Composition for non-aqueous secondary battery functional layer, functional layer-equipped substrate for non-aqueous secondary battery, method for producing laminate for non-aqueous secondary battery, and non-aqueous secondary battery
Provided is a composition for a non-aqueous secondary battery functional layer capable of forming a functional layer for a non-aqueous secondary battery that can provide a battery component with high blocking resistance and cause excellent adhesiveness to be displayed before and after immersion in electrolysis solution. The composition contains a particulate polymer having a core-shell structure including a core portion and a shell portion partially covering an outer surface thereof. The core portion is formed by a polymer having a glass transition temperature of −50° C. to 60° C. and a degree of swelling in electrolysis solution of at least a factor of 5 and no greater than a factor of 30. The shell portion is formed by a polymer having a glass transition temperature of 50° C. to 200° C. and a degree of swelling in electrolysis solution of greater than a factor of 1 and no greater than a factor of 4.
1. A composition for a non-aqueous secondary battery functional layer comprising
a particulate polymer, wherein
the particulate polymer has a core-shell structure including a core portion and a shell portion that partially covers an outer surface of the core portion,
the core portion is formed by a polymer having a glass transition temperature of at least −50° C. and no higher than 60° C. and a degree of swelling in electrolysis solution of at least a factor of 5 and no greater than a factor of 30, and
the shell portion is formed by a polymer having a glass transition temperature of at least 50° C. and no higher than 200° C. and a degree of swelling in electrolysis solution of greater than a factor of 1 and no greater than a factor of 4.
2. The composition for a non-aqueous secondary battery functional layer of claim 1 , wherein
the glass transition temperature of the polymer forming the core portion of the particulate polymer is lower than the glass transition temperature of the polymer forming the shell portion of the particulate polymer.
3. A functional layer-equipped substrate for a non-aqueous secondary battery comprising:
a substrate; and
a functional layer formed on the substrate, wherein
the functional layer is formed by using the composition for a non-aqueous secondary battery functional layer of claim 1 .
4. The functional layer-equipped substrate for a non-aqueous secondary battery of claim 3 , wherein
the substrate is a separator substrate or an electrode substrate.
5. A method for producing a laminate for a non-aqueous secondary battery in which a separator substrate, a functional layer, and an electrode substrate are laminated, the method comprising:
laminating the separator substrate and the electrode substrate with the functional layer in-between; and
heating the functional layer such as to cause adhesion, through the functional layer, of the separator substrate and the electrode substrate that have been laminated, wherein
the functional layer is formed by using the composition for a non-aqueous secondary battery functional layer of claim 1 .
6. The method for producing a laminate for a non-aqueous secondary battery of claim 5 , wherein
the glass transition temperature of the polymer forming the core portion of the particulate polymer is lower than the glass transition temperature of the polymer forming the shell portion of the particulate polymer, and
the heating of the functional layer is performed to a temperature that is at least as high as the glass transition temperature of the polymer forming the core portion of the particulate polymer and lower than the glass transition temperature of the polymer forming the shell portion of the particulate polymer.
7. A non-aqueous secondary battery comprising
a laminate for a non-aqueous secondary battery that is producible by the method for producing a laminate for a non-aqueous secondary battery of claim 5 .