ADSORBENT WITH MULTIPLE LAYERS
A method, device, article of manufacture and apparatus are disclosed for binding successive layers of a “guest specie” such as an atom, cation, anion, organic molecule, and/or pathogen to a substrate or multiple different substrates. Possible substrates include materials with a porous nature; macro, micro and nano porous materials are all candidates. The adsorbent capacity of a substrate is extended by coordinating a layer of bi- or multi-functional ligand (L) to an adsorbed atom or ion or molecule or pathogen, which is then coordinate to a second layer of adsorbed atom or ion or molecule or pathogen.
1 . A method for making an article for separating one or more species from a fluid comprising the steps:
a) determining one or more species to be separated;
b) choosing a substrate comprising an attachment site; and
c) determining a ligand comprising first and second coordination sites wherein the first and second coordination sites are identical such that the first coordination site of the predetermined ligand can bind to the attachment site and the second coordination site can bind to at least one of the one or more species.
2 . The method of claim 1 wherein said substrate comprises one a group comprising titanium dioxide, zeolite, carbon, polymers, alumina, aluminum hydroxide, and porous minerals.
3 . The method of claim 1 wherein said predetermined ligand comprises a material chosen from a class comprising aliphatic and aromatic dithiols, aliphatic diureas, aliphatic and aromatic dicarboxylic acids, aliphatic and aromatic diamines, dicatecholates, aliphatic and aromatic phosphines and phosphine oxides, carcerands, cavitands and cryptands.
4 . The method of claim 1 wherein said substrate comprises at least one from a group comprising trimethoxysilanes, phosphonic acids, metallic thin films, carbon, ceramic particles, proteins and organic templates.
5 . The method of claim 1 wherein said specie is chosen from a group comprising an organic molecule, an inorganic element, inorganic compound and a pathogen.
6 . The method of claim 1 wherein said fluid comprises water.
7 . A method for separating one or more species from a fluid comprising the steps:
a) selecting a fluid comprising one or more species to be separated;
b) selecting at least one of the one or more species to be separated;
c) choosing a substrate comprising an attachment site;
d) determining a ligand comprising first and second coordination sites wherein the first and second coordination sites are identical such that the first coordination site of the determined ligand can bind to the attachment site and the second coordination site can bind to the selected one of the one or more species to be separated.
8 . A method for separating one or more species from a fluid the method comprising:
causing an attachment site comprised in a substrate to bind to a predetermined ligand comprising first and second coordination sites wherein the first and second coordination sites are identical such that the first coordination site of the predetermined ligand can bind to the attachment site and the second coordination site can bind to at least one of the one or more species; and
causing the predetermined ligand to enable multiple layers adsorbing by attaching to a specie of one layer as well as attaching to at least one more guest specie to enable a subsequent layer, such that the adsorptive capacity of the substrate is increased by adding additional layers of the predetermined ligand.
9 . The method of claim 8 wherein said substrate comprises one a group comprising titanium dioxide, zeolite, carbon, polymers, alumina, aluminum hydroxide, and porous minerals.
10 . The method of claim 8 wherein said predetermined ligand comprises a material chosen from a class comprising aliphatic and aromatic dithiols, aliphatic diureas, aliphatic and aromatic dicarboxylic acids, aliphatic and aromatic diamines, dicatecholates, aliphatic and aromatic phosphines and phosphine oxides, carcerands, cavitands and cryptands.
11 . The method of claim 8 wherein said substrate comprises at least one from a group comprising trimethoxysilanes, phosphonic acids, metallic thin films, carbon, ceramic particles, proteins and organic templates.
12 . The method of claim 8 wherein said specie is chosen from a group comprising an organic molecule, an inorganic element, inorganic compound and a pathogen.
13 . The method of claim 8 wherein said fluid comprises water.