Reforming catalyst
A reforming catalyst with improved surface area is provided by using high surface area alumina doped with a stabilizer metal as a catalyst support. The surface area of the catalyst can be higher than a typical reforming catalyst, and the surface area can also be maintained under high temperature operation. This can allow use of the catalyst for reforming in a higher temperature environment while maintaining a higher surface area, which can allow for improved dispersion and/or activity of an active metal such as rhodium on the catalyst support. The catalyst can be suitable for production of syngas from natural gas or other hydrocarbon-containing feeds.
1. A catalyst comprising about 0.1 wt % to about 10.0 wt % of a Group VIII metal, a Group IX metal, or a combination thereof on a lanthanum-stabilized alumina support, the lanthanum-stabilized alumina support having a thermally stable surface area of about 10 m 2 /g to about 60 m 2 /g and having an X-ray diffraction pattern after calcination at about 1200° C. as shown in FIG. 3 ,
wherein the lanthanum-stabilized alumina support has been calcined at a temperature below about 800° C. to reduce or minimize conversion of the alumina support to a lower surface area phase.
2. The catalyst of claim 1 , wherein the Group VIII metal, Group IX metal, or combination thereof has a dispersion value of at least 0.20.
3. The catalyst of claim 1 , wherein the Group VIII metal, Group IX metal, or combination thereof comprises Rh, Ni, Co, Pd, Pt, or a combination thereof.
4. The catalyst of claim 1 , wherein the lanthanum-stabilized alumina support has a thermally stable surface area of about 20 m 2 /g to about 60 m 2 /g.
5. The catalyst of claim 1 , wherein the lanthanum-stabilized alumina support comprises theta-alumina.
6. The catalyst of claim 1 , the catalyst being deposited on a surface of a monolith having an average wetted surface area per unit volume that ranges from about 50 ft −1 to about 3000 ft −1 .
7. The catalyst of claim 6 , wherein the monolith comprises alumina, zirconia, silicon carbide, or a combination thereof.
8. A catalyst comprising about 0.1 wt % to about 10.0 wt % of a Group VIII metal, a Group IX metal, or a combination thereof on a lanthanum-stabilized theta-alumina support, wherein said support comprises about 3 to about 5 wt. % lanthanum and has an X-ray diffraction pattern after calcination at about 1200° C. as shown in FIG. 3
wherein the lanthanum-stabilized theta-alumina support has been calcined at a temperature below about 800° C. to reduce or minimize conversion of the alumina support to a lower surface area phase.
9. The catalyst of claim 8 , wherein the Group VIII metal, Group IX metal, or combination thereof (i) comprises Rh, Ni, Co, Pd, Pt, or a combination thereof, (ii) has a dispersion value of at least 0.20, or (iii) both (i) and (ii).