Power storage device packaging material and power storage device using the same
A power storage device packaging material including a base material layer; an adhesion-enhancing treatment layer on a surface of the base material layer; an adhesive layer on a surface of the adhesion-enhancing treatment layer opposite the base material layer; a metal foil layer formed on one side of the adhesive layer opposite the adhesion-enhancing treatment layer; and a sealant layer disposed on a surface of the metal foil layer opposite the adhesive layer. The base material layer is formed of a biaxially oriented film to have a breaking strength of 240 MPa or more in at least one of four directions (0° (MD), 45°, 90° (TD), 135°) and an elongation of 80% or more in at least one direction in a tensile test (test specimen shape: test specimen type 5 stipulated in JIS K7127; inter-chuck distance: 60 mm; tensile speed: 50 mm/min).
1. A power storage device packaging material comprising a base material layer, an adhesion-enhancing treatment layer directly on a surface of the base material layer, an adhesive layer directly on a surface on one side of the adhesion-enhancing treatment layer opposite to the base material layer so that the adhesion-enhancement treatment layer is between the base material layer and the adhesive layer, a metal foil layer formed on a surface on one side of the adhesive layer opposite to the adhesion-enhancing treatment layer, and a sealant layer disposed on a surface on one side of the metal foil layer opposite to the adhesive layer, wherein:
the base material layer is formed of a biaxially oriented film to have a breaking strength of 240 MPa or more in at least one of four directions (0° (MD), 45°, 90° (TD), 135°) and an elongation of 80% or more in at least one direction in a tensile test for a test specimen having a shape given by test specimen 5 in JIS K7127 with an inter-chuck distance of 60 mm and a tensile speed of 50 mm/min, the adhesion-enhancing treatment layer comprises a) at least one resin selected from the group consisting of a polyester resin, acrylic resin, polyurethane resin, epoxy resin and acrylic graft polyester resin and b) silica particles, and wherein the adhesive layer comprises a polyurethane resin and does not contain silica.
2. The power storage device packaging material of claim 1 , wherein the base material layer has a breaking strength of less than 240 MPa in at least one of the four directions in the tensile test.
3. The power storage device packaging material of claim 1 , wherein the base material layer is a biaxially-oriented polyester film or a biaxially-oriented polyamide film.
4. The power storage device packaging material of claim 1 , further comprising a base material protective layer formed on a surface on one side of the base material layer opposite to the adhesion-enhancing treatment layer.
5. The power storage device packaging material of claim 1 , wherein the base material layer has a thickness in a range of 6 to 40 μm.
6. The power storage device packaging material of claim 1 , wherein the adhesion-enhancing treatment layer has a thickness in a range of 0.02 to 0.5 μm.
7. The power storage device packaging material of claim 1 , wherein the adhesive layer contains a pigment.
8. A power storage device comprising a battery element including an electrode, a lead extending from the electrode, and a container accommodating the battery element, wherein:
the container is formed from the power storage device packaging material of claim 1 so that the sealant layer is located on an inner side.
9. The power storage device packaging material of claim 1 , wherein the base material layer is a biaxially-oriented polyester film or a biaxially-oriented polyamide film, the base material layer has a thickness in a range of 6 to 40 μm, and the adhesion-enhancing treatment layer has a thickness in a range of 0.02 to 0.5 μm.
10. The power storage device packaging material of claim 9 , further comprising a base material protective layer formed on a surface on one side of the base material layer opposite to the adhesion-enhancing treatment layer, wherein the base material protective layer comprises an oriented polyester film.
11. The power storage device packaging material of claim 10 , wherein the base material protective layer comprises a biaxially-oriented polyethylene terephthalate.
12. The power storage device packaging material of claim 9 , wherein the base material layer has an elongation of 80% or more in all of the four directions (0° (MD), 45°, 90° (TD),135°).
13. The power storage device packaging material of claim 9 , wherein the base material layer has a breaking strength of 250 MPa or more in at least one of the four directions.
14. The power storage device packaging material of claim 9 , wherein the adhesion-enhancing treatment layer comprises a polyester resin and silica particles.
15. The power storage device packaging material of claim 9 , wherein the adhesion-enhancing treatment layer comprises an acrylic resin and silica particles.
16. The power storage device packaging material of claim 9 , wherein the adhesion-enhancing treatment layer comprises a polyurethane resin and colloidal silica.