Method for producing lithium carbonate
The present invention provides a method for producing lithium carbonate, that can shorten the time required in the production of lithium carbonate and has excellent maintenance property and production efficiency without forming fixed matters that require complicated procedures to remove in a reaction apparatus.
1. A method for producing lithium carbonate, the method comprising:
mixing water, ammonia and carbon dioxide gas to form an ammonium carbonate aqueous solution;
mixing lithium chloride brine with the ammonium carbonate aqueous solution to conduct a carbonation reaction; and
recovering a solid formed after the carbonation reaction through solid-liquid separation,
wherein, as the carbon dioxide gas, carbon dioxide gas produced by thermally decomposing limestone is used, and
as the ammonia, regenerated ammonia obtained by reacting ammonium chloride by-produced during the carbonation reaction with quicklime by-produced during the production of the carbon dioxide gas or slaked lime obtained by hydrating the quicklime is used.
2. A method for producing lithium carbonate, the method comprising:
mixing water, ammonia and carbon dioxide gas to form an ammonium carbonate aqueous solution;
mixing a part divided from the ammonium carbonate aqueous solution with lithium chloride brine to conduct a primary carbonation reaction, thereby depositing magnesium carbonate, followed by conducting solid-liquid separation;
mixing the residual ammonium carbonate aqueous solution with liquid obtained after the solid-liquid separation to conduct a secondary carbonation reaction; and
recovering a solid formed after the carbonation reaction through solid-liquid separation,
wherein, as the carbon dioxide gas, carbon dioxide gas produced by thermally decomposing limestone is used, and
as the ammonia, regenerated ammonia obtained by reacting ammonium chloride by-produced during the carbonation reaction with quicklime by-produced during the production of the carbon dioxide gas or slaked lime obtained by hydrating the quicklime is used.
3. The method for producing lithium carbonate according to claim 1 , wherein the reaction for forming the ammonium carbonate aqueous solution by mixing water, ammonia and carbon dioxide gas is conducted using a vertically long absorption tower equipped with a member for improving gas-liquid contact efficiency in an inside thereof, in which water was supplied from a top of the absorption tower, and ammonia and carbon dioxide gas are supplied from a bottom of the absorption tower.
4. The method for producing lithium carbonate according to claim 1 , wherein the regenerated ammonia is obtained using an ammonia recovery apparatus comprising a vertically long stripping tower equipped with a member for improving gas-liquid contact efficiency in an inside thereof and a decomposition reaction tank for taking out an ammonium chloride-containing reaction residual liquid in the stripping tower and conducting decomposition reaction of ammonium chloride, in which the reaction residual liquid is supplied to a top of the stripping tower, the reaction residual liquid is taken out from a central part of the stripping tower, ammonium chloride is decomposed in the decomposition reaction tank, a decomposition residual liquid having dissolved therein ammonia formed is returned to the central part of the stripping tower, steam is supplied to a bottom of the stripping tower, simultaneously regenerated ammonia is recovered from the top of the stripping tower, and a residual liquid containing a calcium component is discharged from the bottom of the stripping tower.
5. The method for producing lithium carbonate according to claim 2 , wherein the reaction for forming the ammonium carbonate aqueous solution by mixing water, ammonia and carbon dioxide gas is conducted using a vertically long absorption tower equipped with a member for improving gas-liquid contact efficiency in an inside thereof, in which water was supplied from a top of the absorption tower, and ammonia and carbon dioxide gas are supplied from a bottom of the absorption tower.
6. The method for producing lithium carbonate according to claim 2 , wherein the regenerated ammonia is obtained using an ammonia recovery apparatus comprising a vertically long stripping tower equipped with a member for improving gas-liquid contact efficiency in an inside thereof and a decomposition reaction tank for taking out an ammonium chloride-containing reaction residual liquid in the stripping tower and conducting decomposition reaction of ammonium chloride, in which the reaction residual liquid is supplied to a top of the stripping tower, the reaction residual liquid is taken out from a central part of the stripping tower, ammonium chloride is decomposed in the decomposition reaction tank, a decomposition residual liquid having dissolved therein ammonia formed is returned to the central part of the stripping tower, steam is supplied to a bottom of the stripping tower, simultaneously regenerated ammonia is recovered from the top of the stripping tower, and a residual liquid containing a calcium component is discharged from the bottom of the stripping tower.