Light-emitting element
A light-emitting element having high external quantum efficiency is provided. A light-emitting element having a long lifetime is provided. A light-emitting element is provided which includes a light-emitting layer containing a phosphorescent compound, a first organic compound, and a second organic compound between a pair of electrodes, in which a combination of the first organic compound and the second organic compound forms an exciplex (excited complex). The light-emitting element transfers energy by utilizing an overlap between the emission spectrum of the exciplex and the absorption spectrum of the phosphorescent compound and thus has high energy transfer efficiency. Therefore, a light-emitting element having high external quantum efficiency can be obtained.
1. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer comprising a phosphorescent compound, a first organic compound, and a second organic compound between the pair of electrodes,
wherein the first organic compound and the second organic compound are selected so as to form an exciplex,
wherein an emission spectrum of the exciplex overlaps with a longest wavelength side absorption band in an absorption spectrum of the phosphorescent compound, and
wherein a difference between an energy value of a peak of the emission spectrum of the exciplex and an energy value of a peak of the longest wavelength side absorption band in the absorption spectrum of the phosphorescent compound is 0.3 eV or less.
2. The light-emitting element according to claim 1 , wherein the first organic compound, the second organic compound, and the phosphorescent compound are mixed in the light-emitting layer.
3. The light-emitting element according to claim 1 , wherein the phosphorescent compound is an organometallic complex.
4. The light-emitting element according to claim 1 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.
5. An electronic device comprising the light-emitting element according to claim 1 .
6. A lighting device comprising the light-emitting element according to claim 1 .
7. The light-emitting element according to claim 1 , wherein an energy of the exciplex can be transferred to the phosphorescent compound from the exciplex.
8. The light-emitting element according to claim 1 , wherein each of a level of a triplet excitation energy of the first organic compound and a level of a triplet excitation energy of the second organic compound is higher than a level of a triplet excitation energy of the phosphorescent compound.
9. A light-emitting element comprising:
a first electrode;
a first light-emitting layer over the first electrode;
a charge-generation layer over the first light-emitting layer;
a second light-emitting layer over the charge-generation layer; and
a second electrode over the second light-emitting layer,
wherein at least one of the first light-emitting layer and the second light-emitting layer comprises a phosphorescent compound, a first organic compound, and a second organic compound,
wherein the first organic compound and the second organic compound are selected so as to form an exciplex,
wherein an emission spectrum of the exciplex overlaps with a longest wavelength side absorption band in an absorption spectrum of the phosphorescent compound, and
wherein a difference between an energy value of a peak of the emission spectrum of the exciplex and an energy value of a peak of the longest wavelength side absorption band in the absorption spectrum of the phosphorescent compound is 0.3 eV or less.
10. The light-emitting element according to claim 9 , wherein the difference between the energy value of the peak of the emission spectrum of the exciplex and the energy value of the peak of the longest wavelength side absorption band in the absorption spectrum of the phosphorescent compound is 0.2 eV or less.
11. The light-emitting element according to claim 9 , wherein an energy of the exciplex can be transferred to the phosphorescent compound from the exciplex.
12. The light-emitting element according to claim 9 , wherein each of a level of a triplet excitation energy of the first organic compound and a level of a triplet excitation energy of the second organic compound is higher than a level of a triplet excitation energy of the phosphorescent compound.
13. The light-emitting element according to claim 9 , wherein the difference between the energy value of the peak of the emission spectrum of the exciplex and the energy value of the peak of the longest wavelength side absorption band in the absorption spectrum of the phosphorescent compound is 0.1 eV or less.
14. The light-emitting element according to claim 9 , wherein the other one of the first light-emitting layer and the second light-emitting layer comprises a fluorescent material.
15. The light-emitting element according to claim 9 , wherein an emission color of the first light-emitting layer and an emission color of the second light-emitting layer are complementary.
16. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer comprising a phosphorescent compound, a first organic compound, and a second organic compound between the pair of electrodes,
wherein the first organic compound and the second organic compound are selected so as to form an exciplex,
wherein an emission spectrum of the exciplex overlaps with a longest wavelength side absorption band in an absorption spectrum of the phosphorescent compound, and
wherein a difference between an energy value of a peak of the emission spectrum of the exciplex and an energy value of a peak of the longest wavelength side absorption band in the absorption spectrum of the phosphorescent compound is 0.2 eV or less.
17. The light-emitting element according to claim 16 , wherein the difference between the energy value of the peak of the emission spectrum of the exciplex and the energy value of the peak of the longest wavelength side absorption band in the absorption spectrum of the phosphorescent compound is 0.1 eV or less.
18. The light-emitting element according to claim 16 , wherein the first organic compound, the second organic compound, and the phosphorescent compound are mixed in the light-emitting layer.
19. The light-emitting element according to claim 16 , wherein the phosphorescent compound is an organometallic complex.
20. The light-emitting element according to claim 16 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.
21. An electronic device comprising the light-emitting element according to claim 16 .
22. A lighting device comprising the light-emitting element according to claim 16 .
23. The light-emitting element according to claim 16 , wherein an energy of the exciplex can be transferred to the phosphorescent compound from the exciplex.
24. The light-emitting element according to claim 16 , wherein each of a level of a triplet excitation energy of the first organic compound and a level of a triplet excitation energy of the second organic compound is higher than a level of a triplet excitation energy of the phosphorescent compound.