Graphene dispersion and graphene reinforced polymer
A graphene dispersion includes a graphene material and a polymerizable monomer. The polymerizable monomer has a structure including the first part and the second part. The first part is at one end of the structure and includes at least one benzene ring, and the second part is at another end of the structure and has polarity.
1. A graphene dispersion comprising:
a graphene material; and
a polymerizable monomer including a structure comprising:
a first part including at least one benzene ring at one end of the structure; and
a second part having polarity at another end of the structure.
2. The graphene dispersion according to claim 1 , wherein the first part including at least one benzene ring is selected from the group consisting of a phenyl group and a phenoxy group.
3. The graphene dispersion according to claim 1 , wherein the first part comprises a biphenyl group.
4. The graphene dispersion according to claim 1 , wherein the first part is conjugated to the graphene material through 7C-7C interactions.
5. The graphene dispersion according to claim 1 , wherein the second part having polarity is selected from the group consisting of an acrylate-based functional group, a methacrylate-based functional group, a thiol-based functional group, an epoxide-based functional group, and an isocyanate-based functional group.
6. The graphene dispersion according to claim 1 , wherein the second part having polarity comprises maleic anhydride group.
7. The graphene dispersion according to claim 1 , wherein the polymerizable monomer is selected from a group consisting of 2-phenoxy ethyl acrylate (PHEA) and ortho-phenyl phenoxy ethyl acrylate (OPPEA).
8. The graphene dispersion according to claim 1 , wherein the graphene material comprises a plurality of graphene nanosheets, a plurality of graphene petals or a plurality of graphene nanoplatelets.
9. The graphene dispersion according to claim 1 , wherein a content of the graphene material is 0.1% to 0.5% by weight.
10. The graphene dispersion according to claim 1 , further comprising an initiator.
11. The graphene dispersion according to claim 10 , wherein the initiator comprises one of 1-hydroxy-cyclohexyl-phenyl-ketone, benzophenone, 2-hydroxy-2-methyl-1-phenyl-1-propanone, 2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methyl-1-propanone, alpha, alpha-dimethoxy-alpha-phenylacetophenone, oxy-phenyl-acetic acid 2-[2 oxo-2 phenyl-acetoxy-ethoxy]-ethyl ester, oxy-phenyl-acetic 2-[2-hydroxy-ethoxy]-ethyl ester, methylbenzoylformate, 2-benzyl-2-(dimethylamino)-1-[4-(4-morpholinyl) phenyl]-1-butanone, 2-Methyl-1-[4-(methylthio)phenyl]-2-(4-morpholinyl)-1-propanone, diphenyl (2,4,6-trimethylbenzoyl)-phosphine oxide, phosphine oxide, phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide, bis(eta 5-2,4-cyclopentadien-1-yl)-bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanium, and iodonium, (4-methylphenyl) [4-(2-methylpropyl) phenyl]-, hexafluorophosphate(1-).
12. The graphene dispersion according to claim 10 , wherein a content of the initiator is 2% to 20% by weight.
13. The graphene dispersion according to claim 1 , wherein the graphene material and the polymerizable monomer are mixed by an ultrasonic treatment and using a planetary mixer.
14. The graphene dispersion according to claim 1 , wherein the graphene material comprises graphene oxide (GO), and a number of oxygen (O) atoms is present in an amount of 50 or more than 50 atomic percent of the graphene oxide.
15. The graphene dispersion according to claim 1 , wherein the graphene material comprises reduced graphene oxide (rGO), and a number of oxygen (O) atoms is present in an amount of 3 to 50 atomic percent of the reduced graphene oxide.
16. The graphene dispersion according to claim 1 , wherein the graphene material comprises high purity graphene, and a number of oxygen (O) atoms is present in an amount less than 3 atomic percent of the high purity graphene.
17. The graphene dispersion according to claim 1 , wherein the graphene dispersion does not comprise any dispersant.
18. A graphene reinforced polymer, wherein the graphene reinforced polymer is polymerized from the graphene dispersion according to claim 1 .
19. The graphene reinforced polymer according to claim 18 , wherein the graphene material included in the graphene reinforced polymer has a solid content from 1*10 −3 % to 90% by weight.
20. The graphene reinforced polymer according to claim 18 , wherein the graphene reinforced polymer is polymerized with a UV light treatment or a heat treatment.