Binders for flooring adhesives
The present invention relates to a polymer dispersion comprising A) at least one first phase comprising a) at least one chain growth addition polymer P constructed from 1 to 99.9 wt % of at least one ester from ethylenically unsaturated monomers, as monomer A, 0 to 20 wt % of at least one ethylenically unsaturated carbonitrile, as monomer B, 0.1 to 5 wt % of at least one acid-functional ethylenically unsaturated monomer, as monomer C, 0 to 5 wt % of at least one monomer which, alone or with a crosslinking agent, has crosslinking effect and which is different from the monomers A to C, as monomer D, 0 to 20 wt % of at least one ethylenically unsaturated monomer which forms a chain growth addition homopolymer having a glass transition temperature ≥50° C. and which is different from the monomers A to D, as monomer E, the sum of the total amount of the monomers A to E making 100 wt %, a1) optionally at least one polymer seed, b) 10 to 60 parts by weight, based on 100 parts by weight of polymer P, of at least one saccharide compound S, and B) a second phase comprising c) at least one solvent. The present invention also relates to a method for producing the polymer dispersion of the invention, to a polymerization powder, to an adhesive bonding formulation comprising the polymer dispersion of the invention, and to the use of the formulation of the invention as an adhesive.
1. A polymer dispersion, comprising:
A) at least one first phase, comprising:
a) at least one chain growth addition polymer P, having a glass transition temperature Tg of ≤−10° C. and being solely constructed from
1 to 99.9 wt % of at least one ester from ethylenically unsaturated monomers, as monomer A,
0 to 20 wt % of at least one ethylenically unsaturated carbonitrile, as monomer B,
0.1 to 5 wt % of at least one acid-functional ethylenically unsaturated monomer, as monomer C,
0 to 5 wt % of at least one monomer which, alone or with a crosslinking agent, has crosslinking effect and which is different from the monomers A to C, as monomer D,
0 to 20 wt % of at least one ethylenically unsaturated monomer which forms a chain growth addition homopolymer having a glass transition temperature ≥50° C. and which is different from the monomers A to D, as monomer E, selected from the group consisting of styrene, α-methylstyrene, o- or p-vinyltoluene, p-acetoxystyrene, p-bromostyrene, p-tert-butylstyrene, o-, m-, or p-chlorostyrene, methyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, ethyl methacrylate, isobutyl methacrylate, cyclohexyl methacrylate, tert-butyl vinyl ether, and cyclohexyl vinyl ether,
the sum of the total amount of the monomers A to E making 100 wt %,
a1) optionally at least one polymer seed,
b) 10 to 60 parts by weight, based on 100 parts by weight of polymer P, of at least one saccharide compound S, and
B) a second phase comprising at least one solvent.
2. The polymer dispersion according to claim 1 , which is an aqueous polymer dispersion.
3. The polymer dispersion according to claim 1 , wherein the monomer B is acrylonitrile and/or methacrylonitrile.
4. The polymer dispersion according to claim 1 , wherein the saccharide compound S is at least one member selected from the group consisting of starch, cellulose, guaran, xanthan, alginate, pectin, chitosan, gum arabic, and gellan.
5. The polymer dispersion according to claim 1 , wherein saccharide compound S is a starch, starch derivative and/or a substitution product thereof.
6. The polymer dispersion according to claim 1 , wherein the saccharide compound S has a DE (dextrose equivalent) value in a range from 1 to 40.
7. The polymer dispersion according to claim 1 , wherein the saccharide compound S is maltodextrin.
8. A chain growth addition polymer powder obtained by drying the polymer dispersion according to claim 1 .
9. An aqueous formulation for adhesive bonding, comprising:
i) the polymer dispersion according to claim 1 as binder, the formulation having a solids content originating from the polymer dispersion or from the polymer powder of 5 to 90 wt %, based on the total solids content of the formulation.
10. The formulation according to claim 9 , further comprising ii) at least one filler.
11. The formulation according to claim 10 , wherein the filler is calcium carbonate having an average particle diameter of 2 to 50 μm or is finely ground quartz having an average particle diameter of 3 to 50 μm, or is a combination of the two substances.
