Multistage Membrane Separation and Purification Process and Apparatus for Separating High Purity Methane Gas
The present invention provides a method for separating high purity methane gas from biogas, which comprises the steps of: compressing and cooling biogas (step 1); and separating carbon dioxide by introducing the biogas compressed and cooled in step 1 into a four-stage polymer separation membrane system in which the residue stream of the first polymer separation membrane is connected to the second polymer separation membrane, the residue stream of the second polymer separation membrane is connected to the third polymer separation membrane, and the permeate stream of the second polymer separation membrane is connected to the fourth polymer separation membrane (step 2).
1 . A method for separating high purity methane gas from biogas comprising the following steps:
compressing and cooling biogas (step 1); and
separating carbon dioxide by introducing the biogas compressed and cooled in step 1 into the four-stage polymer separation membrane system for gas separation, wherein the residue stream of the first polymer separation membrane is connected to the second polymer separation membrane, the residue stream of the second polymer separation membrane is connected to the third polymer separation membrane, and the permeate stream of the second polymer separation membrane is connected to the fourth polymer separation membrane (step 2).
2 . The method for separating high purity methane gas from biogas according to claim 1 , wherein the polymer separation membrane has the carbon dioxide/methane selectivity of 20˜100.
3 . The method for separating high purity methane gas from biogas according to claim 1 , wherein the compression and cooling of step 1 is performed with the biogas pressure of 5˜100 bar.
4 . The method for separating high purity methane gas from biogas according to claim 1 , wherein the difference of the pressure between the permeation part and the residue part of each of the first polymer separation membrane, the second polymer separation membrane, the third polymer separation membrane, and the fourth polymer separation membrane in step 2 is adjusted in the range of 5˜30 bar by adopting the low lower pressure or adopting the reduced pressure condition.
5 . The method for separating high purity methane gas from biogas according to claim 1 , wherein when the concentration of methane included in the biogas of step 1 is variable, high purity methane gas is purified by regulating the area of the first polymer separation membrane, and the area ratio of the second polymer separation membrane, the third polymer separation membrane, and the fourth polymer separation membrane.
6 . The method for separating high purity methane gas from biogas according to claim 1 , wherein the method additionally includes the step of recirculating the permeate stream of the third polymer separation membrane and the residue stream of the fourth polymer separation membrane back to the stage before the compression process of step 1 above (step 3).
7 . An apparatus for purifying methane gas comprising:
supply part to supply biogas;
compression and cooling part to compress and cool down the biogas supplied from the supply part; and
purification part containing the 4-stage polymer separation membrane system for gas separation to separate carbon dioxide from the gas compressed and cooled down in the compression and cooling part wherein the residue stream of the first polymer separation membrane is connected to the second polymer separation membrane, the residue streams of the second polymer separation membrane is connected to the third polymer separation membrane, and the permeate stream of the second polymer separation membrane is connected to the fourth polymer separation membrane.
8 . A methane gas having a purity of at least 95% separated by the method of claim 1 .
9 . An automobile fuel containing the high purity methane gas of claim 8 .
10 . A city gas containing the high purity methane gas of claim 8 .