Nonaqueous electrolyte secondary battery separator and use thereof
Provided is a nonaqueous electrolyte secondary battery separator excellent in voltage-withstanding property. This nonaqueous electrolyte secondary battery separator has (i) a film thickness of not more than 20 μm, (ii) a peeling strength, measured by a blocking test, of not less than 0.2 N, and (iii) a puncture strength that changes through the blocking test by not more than 15%. The blocking test is carried out by (i) sandwiching, by a jig of 100 mm×100 mm, two 80 mm×80 mm pieces of a separator, (ii) allowing the two 80 mm×80 mm pieces to rest for 30 minutes under a load of 3.5 kg at a temperature of 133° C.±° C., (iii) removing the load, (iv) cooling the two 80 mm×80 mm pieces to room temperature, (vi) cutting out a specimen of 27 mm×80 mm from the two 80 mm×80 mm pieces, and then (vi) measuring a peeling strength of the specimen at 100 mm/min.
1. A nonaqueous electrolyte secondary battery separator comprising a porous film containing a polyolefin-based resin as a main component,
the nonaqueous electrolyte secondary battery separator having:
a peeling strength of not less than 0.2 N, the peeling strength being measured by a blocking test;
a puncture strength of not less than 2 N, the puncture strength changing through the blocking test by not more than 15%;
a heat-sealing property of not less than 10 N; and
a weight per unit area of 4 g/m 2 to 20 g/m 2 ,
the blocking test being carried out by (i) sandwiching, by a jig of 100 mm×100 mm, two 80 mm×80 mm pieces of the porous film containing a polyolefin-based resin as a main component, (ii) allowing the two 80 mm×80 mm pieces to rest under a load of 3.5 kg at a temperature of 133° C.±1° C. for 30 minutes, (iii) removing the load, (iv) cooling the two 80 mm×80 mm pieces to room temperature, (v) cutting out a specimen of 27 mm×80 mm from the two 80 mm×80 mm pieces, and then (vi) measuring a peeling strength of the specimen at 100 mm/min,
the heat-sealing property being calculated by (I) cutting out two 80 mm×80 mm test samples from the porous film, (II) sealing one end of each test sample at 140° C. for one second, (III) cutting out a specimen of 27 mm×80 mm from each sealed test sample, (IV) measuring the peeling strength of each specimen at 100 mm/min three times, and (V) obtaining an average of the three measurements and using the average as the heat-sealing property.
2. A nonaqueous electrolyte secondary battery separator as set forth in claim 1 , wherein:
a thickness of the nonaqueous electrolyte secondary battery separator is not more than 20 μm.
3. A nonaqueous electrolyte secondary battery member comprising:
a cathode;
a nonaqueous electrolyte secondary battery separator recited in claim 1 ; and
an anode,
the cathode, a nonaqueous electrolyte secondary battery separator, and the anode being provided in this order.
4. A nonaqueous electrolyte secondary battery comprising:
a nonaqueous electrolyte secondary battery separator recited in claim 1 .
5. A nonaqueous electrolyte secondary battery laminated separator comprising:
a nonaqueous electrolyte secondary battery separator recited in claim 1 ; and
a porous layer.
6. A nonaqueous electrolyte secondary battery member comprising:
a cathode;
a nonaqueous electrolyte secondary battery laminated separator recited in claim 5 ; and
an anode,
the cathode, the nonaqueous electrolyte secondary battery laminated separator, and the anode being provided in this order.
7. A nonaqueous electrolyte secondary battery comprising:
a nonaqueous electrolyte secondary battery laminated separator recited in claim 5 .