Process for the recovery of carboxylic acid and wood treatment process
The present invention concerns a process for the recovery of carboxylic acid from a fraction comprising carboxylic acid and impurities, and a process for the manufacture of treated wood, which comprise the step of submitting a fraction containing carboxylic acid and impurities to a gas stripping operation.
1. A process for recovering carboxylic acid from a fraction containing carboxylic acid and impurities, the process comprising submitting said fraction to a gas stripping operation, and recovering at least a purified carboxylic acid fraction,
wherein the fraction containing the carboxylic acid and the impurities further contains halogenated impurities selected from the group consisting of hydrogen halides, carboxylic acid halides, and mixtures thereof, wherein the carboxylic acid fraction containing the carboxylic acid and the impurities originates from an acylation process, the acylation process concerns acylation of materials comprising polysaccharides.
2. The process according to claim 1 ,
further comprising an additional separation step prior to the gas stripping operation.
3. The process according to claim 1 ,
further comprising an additional step of pretreating the fraction containing the carboxylic acid and the impurities to be introduced in the gas stripping operation with an aqueous phase.
4. The process according to claim 3 ,
wherein the fraction containing the carboxylic acid and the impurities further contains carboxylic anhydride, wherein the content of the carboxylic anhydride in the fraction containing the carboxylic acid and the impurities prior to the addition of the aqueous phase is less than 20 weight %.
5. The process according to claim 3 ,
wherein the amount of the aqueous phase is controlled such that the water content of the fraction obtained is from 0.01 weight % to 20 weight %.
6. The process according to claim 1 ,
wherein the fraction containing the carboxylic acid and the impurities further contains terpenes, terpenoids, or both.
7. The process according to claim 1 ,
wherein the fraction containing the carboxylic acid and the impurities contains at least one impurity selected from the group consisting of wood preservatives, preservation agents, or combinations thereof.
8. The process according to claim 1 ,
wherein the gas stripping operation comprises at least one gas selected from the group consisting of air, oxygen, CO 2 , exhaust gas, and inert gases.
9. The process according to claim 1 ,
wherein the gas stripping operation is performed continuously in a countercurrent or co-current way, or batchwise.
10. The process according to claim 1 ,
wherein the carboxylic acid fraction submitted to the gas stripping operation has a temperature of from 10 to 90° C. in the gas stripping operation.
11. The process according to claim 1 ,
wherein the process from which the carboxylic acid fraction containing the carboxylic acid and the impurities originates is a wood treatment process.
12. The process according to claim 1 ,
further comprising withdrawing a mixture rich in carboxylic anhydride as a side stream or a bottom stream from a separation step.
13. The process according to claim 12 ,
which further comprises recycling the mixture rich in carboxylic anhydride to a wood treatment process.
14. A process for manufacturing treated wood comprising the process according to claim 1 .
15. The process according to claim 1 ,
wherein the carboxylic acid is acetic acid.
16. The process according to claim 1 ,
wherein the acylation process is an acetylation process.
17. The process according to claim 1 ,
wherein the polysaccharides are selected from starch, cellulose, or combinations thereof.