Dense high-speed scintillator material of low afterglow
The invention relates to an inorganic scintillator material of formula Lu (2-y) Y (y-z-x) Ce x M z Si (1-v) M′ v O 5 , in which: M represents a divalent alkaline earth metal and M′ represents a trivalent metal, (z+v) being greater than or equal to 0.0001 and less than or equal to 0.2; z being greater than or equal to 0 and less than or equal to 0.2; v being greater than or equal to 0 and less than or equal to 0.2; x being greater than or equal to 0.0001 and less than 0.1; and y ranging from (x+z) to 1. In particular, this material may equip scintillation detectors for applications in industry, for the medical field (scanners) and/or for detection in oil drilling. The presence of Ca in the crystal reduces the afterglow, while stopping power for high-energy radiation remains high.
1. A method for the detection of gamma rays, X-rays, cosmic rays or particles having an energy of 1 keV or greater, comprising measuring at least one of gamma rays, X-rays, cosmic rays and particles having an energy of 1 keV or greater with a scintillation detector comprising an inorganic LSO or LYSO scintillator material comprising a divalent alkaline earth metal ion, M, and/or a trivalent metal, M′ ion,
wherein the scintillator material comprises Lu, Si, O, and M, wherein M reduces afterglow and M is Ca, Mg, or Sr.
2. The method of claim 1 , wherein the scintillation material comprises Lu, Si, O, Y, and Ca, wherein Ca reduces an afterglow.
3. The method of claim 1 , wherein the scintillation material has a formula of:
Lu( 2-y) Ce x M z Si( 1-v )M′ v O 5,
wherein:
M represents the divalent alkaline earth metal ion;
M′ represents the trivalent metal ion.:
(z+v) is greater than or equal to 0.0001 and less than or equal to 0.2;
z is greater than or equal to 0 and less than or equal to 0.2;
v is greater than or equal to 0 and less than or equal to 0.2;
x is greater than or equal to 0.0001 and less than 0.1; and
y is equal to (x+z).
4. The method of claim 3 , wherein (z+v) is greater than or equal to 0.0002.
5. The method of claim 3 , wherein (z+v) is less than or equal to 0.05.
6. The method of claim 3 , wherein (z+v) is less than or equal to 0.01.
7. The method of claim 3 , wherein (z+v) is less than or equal to 0.001.
8. The method of claim 3 , characterized in that x is greater than 0.0001 and less than 0.001.
9. The method of claim 1 , wherein the scintillation material has a formula of:
Lu( 2-y )Ce x Ca z SiO 5 ,
wherein:
z is greater than or equal to 0.0001 and less than 0.05;
x is greater than or equal to 0.0001 and less than 0.1; and
y is equal to (x+z).
10. The method of claim 1 , wherein the scintillation material comprises Lu, Si, O, Y and Al, wherein Al reduces an afterglow.
11. The method of claim 1 , wherein the scintillation material is a single-crystal material.
12. The method of claim 1 , wherein the scintillation material is a single-crystal material which is grown in the presence of M or M′ in a melt.
13. The method as claimed in claim 1 , wherein the scintillation material is a single-crystal material which is grown by the Czochralski method in the presence of M or M′ in a melt.
14. The method as claimed in claim 1 wherein M or M′ improves the resolution of the detection.
15. The method as claimed in claim 1 , wherein the scintillation material comprises O and Si, wherein the O is five times that of (Si+M′)±about 2%.
16. A method for the detection of gamma rays, X-rays, cosmic rays or particles having an energy of 1 keV or greater, comprising measuring at least one of gamma rays, X-rays, cosmic rays and particles having an energy of 1 keV or greater with a scintillation detector comprising an inorganic LSO or LYSO scintillator material comprising a divalent alkaline earth metal ion, M, and/or a trivalent metal, M′ ion,
wherein the scintillation material comprises Lu, Si, O, and M′, wherein M′ reduces afterglow and M′ is Al, Ga, or In.
17. The method of claim 16 wherein the scintillation material comprises Lu, Si, O, Y, and Al, wherein Al reduces an afterglow.
18. A method for the detection of gamma rays, X-rays, cosmic rays or particles having an energy of 1 keV or greater, the method comprising:
measuring at least one of gamma rays, X-rays, cosmic rays and particles having an energy of 1 keV or greater with a scintillation detector comprising an inorganic LSO or LYSO scintillator material comprising at least one metal ion selected from the group consisting of Ca, Mg, Sr, Al, Ga, and In, wherein Ca, Mg, Sr, Al, Ga, and In reduce an afterglow.