IP Library › Granted Patent US 10,132,969
Granted Patent B2
US 10,132,969 · App. 15/458,795 · Granted Nov 20, 2018

Retroreflective articles including optically active areas and optically inactive areas

Inventors: Kenneth L. Smith (White Bear Lake, MN); Michael Benton Free (Saint Paul, MN); Bimal V. Thakkar (Woodbury, MN); Raymond C. Chiu (Woodbury, MN)
Assignee: 3M INNOVATIVE PROPERTIES COMPANY
G02B5/124B32B3/263B32B3/30B32B7/12B32B15/20B32B27/08B32B27/281B32B27/302B32B27/306B32B27/308B32B27/32B32B27/322B32B27/325B32B27/34B32B27/38B32B27/42G02B5/122B32B2250/44B32B2255/10B32B2255/12B32B2255/20B32B2255/26B32B2307/416B32B2307/418B32B2307/732B32B2307/75
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Quick Facts
Patent No.
US 10,132,969
App. No.
15/458,795
Granted
Nov 20, 2018
Kind
B2
Abstract

This disclosure generally relates to retroreflective articles and methods of making such articles.

Claims (28)

1. A retroreflective article, comprising:

a retroreflective layer including multiple cube corner elements that collectively form a structured surface that is opposite a major surface; and

a sealing layer having a first region and a second region, wherein the second region is in contact with the structured surface and wherein the second region surrounds the first region to form at least one cell with a cell size that is less than 1000 microns; and

wherein the sealing layer further includes a barrier layer disposed within the first region between the sealing layer and the retroreflective layer separating a low refractive index layer from the sealing layer;

wherein the retroreflective article exhibits a coefficient of retroreflection R A that is not less than about 40 cd/(lux·m 2 ) for an observation angle of 0.2 degrees and an entrance angle of −4 degrees.

2. The retroreflective article of claim 1 , wherein the cell size is less than 750 microns.

3. The retroreflective article of claim 1 , wherein the second region forms multiple discrete cells.

4. The retroreflective article of claim 3 , wherein the multiple discrete cells each have a cell shape and a cell size and at least one of the shape and size of at least two different discrete cells are unequal.

5. The retroreflective article of claim 3 , wherein the multiple discrete cells each have a cell shape and a cell size that are substantially equal to each other.

6. The retroreflective article of claim 1 , wherein the sealing layer is a pressure sensitive adhesive.

7. The retroreflective article of claim 1 , wherein the retroreflective article exhibits a total light return that is not less than about 5% for incident visible light at an entrance angle of −4 degrees.

8. The retroreflective article of claim 1 , wherein the retroreflective article exhibits a coefficient of retroreflection R A that is not less than about 80 cd/(lux·m 2 ) for an observation angle of 0.2 degrees and an entrance angle of −4 degrees.

9. The retroreflective article of claim 1 , wherein the retroreflective article exhibits a coefficient of retroreflection R A that is not less than about 8 cpl for an observation angle of 2.0 degrees and an entrance angle of −4 degrees.

10. The retroreflective article of claim 1 , wherein the retroreflective article exhibits a % R T slope that is not less than about 3%/degree for an entrance angle of −4 degrees and an observation angle of 2 degrees.

11. The retroreflective article of claim 1 , wherein the retroreflective article exhibits a coefficient of retroreflection R A that is not less than about 4 cpl for an observation angle of 3.0 degrees and an entrance angle of −4 degrees.

12. The retroreflective article of claim 1 , wherein the retroreflective article exhibits a % R T slope that is not less than about 1.5%/degree for an entrance angle of −4 degrees and an observation angle of 3 degrees.

13. The retroreflective article of claim 1 , wherein less than about 65% of the structured surface is retroreflective.

14. The retroreflective article of claim 1 , wherein the second region is raised relative to the first region.

15. A retroreflective article, comprising:

a retroreflective layer including multiple cube corner elements that collectively form a structured surface that is opposite a major surface; and

a sealing layer having a first region and a second region, wherein the second region is in contact with the structured surface and wherein the second region surrounds the first region to form at least one cell with a cell size that is less than 1000 microns; and

wherein the sealing layer further includes a barrier layer disposed within the first region between the sealing layer and the retroreflective layer separating a low refractive index layer from the sealing layer;

wherein the multiple discrete cells each have a cell shape and a cell size and at least one of the shape and size of at least two different discrete cells are unequal.

16. A retroreflective article, comprising:

a retroreflective layer including multiple cube corner elements that collectively form a structured surface that is opposite a major surface; and

a sealing layer having a first region and a second region, wherein the second region is in contact with the structured surface and wherein the second region surrounds the first region to form at least one cell with a cell size that is less than 1000 microns; and

wherein the sealing layer further includes a barrier layer disposed within the first region between the sealing layer and the retroreflective layer separating a low refractive index layer from the sealing layer;

wherein the retroreflective article exhibits a total light return that is not less than about 5% for incident visible light at an entrance angle of −4 degrees.

Continuity (2)
Continuation 13641271
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