Multimetallic catalysts for selective hydrogenation of dienes and acetylenes, and purification of olefin feedstocks
A catalyst for hydrogenation reaction processes includes an oxide substrate surface, a MO x promoter, where M is a transition metal or main group elemental oxide, the promoter being deposited on the substrate, and a platinum group catalytic metal.
1. A method of forming a mixture of 1-butene and 2-butenes comprising:
exposing a C4 feedstock contaminant to a catalyst comprising M′/M/E x O y where the catalyst metal M′ is a Pt metal, the promotor M is a material selected from the group consisting of B, Zn, and Sn wherein the promotor has a structure selected from the group consisting of monolayer, single metal sites, or extended structures and E x O y is a substrate where E is Si, Al, Ti, or Zr and x and y represent stoichiometric amounts; and
forming the mixture of 1-butene and 2-butenes.
2. The method of claim 1 , wherein forming the mixture comprises a selectivity for 1-butene and 2-butene of at least 80%.
3. The method of claim 1 , wherein exposing the C4 feedstock contaminant is at a temperature of approximately 200° C.
4. The method of claim 1 , wherein at least 70% of the C4 feedstock contaminant is converted to the mixture.
5. The method of claim 1 , wherein the C4 feedstock contaminant is 1,3-butadiene, vinylacetylene, or a combination thereof.
6. The method of claim 1 , wherein the catalyst comprises the catalyst deposited on the promotor M which is deposited on the substrate and further wherein exposing the C4 feedstock comprises exposing the C4 feedstock to the catalyst metal.
7. The method of claim 1 , wherein the catalyst comprises promotor deposited on the catalyst which is deposited on the substrate and further wherein exposing the C4 feedstock comprises exposing the C4 feedstock to the promotor.