Heat storage member
A heat storage member including: a substrate containing a SiC sintered body as a principal ingredient; a coating layer disposed at least to a part of surface of the substrate; and a heat storage material disposed at least to a part of a surface of the coating layer and configured to store and radiate heat by a reversible chemical reaction with a reaction medium or a heat storage material configured to store and radiate heat by physical adsorption to a reaction medium and by physical desorption from a reaction medium. A softening point of the coating layer is a temperature at 1000° C. or less.
1. A heat storage member comprising:
a substrate containing a SiC sintered body as a principal ingredient;
a coating layer disposed in a surface of the substrate; and
a heat storage material disposed in a surface of the coating layer and configured to store and radiate heat by a reversible chemical reaction with a reaction medium, or
a heat storage material configured to store and radiate heat by physical adsorption to a reaction medium and by physical desorption from a reaction medium;
wherein a softening point of the coating layer is a temperature at 1000° C. or less.
2. The heat storage member according to claim 1 , wherein the coating layer contains P 2 O 5 as a principal ingredient, and a content rate of P 2 O 5 is 20 to 45% by mass.
3. The heat storage member according to claim 1 , wherein the coating layer contains B 2 O 3 as a principal ingredient, and a content rate of B 2 O 3 is 20 to 45% by mass.
4. The heat storage member according to claim 1 , wherein the coating layer contains Bi 2 O 3 as a principal ingredient, and a content rate of Bi 2 O 3 is 65 to 85% by mass.
5. The heat storage member according to claim 2 , wherein the coating layer contains as a secondary ingredient at least one of Al 2 O 3 , SiO 2 , ZnO, V 2 O 5 , PbO, SnO, B 2 O 3 and Bi 2 O 3 .
6. The heat storage member according to claim 3 , wherein the coating layer contains as a secondary ingredient at least one of Al 2 O 3 , SiO 2 , ZnO, V 2 O 5 , PbO, SnO, P 2 O 5 and Bi 2 O 3 .
7. The heat storage member according to claim 4 , wherein the coating layer contains as a secondary ingredient at least one of Al 2 O 3 , SiO 2 , ZnO, V 2 O 5 , PbO, SnO, P 2 O 5 and B 2 O 3 .
8. The heat storage member according to claim 2 , wherein the coating layer contains as the secondary ingredient at least one of CaO, BaO, SrO represented by RO and Li 2 O, Na 2 O, K 2 O represented by R 2 O.
9. The heat storage member according to claim 2 , wherein the coating layer contains as the secondary ingredient at least one of TeO 2 and TiO 2 .
10. The heat storage member according to claim 1 , wherein the substrate has a content ratio of SiC ranging from 40 to 99.7% by mass, excluding an impure ingredient inevitably contained in a raw material.
11. The heat storage member according to claim 1 , wherein the substrate is a porous material including a void, and the coating layer is disposed at least in a part of a surface of the void in the substrate.
12. The heat storage member according to claim 1 , wherein the substrate includes a void, and has a three-dimensional network structure including a skeleton having a porosity of 1% or less, and the coating layer is disposed at least in a part of the surface of the void.
13. The heat storage member according to claim 12 , wherein the skeleton includes a Si—SiC sintered body, and a content ratio of metal Si in the skeleton is ranging from 5 to 60% by mass.
14. The heat storage member according to claim 1 , wherein the surface of the coating layer is disposed with protrusions having a difference between recesses and protrusions of 0.5 to 100 μm.
15. The heat storage member according to claim 14 , wherein density of the protrusions with respect to a surface area of the coating layer is 1 to 1000000 protrusions/10000 μm 2 .
16. The heat storage member according to claim 15 , wherein the coating layer includes particulates dispersed in the coating layer and having an average particle diameter of 5 nm to 100 μm.
17. The heat storage member according to claim 16 , wherein the particulates are at least one of SiC particles, metal Si particles, Si—SiC particles, and C particles.
18. The heat storage member according to claim 1 , wherein the heat storage material includes at least one selected from the group consisting of oxides of Mg, Ca, Sr, Ba, hydroxides of Mg, Ca, Sr, Ba, carbonates of Mg, Ca, Sr, Ba, chlorides of Mg, Ca, Sr, Ba, sulfates of Mg, Ca, Sr, Ba, and zeolite.
19. The heat storage member according to claim 1 , wherein the heat storage material is a particulate having an average particle diameter ranging from 5 nm to 100 μm.