IP Library Granted Patent US 10,703,637
Granted Patent B2
US 10,703,637 · App. 15/430,885 · Granted Jul 7, 2020

Borophenes, boron layer allotropes and methods of preparation

Inventors: Mark C. Hersam (Wilmette, IL); Joshua D. Wood (Chicago, IL); Andrew J. Mannix (Chicago, IL); Brian T. Kiraly (Hillsboro Beach, FL); Brandon L. Fisher (Plainfield, IL); Nathan P. Guisinger (Darien, IL)
Assignees: NORTHWESTERN UNIVERSITY; UCHICAGO ARGONNE, LLC
C01B35/02C01P2002/85C01P2004/03C01P2004/04
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Quick Facts
Patent No.
US 10,703,637
App. No.
15/430,885
Granted
Jul 7, 2020
Kind
B2
Abstract

A boron allotrope comprising an elemental boron layer comprising a boron atomic thickness dimension and a method for preparation thereof.

Claims (18)

1. A boron allotrope comprising an elemental boron layer comprising a periodic lattice and a boron atomic thickness dimension.

2. The allotrope of claim 1 wherein the periodic lattice comprises a rectangular boron lattice.

3. A borophene comprising an elemental boron layer comprising a periodic lattice and a boron atomic thickness dimension.

4. The borophene of claim 3 wherein the periodic lattice comprises a rectangular boron lattice.

5. The borophene of claim 3 absent a boron compound and a boron alloy, said borophene metallic.

6. A boron allotrope comprising an elemental boron monolayer comprising a periodic lattice and a boron atomic thickness dimension, said allotrope absent a boron compound and a boron alloy.

7. The allotrope of claim 6 wherein the periodic lattice comprises a rectangular boron lattice.

8. A metallic boron allotrope comprising an elemental boron layer comprising a rectangular boron lattice and a boron atomic thickness dimension.

9. An article comprising a substrate; and a boron allotrope thereon, said allotrope comprising an elemental boron layer of boron atoms comprising a boron atomic thickness dimension.

10. The article of claim 9 wherein said allotrope comprises a rectangular boron lattice.

11. The article of claim 10 wherein said substrate comprises Ag.

12. The article of claim 11 wherein said substrate comprises single crystal Ag(111).

13. The article of claim 12 wherein said allotrope comprises at least one of a homogeneous boron phase and a striped boron phase.

14. The article of claim 13 wherein said allotrope is metallic.

15. An article comprising a silver substrate; and a metallic boron allotrope thereon, said allotrope comprising an elemental boron monolayer of boron atoms comprising a boron atomic thickness dimension, said allotrope absent a boron compound and a boron alloy.

16. The article of claim 15 wherein said substrate and said allotrope are absent oxygen and carbon contamination.

17. The article of claim 15 wherein said substrate comprises single crystal Ag(111).

18. The article of claim 17 wherein said allotrope comprises at least one of a homogeneous boron phase and a striped boron phase.

Assignments (3)
CONFIRMATORY LICENSE Recorded May 20, 2020
From: NORTHWESTERN UNIVERSITY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 052708/0778 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2017
From: HERSAM, MARK C.; WOOD, JOSHUA D.; KIRALY, BRIAN T.; MANNIX, ANDREW J.
To: NORTHWESTERN UNIVERSITY
Reel/Frame 042390/0249 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2017
From: GUISINGER, NATHAN P.; FISHER, BRANDON L.
To: UCHICAGO ARGONNE, LLC
Reel/Frame 042390/0274 →
Continuity (2)
Provisional Application 62388970 · Feb 12, 2016
Related Publication 20190002298A1 · Jan 3, 2019