Organic compound for organic EL device and using the same
The present invention discloses an organic compound represented by the following formula (1), the organic EL device employing the organic compound as light emitting host of emitting lay and/or an electron transporting layer, and/or a hole blocking layer, and/or a delayed fluorescence material of emitting layer can display good performance. wherein A 1 and A 2 are acceptor, m, n, L 1 , L 2 , Y 1 , Y 2 and X 1 to X 5 are the same definition as described in the present invention.
1. An organic compound with a general formula (1) as follows:
wherein A 1 and A 2 are acceptors each represented from formula (3) to formula (11)
L 1 and L 2 represent a substituted or unsubstituted divalent arylene group having 6 to 30 ring carbon atoms, m and n represent an integer of 0 or 1; m and n cannot be 0 simultaneously, o represents an integer of 0 to 3, p represents an integer of 0 to 4, q represents an integer of 0 to 5, r represents an integer of 1 to 5, Y 1 to Y 3 is a CH group, Y 4 to Y 6 is a divalent bridge selected from the atom or group consisting from O, S, C(R 13 )(R 14 ), NR 15 , and Si(R 16 )(R 17 ); X 1 to X 12 represent a nitrogen atom or C(R s), and each R s represents a hydrogen, a phenyl, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 30 carbon atoms; Z represents a cyano group, R 1 to R 17 are independently selected from the group consisting of a hydrogen atom, a halide, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, and a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms.
2. An organic electroluminescence device comprises a pair of electrodes consisting of a cathode and an anode, and between the pairs of electrodes comprise at least a light emitting layer, and one or more layers of organic thin film layer, wherein the light emitting layer or organic thin film layer comprises the organic compound with a general formula (1) according to claim 1 .
3. The organic electroluminescence device according to claim 2 , wherein a difference between a singlet energy of the organic compound and a triplet energy of the organic compound is less than 0.25 eV.
4. The organic electroluminescence device according to claim 2 , wherein the organic compound is a delayed fluorescence compound.
5. The organic electroluminescence device according to claim 2 , wherein the organic compound with a general formula (1) is a delayed fluorescence host material.
6. The organic electroluminescence device according to claim 2 , wherein the organic compound with a general formula (1) is a delayed fluorescence dopant material.
7. The organic electroluminescence device according to claim 2 , wherein the light emitting layer comprises a dopant material.
8. The organic electroluminescence device according to claim 2 , wherein the light emitting layer comprises a host material.
9. The organic electroluminescence device according to claim 2 , wherein the organic compound with a general formula (1) is a phosphorescent host material.
10. The organic electroluminescence device according to claim 2 , wherein the organic compound with a general formula (1) is a hole blocking material.
11. The organic electroluminescence device according to claim 2 , wherein the organic compound with a general formula (1) is an electron transporting layer(ETL) material.
12. The organic electroluminescence device according to claim 2 , wherein the device is an organic light emitting device.
13. The organic electroluminescent device according to claim 2 , wherein the device is a lighting panel.
14. The organic electroluminescent device according to claim 2 , wherein the device is a backlight panel.
15. An organic compound represented by the following formula (12):
wherein A 1 is an acceptor represented from formula (2) to formula (11)
L 1 and L 2 represent a substituted or unsubstituted divalent arylene group having 6 to 30 ring carbon atoms, m and n represent an integer of 0 or 1; m and n cannot be 0 simultaneously, o represents an integer of 0 to 3, p represents an integer of 0 to 4, q represents an integer of 0 to 5, r represents an integer of 1 to 5, Z is represents a cyano group, R 1 to R 12 and R 18 to R 22 are independently selected from the group consisting of a hydrogen atom, a halide, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, and a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms.
16. An organic compound represented by one of the following: