Methods of forming particulate films and films and devices made therefrom
A method of depositing a film comprising a monolayer of particles. The method includes providing a dispersion comprising particles and at least two liquids and depositing drops of the dispersion onto a substrate and evaporating the at least two liquids resulting in a film of a monolayer of the particles. One embodiment of the method includes a coating on the outer surface of particles such that the coating makes the particles substantially non-dispersible, substantially non-soluble and substantially non-suspendable in one of the liquids. A particulate film containing at least one layer of particles, wherein the at least one layer is substantially made of particles of a chemical composition and has uniform thickness. Optical devices containing a particulate film containing at least one layer of particles, wherein the at least one layer is substantially made of particles of a chemical composition and has uniform thickness.
1. A method of forming a film comprising particles, the method comprising:
providing particles with a coating on their outer surface such that the coating makes the particles substantially non-dispersible, substantially non-soluble and substantially non-suspendable in a first liquid, but are substantially soluble and dispersible in a second liquid, wherein the first liquid and the second liquid are miscible and an evaporation rate of the second liquid is greater than an evaporation rate of the first liquid;
dispersing the particles into the second liquid and mixing the resulting mixture with the first liquid to form a process mixture;
depositing the process mixture onto a substrate; and
evaporating the first liquid and second liquid to form a film comprising the particles on the substrate.
2. The method of claim 1 , wherein the substrate is one of polydimethylsiloxane (PDMS) and silicon.
3. The method of claim 1 , wherein a vapor pressure of the second liquid is greater than a vapor pressure of the first liquid.
4. The method of claim 1 , wherein diffusion coefficient between the second liquid and ambient atmosphere is greater than diffusion coefficient between the first liquid and the ambient atmosphere.
5. The method of claim 1 , wherein the film has a surface roughness in the same order of magnitude as the particle size of the particles.
6. The method of claim 1 , wherein the particles are made of Gallium-Indium alloy.
7. The method of claim 6 , where in the Gallium-Indium alloy is of eutectic composition.
8. The method of claim 7 , wherein the particles have size range of 1 nm to 2000 nm.
9. The method claim 8 , wherein the particles have a size range of 100 nm to 250 nm.
10. The method of claim 1 , the first liquid is water and the second liquid is an organic liquid.
11. The method of claim 1 , wherein the particles are made of a metal and the coating on the outer surface of the particles comprises sulfur-containing molecules.
12. The method of claim 11 , wherein the sulfur-containing molecules are molecules of a thiol.
13. The method of claim 12 , wherein the thiol is 3-mercapto-N-nonylpropionamide.
14. The method of claim 11 , wherein the sulfur-containing molecules are molecules of an ionic liquid.
15. The method of claim 14 , wherein the ionic liquid is Methyltrioctylammonium thiosalicylate.
16. The method of claim 1 , wherein the particles include a first type of particles, and a second type of particles, wherein the first type of particles are capable of dissolving in the first liquid and the second type of particles are capable of dissolving in the second liquid such that the process mixture comprises two liquids and two types of particles and the film formed has one layer substantially made of the first type of particles and a second layer substantially made of the second type of particles.
17. The method of claim 16 , further including a third type of particles capable of dissolving in a third liquid, such that the process mixture comprises three liquids and three types of particles and the film formed has one layer substantially made of the first type of particles, a second layer substantially made of the second type of particles, and a third layer substantially made of the third type of particles.
18. The method of claim 1 , wherein the process mixture is deposited using one of drop casting technique, spin coating technique, doctor blading techniques, aerosol deposition technique, slot die process, microgravure deposition technique, direct writing technique, and inkjet printing.