Electrode active material slurry, preparation method thereof, and all-solid secondary battery comprising the same
Provided is an electrode active material slurry including a clustered complex and a slurry, wherein the clustered complex includes an electrode active material, a solid electrolyte, a conductive material, and a first binder, and the slurry includes a solvent and a second binder. The electrode active material slurry may include the clustered complex including the first binder and the slurry including the second binder so as to decrease a surface area of the overall complex, such that adhesion property with the current collector may be sufficiently secured even by using a small amount of binder, and performance of the all-solid secondary battery may be further improved.
1. An electrode active material slurry comprising:
a clustered complex and a slurry,
wherein the clustered complex comprises an electrode active material, a solid electrolyte, a conductive material, and a first binder, and the slurry comprises a solvent and a second binder,
wherein the first binder is applied on a surface of the electrode active material, and the second binder is present between the electrode active materials,
wherein the first binder comprises polytetrafluoroethylene (PTFE).
2. The electrode active material slurry according to claim 1 , wherein the first binder is in a form of particles having an average particle size (D 50 ) of about 0.01 μm to 10 μm.
3. The electrode active material slurry according to claim 1 , wherein the second binder is any one selected from the group consisting of styrene butadiene rubber (SBR), butadiene rubber (BR), nitrile butadiene rubber (NBR), styrene butadiene styrene block polymer (SBS), styrene ethylene butadiene block polymer (SEB), styrene-(styrene butadiene)-styrene block polymer, natural rubber (NR), isoprene rubber (IR), ethylene-propylene-diene terpolymer (EPDM) and poly(ethylene-co-propylene-co-5-methylene-2-norbornene), or mixtures thereof.
4. The electrode active material slurry according to claim 1 , wherein a weight ratio of the first binder and the second binder is about 1:0.1 to 2 (parts by weight).
5. The electrode active material slurry according to claim 1 , wherein the first binder has a content of about 1 to 5 wt % based on 100 wt % of a mixture of the active material and the solid electrolyte.
6. The electrode active material slurry according to claim 1 , wherein the second binder has a content of about 1 to 10 wt % based on 100 wt % of a mixture of the active material and the solid electrolyte.
7. The electrode active material slurry according to claim 1 , wherein the clustered complex has a specific surface area of about 0.5 to 1 m 2 /g.
8. The electrode active material slurry according to claim 1 , wherein the electrode active material has a content of about 50 to 85 wt %, the solid electrolyte has a content of about 10 to 40 wt %, the conductive material has a content of about 2 to 5 wt %, and the first binder has a content of about 1 to 5 wt %, all the wt % based on 100 wt % of a mixture of the active material and the solid electrolyte.
9. The electrode active material slurry according to claim 1 , wherein the solid electrolyte is a sulfide-based solid electrolyte.
10. The electrode active material slurry according to claim 1 , wherein, when the electrode is a cathode, the electrode active material slurry has a solid content of about 40 to 70 wt % based on a total weight of a cathode active material slurry.
11. A cathode comprising:
an electrode active material layer comprising an electrode active material slurry of claim 1 ; and
a base layer.
12. An all-solid secondary battery comprising a cathode of claim 11 .