Composite dielectric ceramic material having anti-reduction and high temperature stability characteristics and method for preparing same
A composite dielectric ceramic material having anti-reduction and high temperature stability characteristics includes the main component of (1-x)(BaTiO 3 )-x(Ba 2 LiTa 5 O 15 ) formulated in accordance with the relative molar ratio of up to 100 mole composite dielectric ceramics and a predetermined ratio of one or multiple oxide subcomponents corresponding to 100 moles of the main component. The oxide subcomponents of Li 2 TiO 3 , BaSiO 3 , (Ba 0.6 Ca 0.4 )SiO 3 and SiO 2 can be used as sintering aids to provide a sintering promotion effect. The oxide subcomponents of CaO, MnO, MgO can also be selected used to improve dielectric stability. More particularly, CaO has the advantages of improving the anti-reduction ability and increasing the coefficient of resistance. Therefore, with the adding of the oxide subcomponents and their interactions, the rate of change of the TCC curve of the composite dielectric ceramic material (1-x)(BaTiO 3 )-x(Ba 2 LiTa 5 O 15 ) in the temperature range of −55° C.˜200° C. is significantly inhibited, and its dielectric constant (k-values) is also well improved.
1. A composite dielectric ceramic material comprising:
main components of BaTiO 3 and Ba 2 LiTa 5 O 15 ; and
Li 2 TiO 3 to improve the dielectric characteristics of said main components, an amount of said Li 2 TiO 3 is in the range of 0.1˜30 moles corresponding to 100 moles of said main components.
2. The composite dielectric ceramic material as claimed in claim 1 , further comprising a unary oxide selected from the group of MnO, MgO, CaO, SiO 2 and their combinations, the added amount of said unary oxide is in the range of 0.1˜10.0 moles.
3. The composite dielectric ceramic material as claimed in claim 2 , wherein the rate of change of the TCC curve in the temperature range of 150˜200° C. is between ±15.0%.