IP Library Granted Patent US 10,603,891
Granted Patent B2
US 10,603,891 · App. 15/499,425 · Granted Mar 31, 2020

Additively manufactured high temperature objects

Inventors: Scott DeFelice (Holyoke, MA); Anthony DeCarmine (Lebanon, CT)
Assignee: Hexcel Corporation
B33Y10/00B28B11/24B29C64/153C04B35/524C04B35/63488C04B35/83C23C18/1653C23C18/1692C23C18/32C23C18/34C23C18/36C25D5/12C25D5/50B29K2071/00B29K2105/06B29K2307/04B33Y70/00B33Y80/00C04B2235/48C04B2235/6026C04B2235/658C04B2235/6562C04B2235/665
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Quick Facts
Patent No.
US 10,603,891
App. No.
15/499,425
Granted
Mar 31, 2020
Kind
B2
Abstract

Method for producing an object by additively manufacturing a preform of the object from a building material comprising a polymer. The preform is encapsulated with a metal or metal alloy encapsulant that is capable of withstanding temperatures greater than the preform. The encapsulated preform is heated at a predetermined temperature and for a period of time, such that the preform at least partially transmutes into the form of a carbonaceous solid.

Claims (37)

1. A method of producing a three-dimensional object, comprising the steps of:

additively manufacturing a preform of a three-dimensional object from a building material selected from the group consisting of a polymer, polyaryletherketone (“PAEK”), carbon fiber, at least 15% carbon fiber by weight, or polyetherketone ketone (“PEKK”);

encapsulating the preform with a metal or metal alloy that is capable of withstanding temperatures greater than the preform;

providing venting holes in the encapsulated preform prior to a step of heating so that solvents may be vented from the encapsulated preform during the step of heating;

heating the encapsulated preform at a predetermined temperature and for a period of time, such that the preform substantially transmutes into a form of a carbonaceous solid residue;

maintaining the preform within an inert gas environment during the heating step;

wherein the step of additively manufacturing the preform of the three-dimensional object from the building material comprises the following steps:

applying a layer of the building material on a bed or on a previously applied layer of the building material in a powder form;

solidifying select points of the layer of the building material by a heat energy introduced by electromagnetic radiation or particle radiation according to a cross-section pattern assigned to layer so that the building material at the select points is solidified by the radiation;

wherein the applying step and the solidifying step are successively repeated until all cross sections of the preform of the object are solidified;

wherein the step of encapsulating the preform comprises the step of applying a nickel plating that is capable of withstanding high temperatures;

wherein the step of heating comprises:

increasing the temperature in the inert gas environment at a controlled rate that minimizes expansion of the preform;

maintaining a temperature in the inert gas environment, after the step of increasing the temperature, between 400 Celsius and 500 Celsius.

2. The method of claim 1 , further comprising a step of closing the venting holes in the metal alloy encapsulant after the step of heating.

3. The method of claim 2 , wherein the step of closing the venting holes is performed in the inert environment.

4. A method of producing a three-dimensional object, comprising the steps of:

additively manufacturing a preform of a three-dimensional object from a building material selected from the group consisting of a polymer, polyaryletherketone (“PAEK”), or carbon fiber;

encapsulating the preform with a metal or metal alloy that is capable of withstanding temperatures greater than the preform;

providing venting holes in the encapsulated preform so that solvents may be vented from the encapsulated preform during a subsequent heating;

heating the encapsulated preform at a predetermined temperature and for a period of time, such that the preform substantially transmutes into a form of a carbonaceous solid residue;

maintaining the preform within an inert gas environment during the heating step;

wherein the step of additively manufacturing the preform of the three-dimensional object from the building material comprises the following steps:

applying a layer of the building material on a bed or on a previously applied layer of the building material in a powder form;

solidifying select points of the layer of the building material by a heat energy introduced by electromagnetic radiation or particle radiation according to a cross-section pattern assigned to layer so that the building material at the select points is solidified by the radiation;

wherein the applying step and the solidifying step are successively repeated until all cross sections of the preform of the object are solidified;

wherein the step of encapsulating the preform comprises the step of applying a nickel plating that is capable of withstanding high temperatures;

wherein the step of heating comprises:

increasing the temperature in the inert gas environment at a controlled rate that minimizes expansion of the preform;

maintaining a temperature in the inert gas environment, after the step of increasing the temperature, at 400 Celsius or greater.

5. The method of claim 4 , wherein the temperature is maintained for a period of time such that the preform substantially transmutes into the form of a carbonaceous solid residue.

6. The method of claim 4 , further comprising a step of closing the venting holes in the metal alloy encapsulant after the step of heating.

7. The method of claim 4 , wherein the step of closing the venting holes is performed in the inert environment.

8. The method of claim 4 , wherein the building material is at least 15% carbon fiber by weight.

9. The method of claim 4 , wherein the building material comprises polyetherketone ketone (“PEKK”).

10. The method of claim 4 , wherein the step of heating comprises:

maintaining a temperature in the inert gas environment, after the step of increasing the temperature, between 400 Celsius and 500 Celsius.

Assignments (3)
SECURITY INTEREST Recorded Mar 13, 2026
From: OXFORD PERFORMANCE MATERIALS, INC.
To: KENSTON CAPITAL EMERGING TECHNOLOGY FUND I LP
Reel/Frame 074077/0347 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 17, 2018
From: OXFORD PERFORMANCE MATERIALS, INC.
To: HEXCEL CORPORATION
Reel/Frame 044640/0722 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 2, 2017
From: DEFELICE, SCOTT; DECARMINE, ANTHONY
To: OXFORD PERFORMANCE MATERIALS, INC.
Reel/Frame 042210/0475 →
Continuity (2)
Provisional Application 62329480 · Apr 29, 2016
Related Publication 20170313050A1 · Nov 2, 2017