Sealant composition for releasable shingle
A sealant composition for roofing shingles that includes a base asphalt, a linear and/or a radial copolymer, oil, and a wax is provided. The linear copolymer has an A-B di-block or an A-B-A tri-block structure. The radial copolymer may have an (A-B) n radial structure, where n is at least 4, or a tri-block (A-B-A) radial structure having from 4 to 8 arms. Blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. The oil is a petroleum-based oil that both “softens” the asphalt and reduces the viscosity of the sealant composition. The wax may be a bis-stearamide wax. Additionally, the sealant composition may be reacted with elemental sulfur to crosslink the copolymer blend. The sealant composition seals at temperatures lower than conventional sealants and promotes the easy release of the shingle from a shingle bundle.
1. A composition for a sealant for a roofing shingle comprising:
an asphalt-based material;
at least 6.0 wt. % of a copolymer comprising a blend of at least one linear copolymer and at least one radial copolymer, said linear copolymer having an A-B di-block or an A-B-A tri-block structure and said radial copolymer selected from a block copolymer having an (A-B) n radial structure where n is an integer of at least 4 and a block copolymer having a tri-block (A-B-A) radial structure having from 4-8 arms;
2.0 wt. % to 7.0 wt. % of an oil; and
0.2 wt. % to 5.0 wt. % of a bis-stearamide wax, wherein said composition seals and bonds shingles at temperatures as low as 40° F., and wherein said composition has a viscosity of no greater than 1,500 cP at 350° F.
2. The composition of claim 1 , wherein said sealant seals at temperatures lower than 135° F.
3. The composition of claim 1 , wherein said radial copolymer is selected from styrene-butadiene-styrene (SBS) radial copolymers and styrene-isoprene-styrene (SIS) radial copolymers; and wherein the copolymer forming said linear copolymer is selected from styrene-butadiene block copolymers and styrene-isoprene block copolymers.
4. The composition of claim 3 , wherein said radial copolymer and said linear copolymer have a styrene content of less than 50%.
5. The composition of claim 1 , wherein said oil is selected from petroleum-based oils, naphthenic oils, paraffinic oils and combinations thereof.
6. The composition of claim 1 , further comprising up to 30% of one or more fillers selected from calcium carbonate, dolomite, wollastonite, talc and silica.
7. The composition of claim 1 , wherein: said asphalt-based material is present in said sealant composition in an amount from about 74.0% to about 90.5% by weight of said composition; said radial copolymer is present in said sealant composition in an amount from 3.5% to about 9.0% by weight of said composition; said linear copolymer is present in said sealant composition in an amount from about 2.5% to about 11.0% by weight of said composition; said oil is present in said sealant composition in an amount from about 2.0% to about 7.0% by weight of said composition; and said wax is present in said sealant composition in an amount from about 0.2% to about 5.0% by weight of said composition.
8. A composition for a sealant for a roofing shingle comprising:
74.0 weight % to 90.5 weight % of an asphalt-based material;
a copolymer comprising a linear copolymer having an A-B-A tri-block structure;
4.0 weight % to 7.0 weight % of an oil; and
0.5 weight % to 2.0 weight % of a bis-stearamide wax,
wherein said sealant composition has a viscosity of no more than 1,500 cP at 350° F.; and
wherein said sealant composition seals and bonds shingles at temperatures as low as 40° F.