Methods for forming nanotube fabric layers with increased density
View Patent ↗Methods for passivating a nanotube fabric layer within a nanotube switching device to prevent or otherwise limit the encroachment of an adjacent material layer are disclosed. In some embodiments, a sacrificial material is implanted within a porous nanotube fabric layer to fill in the voids within the porous nanotube fabric layer while one or more other material layers are applied adjacent to the nanotube fabric layer. Once the other material layers are in place, the sacrificial material is removed. In other embodiments, a non-sacrificial filler material (selected and deposited in such a way as to not impair the switching function of the nanotube fabric layer) is used to form a barrier layer within a nanotube fabric layer. In other embodiments, individual nanotube elements are combined with and nanoscopic particles to limit the porosity of a nanotube fabric layer.
1. A method for forming a multilayer nanotube fabric, comprising:
forming a first nanotube application solution, said first nanotube application solution comprising a first plurality of nanotube elements suspended in a solvent;
depositing said first nanotube application solution over a material layer to form a first nanotube fabric layer having a first density;
selecting a second plurality of nanotube elements, said second plurality of nanotube elements having a length below a selected limit;
forming a second nanotube application solution, said second nanotube application solution comprising said selected second plurality of nanotube elements suspended in a solvent;
depositing said second nanotube application solution over said first nanotube fabric layer to form a second nanotube fabric layer with a selected second density,
wherein said first nanotube fabric layer and said second nanotube fabric layer form a multilayer nanotube fabric; and
wherein said second density is selected by selecting the length of said second plurality of nanotube elements, and said second density of said second nanotube fabric layer is sufficient to passivate said multilayer nanotube fabric.
2. The method of claim 1 wherein said selected density limits the encroachment of a second material layer formed over or adjacent to said multilayer nanotube fabric into said multilayer nanotube fabric.
3. The method of claim 1 wherein said length of second plurality of nanotube elements is limited to less than about 500 nm.
4. The method of claim 1 wherein said length of second plurality of nanotube elements is limited to less than about 100 nm.
5. The method of claim 1 wherein said first nanotube application solution and said second nanotube application solutions are deposited using one of a spin coating process, a spray coating process, or a dip coating process.
6. The method of claim 1 wherein said nanotube elements are carbon nanotubes.
7. The method of claim 1 wherein said solvent is one of dimethylformamide, n-methylpyrollidinone, n-methyl formamide, ethyl lactate, alcohol, or water.
8. The method of claim 1 wherein said second nanotube fabric layer has a substantially uniform density.
9. The method of claim 1 wherein said first density is selected to increase the switching function of said first nanotube fabric layer.