OLED light-emitting device with silver nanolayer, and production method thereof
This disclosure provides an OLED light-emitting device, a production method thereof as well as a display apparatus, and relates to the technical field of OLED display, which can enhance the internal quantum efficiency of a blue OLED light-emitting device. This OLED light-emitting device comprises a substrate, and an anode, a hole transport layer, a blue light-emitting layer and a cathode provided on the substrate; the OLED light-emitting device further comprises an Ag nanolayer located between the anode and the hole transport layer; wherein the blue light-emitting layer is a blue phosphorescent light-emitting layer; the absorption spectrum of the Ag nanolayer overlaps the emission spectrum of the blue phosphorescent light-emitting layer, and the blue phosphorescent light-emitting layer is located within the penetration depth of surface plasma of Ag nanoparticles in the Ag nanolayer. It is used in the production of a blue OLED light-emitting device and a display apparatus comprising the same.
1. An OLED light-emitting device, comprising a substrate, and an anode, a hole transport layer, a blue light-emitting layer and a cathode provided on the substrate; wherein:
the OLED light-emitting device further comprises an Ag nanolayer located between the anode and the hole transport layer and the Ag nanolayer directly contacts the anode;
the blue light-emitting layer is a blue phosphorescent light-emitting layer;
the absorption spectrum of the Ag nanolayer overlaps the emission spectrum of the blue phosphorescent light-emitting layer, and the blue phosphorescent light-emitting layer is located within the penetration depth of surface plasma of Ag nanoparticles in the Ag nanolayer, and
the hole transport layer has a thickness between 1100 and 1300 nm, and the Ag nanoparticles have a diameter between 15 and 30 nm.
2. The OLED light-emitting device according to claim 1 , wherein:
the anode is opaque, and the cathode is semi-transparent.
3. The OLED light-emitting device according to claim 2 , wherein:
the OLED light-emitting device further comprises a covering layer located on a side of the cathode away from the substrate, wherein the covering layer has a refractive index between 1.8 and 2.0.
4. The OLED light-emitting device according to claim 1 , wherein:
the Ag nanolayer has a thickness between 15 and 60 nm.
5. The OLED light-emitting device according to claim 1 , wherein:
the blue phosphorescent light-emitting layer has a thickness between 20 and 40 nm.
6. The OLED light-emitting device according to claim 1 , wherein:
the OLED light-emitting device further comprises an electron transport layer located between the cathode and the blue phosphorescent light-emitting layer.
7. The OLED light-emitting device according to claim 1 , wherein:
the OLED light-emitting device further comprises a hole injection layer located between the anode and the hole transport layer; and
the Ag nanolayer is located between the hole injection layer and the hole transport layer, or the Ag nanolayer is located between the anode and the hole injection layer.
8. A display apparatus comprising the OLED light-emitting device of claim 1 .
9. The display apparatus according to claim 8 , wherein the display apparatus further comprises a thin film transistor electrically connected to the anode of the OLED light-emitting device.
10. A production method for an OLED light-emitting device, comprising forming an anode, a hole transport layer, a blue light-emitting layer, and a cathode on a substrate; and forming an Ag nanolayer between the anode and the hole transport layer, wherein the Ag nanolayer directly contacts the anode; wherein:
the blue light-emitting layer is a blue phosphorescent light-emitting layer;
the absorption spectrum of the Ag nanolayer overlaps the emission spectrum of the blue phosphorescent light-emitting layer, and the blue phosphorescent light-emitting layer is located within the penetration depth of surface plasma of Ag nanoparticles in the Ag nanolayer;
the hole transport layer, which has a thickness between 1100 and 1300 nm, is formed by an evaporation method; and
the Ag nanoparticles have a diameter between 15 and 30 nm.
11. The method according to claim 10 , wherein:
the Ag nanoparticles having a diameter of 15-30 nm are synthesized by a Liquid-Solid-Solution chemical synthesis method; and
the Ag nanolayer is formed by spin-coating an organic solvent comprising the Ag nanoparticles.
12. The method according to claim 10 , wherein:
the Ag nanolayer has a thickness between 15 and 60 nm.
13. The method according to claim 10 , wherein:
the anode is opaque, and the cathode is semi-transparent.
14. The display apparatus according to claim 8 , wherein the anode is opaque, and the cathode is semi-transparent.
15. The display apparatus according to claim 8 , wherein the OLED light-emitting device further comprises a covering layer located on a side of the cathode away from the substrate, wherein the covering layer has a refractive index between 1.8 and 2.0.
16. The display apparatus according to claim 8 , wherein the OLED light-emitting device further comprises an electron transport layer located between the cathode and the blue phosphorescent light-emitting layer.
17. The display apparatus according to claim 8 , wherein:
the OLED light-emitting device further comprises a hole injection layer located between the anode and the hole transport layer; and
the Ag nanolayer is located between the hole injection layer and the hole transport layer, or the Ag nanolayer is located between the anode and the hole injection layer.