Method for analyzing molecular weight of the poly-p-phenylene terephthalamide
View Patent ↗A method for analyzing molecular weight of the poly-p-phenylene terephthalamide (PPTA) utilizing near infrared spectrum is provided for reducing the time required to analyze the molecular weight of PPTA. The method uses PPTA samples to build a spectrum-viscosity fitting curve. The molecular weight of an unknown PPTA is analyzed via a near infrared analysis software and the spectrum-viscosity fitting curve. The method is beneficial in that it has a short process time and high reliability.
1. A method for analyzing molecular weight of the poly-p-phenylene terephthalamide (PPTA) utilizing near infrared spectrum, comprising the following steps:
(a) preparing 60˜90PPTA samples with different molecular weight, wherein the viscosity of said PPTA samples ranges from 1 to 9 dL/g;
(b) dissolving respectively said PPTA samples in a concentrated sulfuric acid and detecting the viscosity thereof by an Ubbelohde viscometer;
(c) scanning respectively each of said PPTA samples 1˜10 times using a near infrared spectrometer to obtain corresponding spectral data thereof, and calculating an average spectral data of said spectral values;
(d) extrapolating a spectrum data-viscosity fitting curve from said viscosity data of step (b) and said spectrum data of the step (c) via a near infrared analysis software; and
(e) scanning an unknown PPTA resin using said near infrared spectrometer to obtain a near infrared spectrum data and calculating the viscosity of said unknown PPTA by said spectrum-viscosity fitting curve.