IP Library Granted Patent US 10,508,036
Granted Patent B2
US 10,508,036 · App. 15/346,380 · Granted Dec 17, 2019

System and method for mass production of graphene platelets in arc plasma

Inventors: Michael Keidar (Baltimore, MD); Alexey Shashurin (Rockville, MD)
Assignee: The George Washington University
C01B32/186B82Y30/00B82Y40/00C01B2204/02Y10S977/734Y10S977/843
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Quick Facts
Patent No.
US 10,508,036
App. No.
15/346,380
Granted
Dec 17, 2019
Kind
B2
Abstract

A system and method for producing graphene includes a heating block, substrate, motor and collection device. The substrate is arranged about the heating block and is configured to receive heat from the heating block. A motor is connected to the substrate to rotate the substrate about the heating block. A cathode and anode are configured to direct a flux stream for deposit onto the rotating substrate. A collection device removes the deposited material from the rotating substrate. A heating element is embedded in the heating block and imparts heat to the heating block. The heating block is made of cement or other material that uniformly disperses the heat from the heating element throughout the heating block. The flux stream can be a carbon vapor, with the deposited flux being graphene.

Claims (29)

1. A method for synthesizing graphene, the method comprising:

providing a heated substrate;

producing a flux stream of carbon using an anodic arc discharge device having an anodic arc, and depositing material from the flux stream on the heated substrate, wherein the flux stream comprises a carbon vapor and the material deposited on the substrate comprises graphene; and

removing the deposited material from the substrate using a collection device,

wherein the method is conducted at a pressure of up to 500 Torr and a temperature of the substrate of about 700-1,200 degrees Celsius, and configuring a rate of producing the carbon vapor flux stream, a rate of depositing the graphene material from the flux stream onto the substrate, and the substrate temperature to form a single graphene layer on the substrate.

2. The method of claim 1 , further comprising enclosing a heating element in a heating block, the heating element imparting heat to the heating block, and the heating block dispersing the heat from the heating element uniformly throughout the heating block to uniformly heat the substrate.

3. The method of claim 2 , wherein the heating block is a solid cylindrical block and the substrate is a tube coaxially arranged about the cylindrical heating block.

4. The method of claim 2 , wherein the substrate includes a conical top connected to a rotation device.

5. The method of claim 2 , wherein the substrate and the heating block each have a cylindrical shape and the cylindrical heating block is concentrically arranged inside the cylindrical substrate whereby an inside diameter of the cylindrical substrate is greater than an outer diameter of the cylindrical heating block.

6. The method of claim 2 , wherein the heating block comprises cement.

7. The method of claim 2 , wherein the substrate is a tube with at least one open end, the heating block received in the open end of the substrate.

8. The method of claim 1 , wherein the collection device comprises a brush.

9. The method of claim 1 , wherein the flux stream is provided by an anode electrode and a cathode electrode.

10. The method of claim 1 , further comprising rotating the heated substrate, depositing the flux stream on the rotating substrate at a first side of the substrate, and simultaneously removing the deposited material from a second side of the rotating substrate with the collection device, wherein the first side is different from the second side, and whereby the deposited graphene material has a thickness of one atom.

11. The method of claim 10 , wherein the first side comprises a top portion of the substrate and the second side comprises a bottom portion of the substrate.

12. The method of claim 10 , wherein the substrate is cylindrical and has a longitudinal axis that is substantially horizontal.

13. A method comprising:

providing a substrate;

embedding a heating element in a solid cylindrical cement heating block, the heating element imparting heat to the heating block, and the heating block dispersing the heat from the heating element uniformly throughout the heating block to uniformly heat the substrate to a temperature of 700-1,200 degrees Celsius;

producing a carbon vapor flux stream by an anodic arc discharge device having an anodic arc, and depositing a graphene material from the flux stream onto the heated substrate at a pressure of up to 500 Torr;

removing the deposited graphene material from the heated substrate using a collection device; and,

configuring a rate of producing the carbon vapor flux stream, a rate of depositing the graphene material from the flux stream onto the substrate, and substrate temperature to form a single graphene layer on the substrate.

14. The method of claim 13 , wherein the substrate is a tube coaxially arranged about the cylindrical heating block.

15. The method of claim 13 , wherein the substrate has a cylindrical shape and the cylindrical heating block is concentrically arranged inside the cylindrical substrate whereby an inside diameter of the cylindrical substrate is greater than an outer diameter of the cylindrical heating block.

16. The method of claim 13 , wherein the collection device comprises a brush.

17. The method of claim 13 , further comprising rotating the substrate, wherein the carbon vapor flux stream is deposited on the rotating substrate at a first side of the rotating substrate simultaneously with the collection device removing the deposited graphene material from a second side of the rotating substrate, wherein the first side is different from the second side.

18. The method of claim 17 , wherein the first side comprises a top portion of the substrate and the second side comprises a bottom portion of the substrate.

19. The method of claim 16 , wherein the substrate is cylindrical and has a longitudinal axis that is substantially horizontal.

20. The method of claim 13 , wherein the deposited graphene material has a thickness of one atom.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 12, 2017
From: KEIDAR, MICHAEL; SHASHURIN, ALEXEY
To: THE GEORGE WASHINGTON UNIVERSITY
Reel/Frame 043564/0052 →
CONFIRMATORY LICENSE Recorded Feb 2, 2017
From: GEORGE WASHINGTON UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 041605/0331 →
Continuity (3)
Division 13910699 · Jun 5, 2013
Provisional Application 61658665 · Jun 12, 2012
Related Publication 20170217776A1 · Aug 3, 2017