Semiconductor nanoparticle-based materials
The present invention relates to a primary particle comprised of a primary matrix material containing a population of semiconductor nanoparticles, wherein each primary particle further comprises an additive to enhance the physical, chemical and/or photo-stability of the semiconductor nanoparticles. A method of preparing such particles is described. Composite materials and light emitting devices incorporating such primary particles are also described.
1. A method of making a quantum dot (QD)-containing bead-in-bead composition, the method comprising:
encapsulating a plurality of QDs within a first bead material to provide a plurality of primary beads, each primary bead containing a plurality of QDs encapsulated therein;
encapsulating a plurality of the primary beads within a second bead material to provide a plurality of secondary beads, each secondary bead containing a plurality of primary beads encapsulated therein;
incorporating a stability-enhancing additive into either the primary beads or into the secondary beads; and,
coating the secondary beads with an inorganic protective surface.
2. The method of claim 1 , wherein the QDs comprise ions selected from group 13 and group 15 of the periodic table.
3. The method of claim 1 , wherein the first bead material comprises resin, polymer, glass, sol gel, epoxy, silicone, acrylate, or silica.
4. The method of claim 1 , wherein the first bead material is a (meth)acrylate polymer.
5. The method of claim 1 , wherein the first bead material is silica.
6. The method of claim 1 , wherein encapsulating a plurality of QDs within a first bead material comprises suspending the plurality of QDs in a solution of monomer and polymerizing the monomer to provide the first bead material.
7. The method of claim 1 , wherein encapsulating a plurality of QDs within a first bead material comprises suspending the plurality of QDs and a plurality of primary beads in a liquid and allowing the QDs to absorb into the primary beads.
8. The method of claim 1 , wherein the primary beads are about 20 nm to about 0.5 mm in diameter.
9. The method of claim 1 , wherein the inorganic protective surface comprises Al 2 O 3 .
10. The method of claim 1 , wherein the second bead material comprises polymer, resin, glass, sol gel, epoxy, silicone, or (meth)acrylate.
11. The method of claim 1 , wherein the second bead material is a silicone polymer.
12. The method of claim 1 , wherein the stability-enhancing additive is a free-radical scavenger or a reducing agent.
13. A bead-in-bead composition comprising:
a plurality of primary beads encapsulated within a secondary bead, wherein each primary bead comprises a first bead material and a plurality of quantum dots (QDs) encapsulated within the primary bead, the secondary bead comprises a secondary bead material, the primary beads or the secondary bead comprise a stability-enhancing additive, and the secondary bead comprises an inorganic protective surface.
14. The bead-in-bead composition of claim 13 , wherein the QDs comprise ions selected from group 13 and group 15 of the periodic table.
15. The bead-in-bead composition of claim 13 , wherein the first bead material comprises resin, polymer, glass, sol gel, epoxy, silicone, acrylate, or silica.
16. The bead-in-bead composition of claim 13 , wherein the primary beads are about 20 nm to about 0.5 mm in diameter.
17. The bead-in-bead composition of claim 13 , wherein the inorganic protective surface comprises Al 2 O 3 .
18. The bead-in-bead composition of claim 13 , wherein the second bead material comprises polymer, resin, glass, sol gel, epoxy, silicone, or (meth)acrylate.
19. The bead-in-bead composition of claim 13 , wherein the second bead material is a silicone polymer.
20. The bead-in-bead composition of claim 13 , wherein the stability-enhancing additive is a free-radical scavenger or a reducing agent.