INTEGRATED PROCESS FOR CAPTURING CARBON DIOXIDE
The invention pertains to an integrated process for capturing CO 2 . The process involves desorbing gaseous CO 2 from a CO 2 containing aqueous solution comprising carbonate, bicarbonate, sesquicarbonate, carbamate, or a mixture thereof. The desorbing of gaseous CO 2 is conducted in the presence of a suitable water soluble substance. If desired, the process may also at least partially recover the soluble substance using a membrane, distillation, or another technique.
1 . An integrated process for capturing CO 2 comprising:
desorbing gaseous CO 2 from a CO 2 containing solution comprising carbonate, bicarbonate, sesquicarbonate, carbamate, or a mixture thereof;
wherein said desorbing of gaseous CO 2 is conducted in the presence of a suitable soluble substance.
2 . The integrated process of claim 1 which further comprises at least partially recovering said soluble substance.
3 . The integrated process of claim 2 wherein said at least partially recovering comprises employing a membrane capable of at least partially rejecting said soluble substance while allowing substantial passage of CO 2 containing solution.
4 . The integrated process of claim 3 wherein said membrane has a molecular weight cutoff of greater than about 80 daltons.
5 . The integrated process of claim 3 wherein said membrane is comprised of a material selected from the group consisting of:
a) thin film composite;
b) polyamide;
c) cellulose acetate;
d) ceramic membrane; and
e) combinations thereof.
6 . The integrated process of claim 2 wherein said at least partially recovering comprises employing distillation.
7 . The integrated process of claim 1 wherein the soluble substance comprises water, organic solvent, water soluble polymer, soluble polymer, glycol, polyethylene glycol, polypropylene glycol, ethers, glycol ethers, glycol ether esters, triglyme, polyethylene glycols of multiple geometries, including, branched polyethylene glycols, star polyethylene glycols, comb polyethylene glycols, methoxypolyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic Acid, diol polymers, 1,2 propanediol, 1,2 ethanediol, 1,3 propanediol, cellulose ethers, methylcellulose, cellosize, carboxymethylcellulose, hydroxyethylcellulose, sugar alcohol, sugars, alcohols, ketones, aldehydes, esters, organosilicon compounds, halogenated solvents, non-volatile solvents, a substance with a vapor pressure less than 0.01 atm at 20° C., soluble substances with a molecular weight greater than 80 daltons, or a mixture thereof.
8 . The integrated process of claim 1 wherein the soluble substance comprises one or more or a combination of the following: volatile organic solvents, soluble substances with a molecular weight less than 600 daltons, soluble substances with a molecular weight less than 200 daltons, dimethoxymethane, acetone, acetaldehyde, methanol, dimethyl ether, THF, ethanol, isopropanol, propanal, methyl formate, azeotropes, alcohols, ketones, aldehydes, esters, organosilicon compounds, halogenated solvents, a substance with a vapor pressure greater than 0.01 atm at 20° C., or a mixture thereof.
9 . The integrated process of claim 7 which further comprises at least partially recovering said soluble substance by employing a membrane capable of at least partially rejecting said soluble substance while allowing substantial passage of CO 2 containing solution.
10 . The integrated process of claim 8 which further comprises at least partially recovering said soluble substance by distillation.
11 . The integrated process of claim 1 wherein the soluble substance comprises a non-ionic carbon containing compound.
12 . The integrated process of claim 1 wherein the soluble substance comprises a thermally switchable substance.
13 . The integrated process of claim 1 wherein the soluble substance comprises a CO 2 switchable substance.
14 . The integrated process of claim 1 which further comprises capturing CO 2 to form the CO 2 containing solution from a source selected from the group consisting of flue gas; combustion emissions; manufacturing emissions; refining emissions or a combination thereof.
15 . The integrated process of claim 1 wherein the CO 2 containing solution further comprises a CO 2 absorbent.
16 . The integrated process of claim 15 wherein said absorbent comprises: ammonia, ammonium, amine, amino ethyl ethanol amine, 2-amino-2-methylpropan-1-ol (AMP), MDEA, MEA, primary amine, secondary amine, tertiary amine, low molecular weight primary or secondary amine, metal-amine complex, metal-ammonia complex, metal-ammonium complex, sterically hindered amine, imines, azines, piperazine, alkali metal, lithium, sodium, potassium, rubidium, caesium, alkaline earth metal, calcium, magnesium, ionic liquid, thermally switchable compounds, CO 2 switchable compounds, enzymes, metal-organic frameworks, quaternary ammonium, quaternary ammonium cations, quaternary ammonium cations embedded in polymer, or a mixture thereof.
17 . The integrated process of claim 1 wherein CO 2 is desorbed at a temperature of from about 18° C. to about 32° C.
18 . The integrated process of claim 1 wherein CO 2 is desorbed at a temperature of less than or equal to about 40° C.
19 . The integrated process of claim 1 wherein CO 2 is desorbed at a pressure of from about 0.75 to about 1.25 atmospheres.
20 . An integrated process for capturing CO 2 comprising:
capturing CO 2 to with a solution comprising a CO 2 absorbent to form a CO 2 containing solution comprising carbonate, bicarbonate, sesquicarbonate, carbamate, or a mixture thereof;
desorbing gaseous CO 2 from the CO 2 containing solution comprising carbonate, bicarbonate, sesquicarbonate, carbamate, or a mixture thereof wherein said desorbing of gaseous CO 2 is conducted in the presence of a suitable soluble substance; and
at least partially recovering said soluble substance by employing (1) a membrane with a molecular weight cutoff of greater than about 80 daltons or (2) distillation or (3) a combination thereof; wherein said soluble substance comprises water, organic solvent, water soluble polymer, soluble polymer, glycol, polyethylene glycol, polypropylene glycol, ethers, glycol ethers, glycol ether esters, triglyme, polyethylene glycols of multiple geometries, including, branched polyethylene glycols, star polyethylene glycols, comb polyethylene glycols, methoxypolyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic Acid, diol polymers, 1,2 propanediol, 1,2 ethanediol, 1,3 propanediol, cellulose ethers, methylcellulose, cellosize, carboxymethylcellulose, hydroxyethylcellulose, sugar alcohol, sugars, alcohols, ketones, aldehydes, esters, organosilicon compounds, halogenated solvents, non-volatile solvents, a substance with a vapor pressure less than 0.01 atm at 20° C., soluble substances with a molecular weight greater than 80 daltons, volatile organic solvents, soluble substances with a molecular weight less than 600 daltons, soluble substances with a molecular weight less than 200 daltons, dimethoxymethane, acetone, acetaldehyde, methanol, dimethyl ether, THF, ethanol, isopropanol, propanal, methyl formate, azeotropes, alcohols, ketones, aldehydes, esters, organosilicon compounds, halogenated solvents, a substance with a vapor pressure greater than than 0.01 atm at 20° C., or a mixture thereof.
21 . The integrated process of claim 18 wherein the desorbing of gaseous CO 2 from the CO 2 containing solution occurs in the absence of substantial precipitate formation at a temperature of from about 18° C. to about 32° C. and a pressure of from about 0.75 to about 1.25 atmospheres.
22 . The integrated process of claim 18 further comprising producing ammonium carbamate, urea, or a derivative thereof.