Method for preparing taurine
There is disclosed a process for preparing taurine from alkali isethionate by reacting alkali taurinates in the solution of ammonolysis reaction of alkali isethionate with ammonium bisulfite or ammonium sulfite to obtain taurine and to regenerate alkali bisulfite or alkali sulfite, which is used to react with ethylene oxide to afford alkali isethionate.
1. A process for producing taurine from alkali taurinate or a mixture of alkali taurinate, alkali ditaurinate, and alkali tritaurinate, comprising:
(1) adding ammonium bisulfite, or ammonium sulfite, or their mixture to a solution of alkali taurinate or a mixture of alkali taurinate, alkali ditaurinate, and alkali tritaurinate to yield ammonium taurinate and a mixture of alkali sulfite and alkali bisulfite;
(2) decomposing ammonium taurinate by heating and removing ammonia to yield taurine;
(3) separating taurine by means of solid-liquid separation to provide a mother liquor containing a mixture of alkali sulfite and alkali bisulfite.
2. The process according to claim 1 , wherein a mixture of alkali taurinate, alkali ditaurinate, and alkali tritaurinate is produced by an ammonolysis reaction of alkali isethionate or a mixture of alkali isethionate, alkali ditaurinate, and alkali tritaurinate.
3. The process according to claim 2 , wherein a process for using the mother liquor to produce alkali isethionate comprises:
(a) concentrating the mother liquor to crystallize alkali bisulfite, alkali metabisulfite, alkali sulfite, or their mixture and recovering the solid by means of solid-liquid separation;
(b) dissolving alkali metabisulfite, alkali sulfite, or their mixture from step (a) in water and reacting the solution with sulfur dioxide or sulfurous acid to form a solution of alkali bisulfite;
(c) adding ethylene oxide to the solution of step (b) to react with alkali bisulfite to form alkali isethionate.
4. The process according to claim 1 , wherein the molar ratio of ammonium salt to alkali taurinates in the ammonolysis solution is from 0.1 to 10.
5. The process according to claim 1 , wherein the molar ratio of ammonium salt to alkali taurinates in the ammonolysis solution is from 0.4 to 1.1.
6. The process according to claim 2 , wherein a process for recycling the mother liquor to produce a solution of a mixture of alkali isethionate, alkali ditaurinate, and alkali tritaurinate, comprises:
(a) reacting the mother liquor, containing a mixture of alkali sulfite and alkali bisulfite, with sulfur dioxide or sulfurous acid, to form alkali bisulfite;
(b) adding ethylene oxide to the solution of step (a) to react with alkali bisulfite to form alkali isethionate in the presence of alkali ditaurinate and alkali tritaurinate.
7. The process according to claim 1 , wherein the alkali metals are lithium, sodium, or potassium.