which further comprises including the microcapsules in a perfuming composition comprising:
at least one ingredient selected from the group consisting of a perfumery carrier, a perfuming co-ingredient and mixtures thereof; and
optionally, at least one perfumery adjuvant.
11. The process according to claim 8 , which further comprises including the microcapsules in a perfuming consumer product as a perfuming ingredient.
12. The process according to claim 11 , wherein the perfuming consumer product is provided in the form of a fine perfume, a cologne, an after-shave lotion, a liquid or solid detergent, a fabric softener, a fabric refresher, an ironing water, a paper, a bleach, a shampoo, a hair conditioner, a coloring preparation, a hair spray, a vanishing cream, a deodorant or antiperspirant, a perfumed soap, a shower or bath mousse, an oil or gel, a hygiene product, an air freshener, a “ready to use” powdered air freshener, a wipe, a dish detergent, a hard-surface detergent, an animal litter, a diaper, a sanitary napkin, a liner or a wipe.
13. The process according to claim 8 , which further comprises including the microcapsules in a consumer product, wherein the microcapsules extend fragrance release of the perfume when the consumer product contacts a surface.
14. The process according to claim 13 , wherein the consumer product is for skin, hair or fiber.