Solid electrolyte and method of manufacturing solid electrolyte
[Problem to be Solved] An object is to provide a solid electrolyte which is improved in relative density while having favorable lithium-ion conductivity and which can be preferably employed in a lithium-air battery and the like, and a method of manufacturing the same. [Solution] In a solid electrolyte satisfying formula (I): Li 1+X M1 X M2 Y Ti 2−X−Y (PO 4 ) 3 (I) (in formula (I), M1 is one or more elements selected from the group consisting of Al 3+ , Cu 3+ , Co 3+ , Fe 3+ , Ni 3+ , Ga 3+ , Cr 3+ , and Sc 3+ , M2 is one or more elements selected from the group consisting of Si 4+ , Ge 4+ , Sn 4+ , Hf 4+ , and Zr 4+ , and X and Y are real numbers satisfying X+Y≤1), the solid electrolyte has a NASICON-type crystal structure, and lattice constants of the NASICON-type crystal structure are such that a length along an a-axis is 0.8 nm or more and a length along a c-axis is 2.8 nm or less. Moreover, in a solid electrolyte satisfying formula (II): Li 1+X−Y Al X Nb Y Ti 2−X−Y (PO 4 ) 3 (II) (in formula (II), X and Y are real numbers satisfying X+Y≤1), the solid electrolyte has a NASICON-type crystal structure.
1. A solid electrolyte satisfying formula (I):
Li 1+X M1 X M2 Y Ti 2−X−Y (PO 4 ) 3 (I)
(in formula (I), M1 is one or more elements selected from the group consisting of Al, Cu, Co, Fe, Ni, Ga, Cr, and Sc; M2 is one or more elements selected from the group consisting of Si, Ge, Sn, Hf, Zr, and Nb; X and Y are real numbers satisfying X+Y≤1; and the Y satisfies 0.1≤Y≤0.3), wherein
the solid electrolyte has a NASICON-type crystal structure, and
lattice constants of the NASICON-type crystal structure are such that a length along an a-axis is 0.8 nm or more and a length along a c-axis is 2.8 nm or less.
2. The solid electrolyte according to claim 1 , wherein the X satisfies 0.35≤X≤0.50.
3. The solid electrolyte according to claim 2 , which has a relative density of 92% or more.
4. The solid electrolyte according to claim 2 , which has a lithium-ion conductivity of 4.0×10 −4 S/cm or more.
5. The solid electrolyte according to claim 2 , which has a three-point bending strength of 40 N/mm 2 or more.
6. The solid electrolyte according to claim 1 , which has a relative density of 92% or more.
7. The solid electrolyte according to claim 1 , which has a lithium-ion conductivity of 4.0×10 −4 S/cm or more.
8. The solid electrolyte according to claim 1 , which has a three-point bending strength of 40 N/mm 2 or more.
9. A method of manufacturing a solid electrolyte satisfying formula (I):
Li 1+X M1 X M2 Y Ti 2−X−Y (PO 4 ) 3 (I)
(in formula (I), M1 is one or more elements selected from the group consisting of Al, Cu, Co, Fe, Ni, Ga, Cr, and Sc, M2 is one or more elements selected from the group consisting of Si, Ge, Sn, Hf, Zr, and Nb, and X and Y are real numbers satisfying X+Y≤1; and the Y satisfies 0.1≤Y≤0.3), the method comprising the steps of:
mixing a solid powder including a composition to form the solid electrolyte;
forming a compact by pressure-molding the mixed powder; and
annealing the compact.
10. The method of manufacturing a solid electrolyte according to claim 9 , wherein a sintering temperature in the step of annealing the compact is 900 to 1200° C.
11. A solid electrolyte satisfying formula (II):
Li 1+X−Y Al X Nb Y Ti 2−X−Y (PO 4 ) 3 (II)
(in formula (II), X and Y are real numbers satisfying X+Y≤1, and the Y satisfies 0.1≤Y≤0.3), wherein
the solid electrolyte has a NASICON-type crystal structure.
12. The solid electrolyte according to claim 11 , wherein the X satisfies 0.5≤X≤0.6.
13. A method of manufacturing a solid electrolyte satisfying formula (II):
Li 1+X−Y Al X Nb Y Ti 2−X−Y (PO 4 ) 3 (II)
(in formula (II), X and Y are real numbers satisfying X+Y≤1, and the Y satisfies 0.1≤Y≤0.3), the method comprising the steps of:
mixing a solid powder including a composition to form the solid electrolyte;
forming a compact by pressure-molding the mixed powder; and
annealing the compact.
14. The method of manufacturing a solid electrolyte according to claim 13 , wherein a sintering temperature in the step of annealing the compact is 900 to 1000° C.