12. The formulation according to claim 9 , further comprising iii) at least one tackifier.
13. An aqueous formulation for adhesive bonding, comprising:
i) the chain growth addition polymer powder according to claim 8 , as binder, the formulation having a solids content originating from the polymer dispersion or from the polymer powder of 5 to 90 wt %, based on the total solids content of the formulation.
14. A polymer dispersion, comprising: A) at least one first phase, comprising: a) at least one chain growth addition polymer P solely constructed from 1 to 99.9 wt % of at least one ester from ethylenically unsaturated monomers, as monomers A, 0 to 20 wt % of at least one ethylenically unsaturated carbonitrile, as monomer B, 0.1 to 5 wt % of at least one acid-functional ethylenically unsaturated monomer, as monomer C, 0 to 5 wt % of at least one monomer which, alone or with a crosslinking agent, has crosslinking effect and which is different from the monomers A to C, as monomer D, 0 to 20 wt % of at least one ethylenically unsaturated monomer which forms a chain growth addition homopolymer having a glass transition temperature ≥50° C. and which is different from the monomers A to D, as monomer E, selected from the group consisting of styrene, α-methylstyrene, o- or p-vinyltoluene, p-acetoxystyrene, p-bromostyrene, p-tert-butylstyrene, o-, m-, or p-chlorostyrene, methyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, ethyl methacrylate, isobutyl methacrylate, cyclohexyl methacrylate, tert-butyl vinyl ether, and cyclohexyl vinyl ether, the sum of the total amount of the monomers A to E making 100 wt %, a1) optionally at least one polymer seed, b) 10 to 60 parts by weight, based on 100 parts by weight of polymer P, of at least one saccharide compound S, and B) a second phase comprising at least one solvent, wherein the polymer dispersion comprising 45 to 400 parts by weight of solvent, based on 100 parts by weight of chain growth addition polymer P.
15. A chain growth addition polymer powder obtained by drying the polymer dispersion according to claim 14 .
16. An aqueous formulation for adhesive bonding, comprising:
i) the polymer dispersion according to claim 14 as binder, the formulation having a solids content originating from the polymer dispersion or from the polymer powder of 5 to 90 wt %, based on the total solids content of the formulation.
17. An aqueous formulation for adhesive bonding, comprising:
i) the chain growth addition polymer powder according to claim 15 , as binder, the formulation having a solids content originating from the polymer dispersion or from the polymer powder of 5 to 90 wt %, based on the total solids content of the formulation.
18. A method for producing a polymer dispersion according to claim 1 , the method comprising:
I) providing at least one first phase, comprising:
at least one chain growth addition polymer P solely constructed from
1 to 99.9 wt % of at least one ester from ethylenically unsaturated monomers, as monomer A,
0 to 20 wt % of at least one ethylenically unsaturated carbonitrile, as monomer B,
0.1 to 5 wt % of at least one acid-functional ethylenically unsaturated monomer, as monomer C,
0 to 5 wt % of at least one monomer which, alone or with a crosslinking agent, has crosslinking effect and which is different from the monomers A to C, as monomer D,
0 to 20 wt % of at least one ethylenically unsaturated monomer which forms a chain growth addition homopolymer having a glass transition temperature ≥50° C. and which is different from the monomers A to D, as monomer E, selected from the group consisting of styrene, α-methylstyrene, o- or p-vinyltoluene, p-acetoxystyrene, p-bromostyrene, p-tert-butylstyrene, o-, m-, or p-chlorostyrene, methyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, ethyl methacrylate, isobutyl methacrylate, cyclohexyl methacrylate, tert-butyl vinyl ether, and cyclohexyl vinyl ether,
the sum of the total amount of the monomers A to E making 100 wt %,
a1) optionally at least one polymer seed,
b) 10 to 60 parts by weight, based on 100 parts by weight of polymer P, of at least one saccharide compound S, and
II) providing a second phase comprising at least one solvent.